This invention relates to N-alkylated anthranilic acid derivative and their use in lubricants, such as engine oils, as TBN boosters. The invention particularly relates to compositions that deliver an ash-free base to a lubricant in the form of a basic amine additive, without adversely impacting seal compatibility and/or degradation, and methods thereof.

This disclosure describes blends of detergent and antiwear lubricating additives and lubricants including such additive blends effective to reduce high-temperature deposits, and in particular, high-temperature deposits in low ash compositions.

The instant disclosure generally relates to lubricating compositions having an oil of lubricating viscosity, a mixture of boron-containing and boron-free dispersants, an overbased magnesium-based detergent, an overbased calcium-based detergent, an ashless friction modifier, and, optionally, other performance additives. The instant lubricating compositions may improve one or more of cleanliness, TBN retention, fuel economy and low-speed preignition (“LSPI”).

The invention discloses a lubricating grease with thixotropy and a preparation method thereof. The lubricating grease comprises a polyurea/high base number calcium sulfonate composite thickener, colloidally dispersed calcium carbonate solid particles in the form of calcite, a calcium borate or calcium borate composite, and a calcium soap of fatty acid having 12 to 24 carbon atoms. The above components are uniformly dispersed in an oil phase medium. The content of high base number calcium sulfonate in the lubricating grease is less than 22 wt %.

The addition of mixed thio acid amide molybdenum dithiocarbamates to lubricant compositions comprising magnesium detergents and/or overbased magnesium detergents, e.g., overbased magnesium sulfonate, provides lubricant compositions that suppress Low Speed Pre-Ignition and possess excellent low friction characteristics. Furthermore, the addition of molybdenum based friction reducing additives, e.g., mixed thio acid amide molybdenum dithiocarbamates, in combination with one or more fatty acid 2-hydroxyalkylamides, to lubricant compositions comprising magnesium detergents or overbased magnesium detergents provides lubricant compositions that suppress Low Speed Pre-ignition and possess excellent low friction characteristics.

Disclosed herein are marine diesel cylinder lubricating oil compositions comprising (a) a major amount of one or more Group II basestocks, and (b) a detergent composition comprising (i) one or more alkaline earth metal salts of an alkyl-substituted hydroxyaromatic carboxylic acid having a total base number (TBN) greater than 250, and (ii) one or more high overbased alkyl aromatic sulfonic acids or salts thereof; wherein the aromatic moiety of the alkyl aromatic sulfonic acids or salts thereof contains no hydroxyl groups; and wherein the marine diesel cylinder lubricating oil composition has a TBN of about 5 to about 120.

There is provided a refrigeration cycle apparatus in which good lubricity can be achieved when a refrigeration cycle is performed using a refrigerant having a sufficiently low GWP. The refrigeration cycle apparatus contains a refrigerating oil and a refrigerant composition containing a refrigerant containing trans-1,2-difluoroethylene (HFO-1132(E)), trifluoroethylene (HFO-1123), and 2,3,3,3-tetrafluoro-1-propene (R1234yf).

The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.

A method for utilizing a lubricating oil composition in which the content of a metal-based cleaning agent (X) having a base value of 100 mgKOH/g or less is 630 mass ppm or less in terms of metal atoms, and the content of sulfated ash is 1.5 mass % or less. The method includes measuring at least one physical property value among the capacitance and the dielectric constant of the lubricating oil composition while using the lubricating oil composition, and evaluating the progress of degradation of the lubricating oil composition.

A lubricating composition comprising a base oil and one or more additives, wherein the composition has: a sulphated ash content (according to ASTM D 874) of at least 0.4 wt % and at most 1.0 wt. %, by weight of the lubricating composition; a total base number (TBN) value (according to ASTM D 2896) of at least 4.0 mg KOH/g and at most 12 mg KOH/g; a total aromatics content contributed by the base oil in the range from 1 wt % to 30 wt %, by weight of the lubricating composition; and a sulphur content contributed by the base oil of 0.4 wt % or less, by weight of the lubricating composition; and wherein the base oil comprises a blend of (i) a first base oil which is a mineral base oil selected from an API Group I mineral base oil and an API Group II mineral base oil, and mixtures thereof, and (ii) a second base oil selected from an API Group II base oil and an API Group III base oil, preferably wherein the first base oil belongs to a different API group to that of the second base oil.