Patent classifications
C23C2/0224
LOW-SILICON AND LOW-CARBON EQUIVALENT GPA GRADE MULTI-PHASE STEEL PLATE/STEEL STRIP AND MANUFACTURING METHOD THEREFOR
Disclosed are a low-silicon and low-carbon equivalent GPa grade multi-phase steel plate/steel strip and a manufacturing method therefor. The steel plate/steel strip comprises the following components in percentages by weight: 0.03-0.07% of C, 0.1-0.5% of Si, 1.7-2.0% of Mn, P<0.02%, S<0.01%, N<0.01%, 0.01-0.05% of Al, 0.4-0.7% of Cr, 0.001-0.005% of B, and 0.07-0.15% of Ti, and also comprises one or both of 0.15-0.4% of Mo or 0.02-0.08% of Nb, with the balance being Fe and other inevitable impurities; and at the same time, the steel plate/steel strip satisfies: the content of available B*>0.001, the content of available B*=B-[Ti-3.4N-1.2(C—Nb/7.8)]/22, CE<0.58, and CE=C+Mn/6+(Cr+Mo+V)/5+(Si+Ni+Cu)/15. The steel plate has a tensile strength of >980 MPa and a yield strength of >780 MPa, and the hole expansion rate satisfies: if an original hole is a punched hole, the hole expansion rate is >50%; and if the original hole is a reamed hole, the hole expansion rate is >60%. The steel plate is mainly used in the preparation of vehicle chassis and suspension system parts.
STEEL SHEET AND METHOD OF MANUFACTURING THE SAME
A steel sheet includes a predetermined composition satisfying Expression (1), in which the microstructure at the ¼ thickness position from the surface in the sheet thickness direction includes, by vol %, ferrite: 95% or more and a remainder of the microstructure: 5% or less, has a proportion of unrecrystallized ferrite in the ferrite of 5% or less, and a half width w and an X-ray wavelength λ at a peak of (200) plane of the ferrite satisfy Expression (2).
0.80≤{(Ti/48−N/14)+Nb/93}/(C/12)≤5.00 (1)
w×λ≥0.20 (2)
Method for the manufacture of a galvannealed steel sheet
Method for the manufacture of a galvannealed steel sheet includes the following steps: A) the provision of a pre-coated steel sheet coated with a first coating comprising iron and nickel, such steel sheet having the following chemical composition in weight percent 0.10<C<0.40%, 1.5<Mn<3.0%, 0.7<Si<2.0%, 0.05<Al<1.0%, 0.75<(Si+Al)<3.0% and on a purely optional basis, one or more elements such as Nb≤0.5%, B≤0.005%, Cr≤1.0%, Mo≤0.50%, Ni≤1.0%, Ti≤0.5%, the remainder of the composition making up of iron and inevitable impurities resulting from the elaboration, B) the thermal treatment of such pre-coated steel sheet at a temperature between 600 to 1000° C., C) the hot-dip coating of the steel sheet obtained in step B) with a second coating based on zinc and D) an alloying treatment to form a galvannealed steel sheet.
STEEL SHEET AND METHOD OF MANUFACTURING THE SAME
A steel sheet includes a predetermined composition, in which a microstructure at a ¼ thickness position from a surface in a sheet thickness direction includes, by vol %, ferrite: 80% or more, martensite: 2% or less, and residual austenite: 2% or less, a proportion of unrecrystallized ferrite in the ferrite of 5% or less, and in the microstructure of the steel sheet stretched by 10% at the ¼ thickness position from the surface in the sheet thickness direction, a number density of voids having a maximum diameter of 1.0 μm or more is 1.0×10.sup.9 pieces/m.sup.2 or less.
METHOD OF MAKING A COLD FORMABLE HIGH STRENGTH STEEL STRIP AND STEEL STRIP
A method of manufacturing steel strip including the steps of: casting molten steel into slabs; reheating the slabs at 1150° C. or more for 1 hour or more; hot rolling the steel into a strip, preferably with an average F1 slab entry temperature above 1000° C.; coiling the hot rolled steel strip; batch annealing the steel strip: at an intercritical temperature (i.e. between Ac1 and Ac3), preferably below 700° C.; in non-oxidising and non-nitrogenated atmosphere; total annealing time at least 5 hours, preferably at least 10 hours to get Mn enrichment in austenite such that Mn content is at least 1.25 times bulk Mn content of the steel and C enrichment such that C content is at least 1.2 times bulk C content of the steel; cooling the steel after batch annealing in air, forced air or water quench.
HIGH STRENGTH GALVANIZED STEEL SHEET HAVING EXCELLENT SURFACE QUALITIES, PLATING ADHESION, AND FORMABILITY, AND METHOD FOR MANUFACTURING SAME
A high strength galvanized steel sheet having excellent surface qualities, plating adhesion, and formability is provided, wherein a galvanized layer is formed on a cold-rolled steel sheet comprising 0.1-0.3 wt % of C, 1-2.5 wt % of Si, 2.5-8 wt % of Mn, 0.001-0.5 wt % of sol. Al, at most 0.04 wt % of P, at most 0.015 wt % of S, at most 0.02 wt % of N (excluding 0 wt %), 0.1-0.7 wt % of Cr, at most 0.1 wt % of Mo, (48/14)*[N] to 0.1 wt % of Ti, 0.005-0.5 wt % of Ni, 0.01-0.07 wt % of Sb, at most 0.1 wt % of Nb, and at most 0.005 wt % of B, with the remainder being Fe and other inevitable impurities.
HIGH-STRENGTH GALVANIZED STEEL SHEET AND METHOD FOR PRODUCING THE SAME
A high-strength galvanized steel sheet that includes a chemical composition containing, by mass %, C: 0.15% or more and 0.25% or less, Si: 0.50% or more and 2.5% or less, Mn: 2.3% or more and 4.0% or less, P: 0.100% or less, S: 0.02% or less, Al: 0.01% or more and 2.5% or less, and Fe and inevitable impurities. The steel sheet having a microstructure containing, by an area percentage basis, a tempered martensite phase: 30% or more and 73% or less, a ferrite phase: 25% or more and 68% or less, a retained austenite phase: 2% or more and 20% or less, and other phases: 10% or less (including 0%), the other phases containing a martensite phase: 3% or less (including 0%) and a bainitic ferrite phase: less than 5% (including 0%).
METHOD FOR APPLYING A METAL PROTECTIVE COATING TO A SURFACE OF A STEEL PRODUCT
A method for applying a metallic protective coating to a surface of a steel product, where another surface is to remain free from the metallic protective coating, may involve applying the metallic protective coating by hot dip coating in a hot dip coating bath. A preliminary coating may be applied to the surface that is to remain free from the metallic protective coating prior to the hot dip coating. The preliminary coating may include SiO.sub.2 and may prevent the metallic protective coating from adhering to the intended surface during hot dip coating. Thus one surface of a steel product may be provided with a metallic protective coating, and another surface of the steel product may be kept free from the protective coating, all with a minimum of cost and complexity and with optimized resource economics. Further, the preliminary coating, deposited from a gas phase to that surface of the steel product that is to be kept free from the metallic protective coating, may be a layer that includes amorphous silicon dioxide and has a layer thickness of 0.5-500 nm.”
HIGH STRENGTH STEEL PRODUCT AND METHOD OF MANUFACTURING THE SAME
A hot-rolled strip steel product is described having a chemical composition consisting of, in terms of weight percentages (wt. %): 0.030%-0.10% C, 0%-1.10% Si, 0.50%-2.0% Mn, <0.020% P, <0.010% S,<0.010% N, 0%-0.60% Cr, 0%-0.20% Ni, 0%-0.25% Cu, 0%-0.30% Mo, 0%-0.15% Al, 0%-0.10% Nb, 0.10%-0.30% V, <0.020% Ti, 0%-0.0010% B, remainder being Fe and inevitable impurities, wherein the hot rolled strip steel product has a a microstructure comprising, in terms of volume percentages (vol. %), ferrite≥90, wherein the ferrite structure comprises bainite, at least 50% of polygonal ferrite and at most 10% quasi-polygonal ferrite, and wherein the steel strip product has an average hole expansion ratio≥50%, a yield strength (Rp0.2%) longitudinal to rolling direction of ≥660 MPa and a tensile strength≥760 MPa.
COATED STEEL SHEET WITH THIN ALUMINIUM ALLOY COATING AND COATING METHOD THEREOF
The present invention relates to a coated steel sheet having a thin aluminium alloy coating and a coating method thereof The coated steel sheet of the present invention is used for hot stamping. The coating thickness of the coated steel sheet is 5˜14 μm, wherein the aluminium alloy coating comprises a FeAlSi inhibitive layer adjacent to a substrate steel sheet and an Al alloy layer outside the FeAlSi inhibitive layer, wherein the thickness of the FeAlSi inhibitive layer is no more than 60% of the coating thickness and is 1.5˜6.0 μm. The diameters of Kirkendall voids within 2 μm from an interface between the FeAlSi inhibitive layer and the substrate steel to the interior of the substrate steel are no more than 2.5 μm, wherein the number of Kirkendall voids with a diameter of no less than 0.5 μm and no more than 2.5 μm does not exceed 15 per 35 μm. The present invention also discloses a coating method for coating a thin aluminium alloy coating on a substrate steel sheet for hot stamping. It can eliminate skip coating and enable a hot stamped component obtained by the coated steel sheet to have excellent resistance spot welding performance.