The method of recovering copper from sulfide ores with copper and iron, comprises the steps of reacting, in a reaction vessel, a copper-containing sulfide ore with sulfur dioxide gas to form elemental sulfur, an iron oxide and a copper sulfide, separating the solids comprising the iron oxide and copper sulfate from a liquid phase of the reaction mixture, leaching the dried solids with an aqueous solution comprising water or dilute sulfuric acid and solubilizing the copper sulfate, and recovering copper from the solubilized copper sulfate.

Oxygen is injected into the windbox of a fluidized bed ore roaster to form a fluidizing and oxidizing gas stream of elevated oxygen content which is fed into only the feed zone into which the ore to be fluidized is fed.

Oxygen is injected into the windbox of a fluidized bed ore roaster to form a fluidizing and oxidizing gas stream of elevated oxygen content which is fed into only the feed zone into which the ore to be fluidized is fed.

The method of recovering copper from sulfide ores with copper and iron, comprises the steps of reacting, in a reaction vessel, a copper-containing sulfide ore with sulfur dioxide gas to form elemental sulfur, an iron oxide and a copper sulfide, separating the solids comprising the iron oxide and copper sulfate from a liquid phase of the reaction mixture, leaching the dried solids with an aqueous solution comprising water or dilute sulfuric acid and solubilizing the copper sulfate, and recovering copper from the solubilized copper sulfate.

Provided is a recovery method for valuable metals in copper anode slime. By using the recovery method of the disclosure, selenium, copper, tellurium, arsenic, lead, bismuth, and precious metals gold and silver in the copper anode slime are recovered. The method adopts two-step vacuum carbothermal reduction to replace reduction smelting of anode slime and stepwise blowing of noble lead in the traditional pyrometallurgy, and avoids the emission of arsenic-containing soot in the traditional process. The recovered gold-rich residue contains almost no base metals such as lead, bismuth, antimony, and arsenic. After subjecting the gold-rich residue to leaching gold by chlorination and reduction, a gold powder could be obtained therefrom with a lower content of base metals than traditional processes. Therefore, the method greatly reduces the amount of produced slag, shortens the production cycle, and reduces the loss of precious metals in the slag.