Compositions, systems, and methods for introducing lubricants, and additives, that are designed to work with environmentally friendly refrigerants into vehicle heat management systems including passenger compartment air conditioning (A/C) systems are disclosed. Methods for charging lubricants and specific additives using environmentally desirable (low GWP) refrigerant or refrigerant blend compositions into an environmentally friendly system, such as a system that uses HFO-1234yf, are also disclosed.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

A refrigerating oil comprising a lubricating base oil, a first extreme pressure agent containing sulfur and phosphorus as constituent elements and a second extreme pressure agent containing phosphorus but not containing sulfur as constituent elements, and having a kinematic viscosity at 100° C. of 0.5 mm.sup.2/s or more and 2.5 mm.sup.2/s or less.

The invention relates to a lubricating oil composition and a refrigerant composition containing a polyalkylene glycol having a terpenoid end group, such as a farnesol end group.

An aspect of the present invention provides a refrigerating machine oil containing an ester-based base oil, at least one epoxy compound selected from an alkyl glycidyl ether and an aryl glycidyl ether, and a phenol-based antioxidant, wherein a content of the epoxy compound is 0.7% by mass or more based on a total amount of the refrigerating machine oil, and the refrigerating machine oil is used with a refrigerant containing trifluoroiodomethane.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

The present invention provides a refrigerating machine oil containing an ester base oil obtained from pentaerythritol and mixed fatty acids of a fatty acid having 8 carbon atoms and a fatty acid having 9 carbon atoms, wherein a ratio of a weight average molecular weight Mw to a number average molecular weight Mn, Mw/Mn, of the ester base oil is 1.06 to 1.20, and used with a mildly flammable hydrofluorocarbon refrigerant.

The present invention relates to heat transfer compositions comprising refrigerant, lubricant and stabilizer, wherein the refrigerant comprises about 49% by weight difluoromethane (HFC-32), about 11.5% by weight pentafluoroethane (HFC-125), and about 39.5% by weight trifluoroiodomethane (CF.sub.3I), and wherein said lubricant comprises polyol ester (POE) lubricant and/or polyvinyl ether (PVE) lubricant, and wherein said stabilizer comprises an alkylated naphthalene and optionally but preferably an acid depleting moiety.

The present invention provides a refrigerating machine oil comprising, as a base oil, a polymer having a structural unit represented by the following formula (1):

##STR00001##

wherein R.sup.1, R.sup.2 and R.sup.3, which may be the same as or different from each other, represent a hydrogen atom or a hydrocarbon group; and R.sup.4 represents a hydrocarbon group or an organic group containing an oxygen atom, and having a number average molecular weight Mn of 300 or more and 3000 or less and a ratio of a weight-average molecular weight Mw to a number average molecular weight Mn (Mw/Mn) of 1.10 or more and 2.00 or less, and the refrigerating machine oil being used with a refrigerant selected from the group consisting of difluoromethane, a mixture of difluoromethane and pentafluoroethane, a mixture of difluoromethane, pentafluoroethane and 1,1,1,2-tetrafluoroethane, a mixture of pentafluoroethane, 1,1,1,2-tetrafluoroethane and 1,1,1-trifluoroethane, unsaturated hydrofluorocarbons, hydrocarbons and carbon dioxide.

A method for operating a refrigerant circulation system comprising a compressor, a condenser, an expansion mechanism, and an evaporator connected in this order with piping, wherein a refrigerant comprising trifluoroiodomethane is used as a refrigerant; a refrigerating machine oil comprising, as a base oil, a polyolester synthesized from a polyhydric alcohol and fatty acids, with a proportion of a fatty acid having 9 carbon atoms in the fatty acids being 65 mol % or less is used as a refrigerating machine oil; and a temperature of an entire area of the refrigerant circulation system is kept at 160° C. or lower.