The present disclosure discloses a preparation method of a powder metallurgy (PM) superalloy with high strength and plasticity. Under the multi-field coupling action of a thermal field and a force field, the PM superalloy is obtained in a high-temperature graphite mold by using the method of conducting heat preservation and oscillating-pressure sintering in two steps. Under the action of a circulating pressure, rearrangement of powders and discharge of pores are promoted, and therefore, the PM superalloy is sintered and formed. The present disclosure further discloses a PM superalloy prepared by using the method above. The PM superalloy has the characteristics of low grade of prior particle boundary defects, uniform grain refinement and high density. The sintered PM superalloy obtained in the present disclosure has a yield strength of 955 MPa, a tensile strength of 1,437 MPa and an elongation of 31.9%, and has high strength and plasticity.

A nickel-based brazing foil with a composition consisting essentially of 11 atom %<Cr≤16 atom %, 0 atom %≤Mo≤3.5 atom %, 4 atom %≤B≤5.5 atom %, 11 atom %≤Si≤16 atom %, 0 atom %≤P≤0.5 atom %, 0 atom %≤C≤0.85 atom %, 0 atom %≤Fe≤5 atom %, 0 atom %≤Co≤5 atom %, 0 atom %≤Cu≤2 atom %, 0 atom %≤V≤2 atom %, 0 atom %≤Nb≤2 atom %, incidental impurities of ≤1.0 wt. % and the rest Ni, is provided.

This application relates to a nickel-based superalloy suitable for additive manufacturing and a method for manufacturing a high-temperature member using the same. The nickel-based superalloy includes 13.7% to 14.3% by weight of Cr, 9.0% to 10.0% by weight of Co, 3.7% to 4.3% by weight of Mo, 2.6% to 3.4% by weight of Ti, 3.7% to 4.3% by weight of W, 2.6% to 3.4% by weight of Al, 0.15% to 0.19% by weight of C, greater than 0% by weight and not less than 0.005% by weight of B, 0.01% to 0.05% by weight of Zr, 2.0% to 2.7% by weight of Ta, 0.6% to 1.1% by weight of Hf, Ni residue, and unavoidable impurities. The nickel-based superalloy has a high fraction of strengthening phase, thereby maintaining excellent high-temperature strength. Additive manufacturing with the nick-based superalloy is much easier than existing nickel-based superalloys, thereby cost-effectively providing maximized cooling efficiency.

A Nickel-based superalloy, whose composition includes, in percent by weight of the total composition: Chromium: 10.0-11.25; Cobalt: 11.2-13.7; Molybdenum: 3.1-3.8; Tungsten: 3.1-3.8; Aluminium: 2.9-3.5; Titanium: 4.6-5.6; Niobium: 1.9-2.3; Hafnium: 0.25-0.35; Zirconium: 0.040-0.060; Carbon: 0.010-0.030; Boron: 0.01-0.030; Nickel: remainder as well as unavoidable impurities; the composition being free of tantalum.

A Nickel-based superalloy, whose composition includes, in percent by weight of the total composition: Chromium: 10.0-11.25; Cobalt: 11.2-13.7; Molybdenum: 3.1-3.8; Tungsten: 3.1-3.8; Aluminium: 2.9-3.5; Titanium: 4.6-5.6; Niobium: 1.9-2.3; Hafnium: 0.25-0.35; Zirconium: 0.040-0.060; Carbon: 0.010-0.030; Boron: 0.01-0.030; Nickel: remainder as well as unavoidable impurities; the composition being free of tantalum.

A cemented carbide for a flow component for controlling the pressure and flow of well products includes in wt %: about 7 to about 9 Co; about 5 to about 7 Ni; about 19 to about 24 Ti C; about 1.5 to about 2.5 Cr.sub.3C.sub.2; about 0.1 to about 0.3 Mo and balance of WC. A cemented carbide for fluid handling components and seal ring a comprises in wt %: about 1 to about 30 Ti C; about 12 to about 20 Co+Ni; about 0.5 to about 2.5 Cr; about 0.1 to about 0.3 Mo and balance of WC. A cemented carbide for fluid handling components and seal ring a comprises in wt %: about 15 to about 30 Ti C; about 5 to about 20 Ni; about 0.5 to about 2. Cr; about 0.5 to about 2.5 Mo and balance of WC.

Provided is a Ni-based alloy having a composition consisting of, by mass %, Cr: 14.0% to 17.0% (preferably, not less than 14.0% and less than 15.0%), Fe: 5.0% to 9.0%, Ti: 2.2% to 2.8%, Al: 0.40% to 1.00%, a total amount of Nb+Ta: 0.7% to 1.2%, B: 0.001% to 0.010%, Zr: 0.01% to 0.15%, Mg: 0.001% to 0.050%, Mn: 0.01% to 0.20%, Cu: 0.005% to 0.300%, Mo: 0.01% to 0.30%, C: 0.01% to 0.05%, and the balance of Ni with inevitable impurities. In a creep test under conditions of a test temperature of 750° C. and a test load of 330 MPa, the Ni-based alloy preferably has a creep rupture life of not less than 120 hours and an elongation of not less than 16%, i.e., has good high-temperature creep characteristics. The Ni-based alloy is suitable for a gas turbine member.

Provided is a Ni-based alloy having a composition consisting of, by mass %, Cr: 14.0% to 17.0% (preferably, not less than 14.0% and less than 15.0%), Fe: 5.0% to 9.0%, Ti: 2.2% to 2.8%, Al: 0.40% to 1.00%, a total amount of Nb+Ta: 0.7% to 1.2%, B: 0.001% to 0.010%, Zr: 0.01% to 0.15%, Mg: 0.001% to 0.050%, Mn: 0.01% to 0.20%, Cu: 0.005% to 0.300%, Mo: 0.01% to 0.30%, C: 0.01% to 0.05%, and the balance of Ni with inevitable impurities. In a creep test under conditions of a test temperature of 750° C. and a test load of 330 MPa, the Ni-based alloy preferably has a creep rupture life of not less than 120 hours and an elongation of not less than 16%, i.e., has good high-temperature creep characteristics. The Ni-based alloy is suitable for a gas turbine member.

A method for preparing an improved article including a nickel-based superalloy is presented. The method includes heat-treating a workpiece including a nickel-based superalloy at a temperature above the gamma-prime solvus temperature of the nickel-based superalloy and cooling the heat-treated workpiece with a cooling rate less than 50 degrees Fahrenheit/minute from the temperature above the gamma-prime solvus temperature of the nickel-based superalloy so as to obtain a cooled workpiece. The cooled workpiece includes a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers. An article having a minimum dimension greater than 6 inches is also presented. The article includes a material having a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers.

A method for preparing an improved article including a nickel-based superalloy is presented. The method includes heat-treating a workpiece including a nickel-based superalloy at a temperature above the gamma-prime solvus temperature of the nickel-based superalloy and cooling the heat-treated workpiece with a cooling rate less than 50 degrees Fahrenheit/minute from the temperature above the gamma-prime solvus temperature of the nickel-based superalloy so as to obtain a cooled workpiece. The cooled workpiece includes a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers. An article having a minimum dimension greater than 6 inches is also presented. The article includes a material having a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers.