Disclosed is an electrical steel sheet with an insulating coating formed by applying a surface-treatment agent to at least one surface of the electrical steel sheet and drying the surface-treatment agent, wherein the surface-treatment agent contains: certain trialkoxysilane and/or dialkoxysilane (A); a silane coupling agent (B) that does not contain a polymerizable unsaturated group in its structure; plate-like silica (C); a polymerizable unsaturated-group-containing compound (D); and water, within a range satisfying the following conditions (1) to (3): (1) a mass ratio (A/B) of (A) to (B) is from 0.05 to 1.00; (2) a content of (C) is 2 mass % to 30 mass % with respect to a total mass of (A) to (D) in the surface-treatment agent; and (3) a content of (D) is 2 mass % to 18 mass % with respect to the total mass of (A) to (D) in the surface-treatment agent.

A process comprising: (i) coating particles of silicon carbide, silicon nitride, boron carbide or boron nitride with a metal alloy or metal layer; (ii) agglomerating the particles of step (i); thermally spraying the agglomerated metal or metal alloy coated particles onto a substrate to provide a coating thereon.

The present disclosure relates to a transition metal-doped nickel phosphide nanostructure, a method for preparing the same, and a catalyst for electrochemical water decomposition including the transition metal-doped nickel phosphide nanostructure. More specifically, a transition metal-doped nickel phosphide nanostructure can be prepared by converting a zinc oxide nanostructure grown on a substrate vertically by hydrothermal synthesis to a transition metal-doped nickel oxide nanostructure by cation exchange and then phosphorizing the nickel oxide. The transition metal-doped nickel phosphide nanostructure of the present disclosure is advantageous in that it has superior catalytic activity and conductivity due to large surface area. In addition, when used as a catalyst for water decomposition under an alkaline condition, it has a low overvoltage and can have excellent catalytic activity for hydrogen evolution reaction or oxygen evolution reaction.

A method for manufacturing a coated metal powder includes: preparing a silanol solution in which a silicon-containing substance is dissolved in an alkaline aqueous solution; charging a metal powder into the silanol solution to obtain a dispersion; and forming a coating containing a silicon oxide on a particle surface of the metal powder by adding an acidic aqueous solution to the dispersion.

The present invention relates to a photoelectric film and a fabrication method thereof, and in particular, to a layered polycrystalline lead selenide (PbSe) film and a fabrication method thereof. The fabrication method mainly includes: (1) fabricating a dense PbSe layer on a substrate through chemical bath deposition (CBD); (2) fabricating a loose plumbonacrite (Pb.sub.10O(OH).sub.6(CO.sub.3).sub.6) layer on the dense PbSe layer through CBD; (3) placing a sample with the dense PbSe layer and the Pb.sub.10O(OH).sub.6(CO.sub.3).sub.6 layer in a selenium ion-containing solution to allow an ion exchange reaction to finally form the layered polycrystalline PbSe film. The fabrication method has the advantages of simple process, low cost, and high controllability. The PbSe film fabricated by the method is composed of a lower dense polycrystalline cubic PbSe layer and an upper loose polycrystalline cubic PbSe layer, which can be widely used in the fabrication of components in the field of photoelectric conversion or thermoelectric conversion, such as infrared (IR) sensors, solar cells, laser emitters, and thermoelectric converters.

A methods and systems are disclosed for coating a large oven cavity. A method of coating an oven includes spraying a coating at room temperature onto a plurality of surfaces in the oven cavity in one or more layers and manipulating the oven to position the plurality of surfaces while spraying in various embodiments. An article includes an oven having a cavity, where the cavity has a surface with a volume of about 3 ft.sup.3 to about 7 ft.sup.3, and a coating on the surface of the cavity, the coating including a sol-gel ceramic.

Methods for forming and controlling morphology cracks in silicon dioxide (SiO.sub.2) film comprising: preparing SiO.sub.2precursor solution comprising solvent, precursor of SiO.sub.2, precursor of metal oxide nanocrystals, water, and acid; coating the solution onto substrate; drying the solution atop the substrate at a temperature between about 20° C. to 100° C. between 1 minute to 24 hours to form SiO.sub.2 film having uniformly dispersed metal oxide nanocrystals, wherein shorter drying times yield substantially spherical shaped metal oxide nanocrystals and longer drying times yield rod and disc shaped metal oxide nanocrystals; and thermally treating the SiO.sub.2 film between about 60° C. to 500° C. between 1 minute to 24 hours to form cracked mesh SiO.sub.2 film, wherein two cracks initiate from rod shaped metal oxide nanocrystals, three to four cracks initiate from spherical shaped metal oxide nanocrystals, and four or more cracks initiate from disc shaped metal oxide nanocrystals. Other embodiments are described and claimed.

The present disclosure relates to an electrode for electrolysis, in which a structure of a metal base layer is optimized, and a preparation method thereof, wherein the electrode for electrolysis of the present invention exhibits an overvoltage improved in comparison to a conventional electrode while having excellent durability due to a small loss of a coating layer.

Aspects described herein generally relate to a method of coating a metallic surface. The method includes forming a solution including a corrosion inhibitor having one or more thiol moieties and a hydroxide. The metallic surface is coated with the solution to form a treated metallic surface. The treated metallic surface is further coated with an organosilane, an acid, and a metal alkoxide to form a coating system.

The present invention relates to different inorganic ceramic coatings whose chemical compositions comprise silicates, acids, metallic oxysalts such as tungstates and molybdates, water, and non-metallic oxides such as silicon oxide. Said water-based inorganic ceramic coatings improve the ceramic, anti-corrosive and resistance properties of the metal substrates that are coated with same. Likewise, the present invention relates to a sol-gel process for synthesizing said coatings in which the non-metallic oxide, before being mixed with the rest of the components of the chemical compositions as claimed, can be pre-treated with hydrochloric acid and ammonium hydroxide, or can be sonicated to achieve a particle size in the range from approximately 160 to approximately 180 nm. Finally, the present invention also relates to a method for coating the metal parts with the inorganic ceramic coatings as claimed in the present invention.