C21C5/005

HIGH STRENGTH STAINLESS STEEL MATERIAL
20230059069 · 2023-02-23 ·

Methods for improving a toughness and a strength of a stainless steel material are described herein. For example, a high strength stainless steel material can comprise at least 11 wt. % Cr, between 0.01 wt. % and 1.0 wt. % Ni, more 0 wt. % Mo, more than 0 wt. % W, more than 0 wt. % Ti, more than 0 wt. % Nb, and more than 0 wt. % V. In some examples, the high strength stainless steel material can be heat treated with at least one quench treatment and at least one tempering heat treatment. In some examples, the high strength stainless steel material can comprise between 0.01 wt. % and 0.5 wt. % Ni, no more than 0.25 wt. % Mo, no more than 0.1 wt. % W, no more than 0.1 wt. % Ti, no more than 0.1 wt. % Nb, and no more than 0.1 wt. % V.

FERRITIC STAINLESS STEEL

A ferritic stainless steel with chemical composition includes, in mass %, Cr: 10.5 to 25.0%; Al: 0.01 to 0.20%; Ti: 0.15% to 0.35%; O: 0.0001 to 0.0030%; and Mg: 0.008×[% Al] or more, in which oxysulfide-containing inclusions are present in the steel, a number ratio of the oxysulfide-containing inclusions whose minor axis is 3 μm or more is 5 pieces/mm.sup.2 or less, and a number ratio of the oxysulfide-containing inclusions whose minor axis is 15 μm or more is 0.05 pieces/mm.sup.2 or less. 75% or more of the inclusions whose minor axis is 3 μm or more have an oxysulfide part whose composition satisfies formulae (1) and (2),


CaO+Al.sub.2O.sub.3+MgO≥90%  formula (1),


Al.sub.2O.sub.3/MgO≤1.25  formula (2).

STAINLESS STEEL FOR METAL FOILS, STAINLESS STEEL FOIL, AND METHODS FOR PRODUCING THEM

The stainless steel for metal foils includes, in mass %, 0.0001% or more and 0.15% or less of C, 0.30% or more and 2.0% or less of Si, 0.1% or more and 15% or less of Mn, 0.040% or less of P, 5% or more and 30% or less of Ni, 0.0001% or more and 0.01% or less of S, 16% or more and 25% or less of Cr, 5% or less of Mo, 0.005% or less of Al, 0.0030% or less of Ca, 0.0010% or less of Mg, 0.0010% or more and 0.0060% or less of O, and 0.0001% or more and 0.5% or less of N. The number of inclusions with a maximum equivalent circle diameter of 5 μm or more is 0.5 inclusions/mm.sup.2 or less in a thickness of 0.010 mm or more and 0.2 mm or less.

STAINLESS STEEL, STAINLESS STEEL MATERIAL, AND METHOD FOR PRODUCING STAINLESS STEEL

A stainless steel with reduced S and suppressed generation of hard inclusions. Inclusions with an equivalent circle diameter of 5 μm or more, the number density of a first inclusion having the average composition of, in mass %, CaO: 0% or more and 15% or less, SiO.sub.2: 0% or more and 20% or less, Al.sub.2O.sub.3: 50% or more and 70% or less, and MgO: 10% or more and 40% or less is 0.5 inclusions/mm.sup.2 or less, the number density of a second inclusion having CaO: 10% or more and 70% or less, SiO.sub.2: 10% or more and 65% or less, Al.sub.2O.sub.3: 20% or less, MgO: 5% or more and 50% or less, and CaF.sub.2: 0% or more and 5% or less is 0.2 inclusions/mm.sup.2 or less, and the number density of a third inclusion having CaO: 5% or more and 40% or less, SiO.sub.2: 10% or more and 40% or less, Al.sub.2O.sub.3: 10% or more and 40% or less, MgO: 5% or more and 30% or less, and CaF.sub.2: 5% or more and 40% or less is 0.005 inclusions/mm.sup.2 or more and 0.5 inclusions/mm.sup.2 or less.

STAINLESS STEEL WITH GOOD MIRROR POLISHABILITY AND METHOD FOR PRODUCING SAME

The stainless steel contains 0.0001 mass % or more and 0.15 mass % or less of C, 0.30 mass % or more and 2.0 mass % or less of Si, 0.1 mass % or more and 15 mass % or less of Mn, 5 mass % or more and 30 mass % or less of Ni, 0.0001 mass % or more and 0.01 mass % or less of S, 16 mass % or more and 25 mass % or less of Cr, 0 mass % or more and 5 mass % or less of Mo, 0 mass % or more and 0.005 mass % or less of Al, 0 mass % or more and 0.0010 mass % or less of Mg, 0.0010 mass % or more and 0.0060 mass % or less of 0, and 0.0001 mass % or more and 0.5 mass % or less of N, and at least includes an inclusion with an equivalent circle diameter of 5 μm or more, having the average composition of 5 mass % or more of MnO, 20 mass % or more of Cr.sub.2O.sub.3+Al.sub.2O.sub.3, 1 mass % or more of Al.sub.2O.sub.3, and 5 mass % or less of Ca0. The number density of the inclusion having the composition is 0.5 inclusions/mm.sup.2 or less.

DUAL-PHASE STAINLESS STEEL AND DUAL-PHASE STAINLESS STEEL SEAMLESS PIPE

A dual-phase stainless steel or dual-phase stainless steel seamless pipe has a certain composition, the dual-phase stainless steel or dual-phase stainless steel seamless pipe having a microstructure containing 20 to 70% austenitic phase and 30 to 80% ferritic phase by volume, the dual-phase stainless steel or dual-phase stainless steel seamless pipe having a yield strength, YS, of 448 MPa or more, and containing oxide inclusions of which oxide inclusions having an average particle diameter of 1 μm or more have a number density of 15/mm.sup.2 or less, and at most 50 mass % of the oxide inclusions having an average particle diameter of 1 μm or more are oxide inclusions containing aluminum.

METHOD FOR PRODUING HIGH NITROGEN STEEL BY DUPLEX MELTING PROCESS OF PRESSURIZED LADLE REFINING AND PRESSURIZED ELECTROSLAG REMELTING

The present disclosure provides a method for producing a high nitrogen steel by a duplex melting process of a pressurized ladle refining and a pressurized electroslag remelting, which relates to the technical field of high nitrogen steel melting. In the present disclosure, the molten steel is subjected in sequence to a nitrogen alloying, a deep deoxidation and a deep desulfurization by adding a nickel-magnesium alloy and rare earth in the pressurized ladle furnace, and a combination of a blowing nitrogen from the bottom of the pressurized ladle and a pressurized nitriding at the interface of gas and the molten steel is used to achieve a high-efficiency nitrogen alloying, a uniform nitrogen distribution, and a decreased impurity content in the ingot; then the ingot is subjected to a pressurized electroslag remelting to obtain a high nitrogen steel.

METHOD FOR PRODUCING CHROMIUM-CONTAINING MOLTEN IRON

A charged material containing alloy iron of at least one of ferrochrome containing metallic Si or ferrosilicon, and unreduced slag containing Cr oxide generated by oxidative refining, is charged into an electric furnace as a mixture in which a mass ratio of a metallic Si amount to a Cr oxide amount is from 0.30 to 0.40, and a C concentration is in a range of from 2.0% by mass to a saturation concentration, and molten iron containing Cr obtained due to the Cr oxide undergoing reduction processing is produced, such that, when the charged material is heated and melted in the electric furnace, an attainment temperature is set to from 1400° C. to 1700° C., a maximum average heating rate in any 80° C. interval from 1300° C. to the attainment temperature is set to 15.0° C./min or less, and a minimum average heating rate in any 80° C. interval from 1300° C. to the attainment temperature is set to 3.0° C./min or greater.

METHOD FOR PRODUCING CHROMIUM-CONTAINING MOLTEN IRON

A charged material containing a metal raw material of at least one of ferrochromium containing metal Si or ferrosilicon and unreduced slag containing Cr oxide generated by oxidation refining is charged into an AC electric furnace including three electrodes, a mass ratio of a metal Si amount to a Cr oxide amount being from 0.30 to 0.40, and a C concentration being from 2.0% by mass to a saturation concentration, and operation is performed under a condition where a diameter PCD (m) of a circle passing through the centers of the three electrodes viewed in a plan view from a central axis direction of the electric furnace, an average electrode height H.sub.e (m) that is a vertical distance from a tip of each electrode to a molten metal surface, a furnace inner diameter D.sub.f (m), a molten slag thickness H.sub.s (m), a spreading diameter D.sub.arc (m) of an arc on the molten metal surface, and a deflection angle θ (deg) of the arc satisfy the following relationships to produce molten iron containing Cr.


D.sub.arc=PCD+2H.sub.e.Math.tan θ


θ=52.5−75.Math.(PCD/D.sub.f)


0.22≤D.sub.arc/D.sub.f≤0.30


0.35≤H.sub.e/H.sub.s≤1.50

Method for producing high nitrogen steel by duplex melting process of pressurized ladle refining and pressurized electroslag remelting

The present disclosure provides a method for producing a high nitrogen steel by a duplex melting process of a pressurized ladle refining and a pressurized electroslag remelting, which relates to the technical field of high nitrogen steel melting. In the present disclosure, the molten steel is subjected in sequence to a nitrogen alloying, a deep deoxidation and a deep desulfurization by adding a nickel-magnesium alloy and rare earth in the pressurized ladle furnace, and a combination of a blowing nitrogen from the bottom of the pressurized ladle and a pressurized nitriding at the interface of gas and the molten steel is used to achieve a high-efficiency nitrogen alloying, a uniform nitrogen distribution, and a decreased impurity content in the ingot; then the ingot is subjected to a pressurized electroslag remelting to obtain a high nitrogen steel.