A method of recovering a cathode active material precursor according to an embodiment of the present invention includes preparing a cathode active material mixture including a lithium composite oxide, separating lithium from the cathode active material mixture to form a preliminary transition metal precursor, acid-treating the preliminary transition metal precursor to form a complex transition metal salt solution, and adding an acidic extractant to the complex transition metal salt solution and then adding a basic compound to recover a transition metal precursor, and thus the extraction rate of transition metals can be improved.

A treatment process for crystallizing a metal sulfate involving pre-treating a feedstock comprising calcium, magnesium, and/or lithium impurities, the pre-treating involving pre-leaching the feedstock in the presence of a lixiviant, selectively extracting a first portion of any of the impurities from the feedstock, and forming a leached solution comprising an uncrystallized metal sulfate and any remaining impurities; and/or refining the leached solution and removing a second portion of any of the remaining impurities; and crystallizing the uncrystallized metal sulfate from the leached solution to form a crystallized metal sulfate. So processed, the crystallized metal sulfate may be battery-grade or electroplating-grade.

Stationary phase for preparative High Pressure Liquid Chromatography (HPLC) for preparative separation of Rare Earth Elements (REEs), the stationary phase comprising porous particles suitable for HPLC having a non-polar surface being impregnated with ligands binding REEs, wherein the porous particles has a pore size of 300 Å or higher, is described.

Methods for recovering a metal from a metal-containing material are provided. In embodiments, such a method comprises exposing a metal-containing material to a leaching solution comprising a solvent and a binoxalate, a tetraoxalate, or a combination thereof, under conditions to provide a leachate comprising a soluble metal oxalate; inducing precipitation of a metal-containing precipitate comprising the metal of the soluble metal oxalate from the leachate; and recovering the metal-containing precipitate.

The present invention relates to a method of preparing a precursor material of a positive electrode active material from a waste lithium secondary battery, to a method of preparing a lithium secondary battery positive electrode active material including a precursor material prepared by the same precursor preparation method, and to a lithium secondary battery positive electrode active material prepared by the same positive electrode active material preparation method.

Provided is a method for separating impurities and cobalt without using an electrolysis process from a cobalt chloride solution containing impurities and producing a high purity cobalt sulfate. The production method includes: a first solvent extraction step (S1) of bringing an organic solvent containing an alkyl phosphoric acid-based extractant into contact with a cobalt chloride solution containing impurities, and extracting zinc, manganese, and calcium into the organic solvent to separate to remove zinc, manganese, and calcium; a copper removal step (S2) of adding a sulfurizing agent to a cobalt chloride solution and generating a precipitate of sulfide of copper to separate to remove copper; a second solvent extraction step (S3) of bringing an organic solvent containing a carboxylic acid-based extractant into contact with a cobalt chloride solution and back extracting cobalt with sulfuric acid after extracting cobalt into the organic solvent to obtain cobalt sulfate solution; and a crystallization step (S4) of the cobalt sulfate solution obtained after having undergone through the second solvent extraction step (S3). These steps are sequentially executed. Without using an electrolysis process, a high purity cobalt sulfate is directly produced by separating cobalt and impurities containing manganese.

A variety of systems, methods and compositions are disclosed, including, in one method for recycling a spent alkaline battery comprising: dissolving insoluble metal ions in aqueous solution thereby producing pregnant leach solution; extracting zinc sulfate from aqueous solution thereby producing zinc sulfate product and raffinate solution comprising manganese sulfate and potassium sulfate; separating manganese hydroxide from raffinate solution thereby producing manganese sulfate product and aqueous potassium sulfate solution; crystallizing aqueous potassium sulfate solution to produce solid potassium sulfate product. A system for recycling spent alkaline battery comprising: first liquid-solid extraction unit capable of dissolving insoluble metal ions in aqueous solution thereby producing pregnant leach solution; liquid-liquid extraction unit capable of extracting zinc from pregnant leach solution; second liquid-solid extraction unit capable of precipitating manganese hydroxide from raffinate produced by liquid-liquid extraction unit; and third liquid-solid extraction unit capable of crystallizing aqueous potassium sulfate solution produced by second liquid-solid extraction unit.

A method for processing positive electrode active material waste of lithium ion secondary batteries, the waste containing cobalt, nickel, manganese and lithium, the method including: a carbon mixing step of mixing the positive electrode active material waste in the form of powder with carbon to obtain a mixture having a ratio of a mass of carbon to a total mass of the positive electrode active material waste and the carbon of from 10% to 30%; a roasting step of roasting the mixture at a temperature of from 600° C. to 800° C. to obtain roasted powder; a dissolution step including a first dissolution process of dissolving lithium in the roasted powder in water or a lithium-containing solution, and a second dissolution process of dissolving the lithium in a residue obtained in the first dissolution process in water; and an acid leaching step of leaching a residue obtained in the lithium dissolution step with an acid.

Single-stage and multi-stage systems and methods for the recovery of critical elements in substantially pure form from lithium ion batteries are provided. The systems and methods include supported membrane solvent extraction using an immobilized organic phase within the pores of permeable hollow fibers. The permeable hollow fibers are contacted by a feed solution on one side, and a strip solution on another side, to provide the simultaneous extraction and stripping of elements from dissolved lithium ion cathode materials, while rejecting other elements from the feed solution. The single- and multi-stage systems and methods can selectively recover cobalt, manganese, nickel, lithium, aluminum and other elements from spent battery cathodes and are not limited by equilibrium constraints as compared to traditional solvent extraction processes.

The present disclosure relates to a method for separating yttrium oxide from a high-yttrium rare earth ore by a grouping manner and a method for separating yttrium oxide from a medium-yttrium and europium-rich rare earth ore by a grouping manner, and belongs to the technical field of rare earth extraction and separation. The separating method by a grouping manner according to the present disclosure have advantages such as being advanced and reasonable, short process, low production cost, good adaptability, and easy operation and control. The method has better overall technical and economic indicator performance than the naphthenic acid process and has the value of practical application.