2-substituted benzimidazoles and methods of preparing the same are disclosed. The compositions may include a compound or salt thereof, a strong acid, and a carboxylic acid. The compositions may exclude a polar aprotic solvent. The compositions may be used to inhibit corrosion of a metal surface in contact with an aqueous system, and provide enhanced protection against corrosion of metals in the aqueous system.

A composition for inhibiting corrosion of a metal is provided. The corrosion inhibitor composition comprises 5-amino-2-mercaptobenzimidazole. The corrosion inhibitor composition can also comprise a 2-mercaptobenzimidazole derivative selected from the group consisting of 2-mercapto-5-methylbenzimidazole, 5-Ethoxy-2-mercaptobenzimidazole, 5-(difluoromethoxy)-2-mercapto-1H-benzimidazole 1-Methyl-1H-benzimidazole-2-thiol and 2-mercapto-5-nitrobenzimidazole. The corrosion inhibitor composition outperforms many other sulfur-containing corrosion inhibitors in kettle testing.

A composition for inhibiting corrosion of a metal is provided. The corrosion inhibitor composition comprises 5-amino-2-mercaptobenzimidazole. The corrosion inhibitor composition can also comprise a 2-mercaptobenzimidazole derivative selected from the group consisting of 2-mercapto-5-methylbenzimidazole, 5-Ethoxy-2-mercaptobenzimidazole, 5-(difluoromethoxy)-2-mercapto-1H-benzimidazole 1-Methyl-1H-benzimidazole-2-thiol and 2-mercapto-5-nitrobenzimidazole. The corrosion inhibitor composition outperforms many other sulfur-containing corrosion inhibitors in kettle testing.

The present invention relates to a process for anticorrosion pretreatment of multiple components in series, each component in the series at least partly comprises metal surfaces of zinc, iron and/or aluminum and undergoes a zinc phosphating step in which the component is contacted with an acidic aqueous composition containing an amount of an activating aid sufficient to ensure a layer weight below 5.5 g/m.sup.2 on a cleaned, untreated hot-dip galvanized steel surface (Z), wherein the activating aid is based on a water-dispersed particulate constituent at least partly selected from hopeite, phosphophyllite, scholzite and/or hureaulite, and at least one polymeric organic compound; and further relates to acidic aqueous zinc phosphating compositions obtainable by adding a particular amount of a colloidal aqueous solution containing the dispersed particulate constituent to an acidic aqueous composition containing zinc ions, phosphate ions and free fluoride.

The present invention relates to a process for anticorrosion pretreatment of multiple components in series, each component in the series at least partly comprises metal surfaces of zinc, iron and/or aluminum and undergoes a zinc phosphating step in which the component is contacted with an acidic aqueous composition containing an amount of an activating aid sufficient to ensure a layer weight below 5.5 g/m.sup.2 on a cleaned, untreated hot-dip galvanized steel surface (Z), wherein the activating aid is based on a water-dispersed particulate constituent at least partly selected from hopeite, phosphophyllite, scholzite and/or hureaulite, and at least one polymeric organic compound; and further relates to acidic aqueous zinc phosphating compositions obtainable by adding a particular amount of a colloidal aqueous solution containing the dispersed particulate constituent to an acidic aqueous composition containing zinc ions, phosphate ions and free fluoride.

A corrosion inhibition package for use with an aqueous acid composition, said package comprising: a terpene; a cinnamaldehyde or a derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are compositions comprising said corrosion inhibitor package. Preferably, the corrosion inhibition package meets the environmental requirements for classification as yellow according to the Norwegian North Sea offshore drilling regulatory requirements.

A corrosion inhibition package for use with an aqueous acid composition, said package comprising: a terpene; a cinnamaldehyde or a derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are compositions comprising said corrosion inhibitor package. Preferably, the corrosion inhibition package meets the environmental requirements for classification as yellow according to the Norwegian North Sea offshore drilling regulatory requirements.

A corrosion inhibitor composition, containing (a) a cinnamaldehyde compound, (b) an alkoxylated fatty amine, and (c) an imidazoline compound, and optionally (d) a surfactant, and (e) a solvent. A method of inhibiting corrosion of metal in contact with an acidic medium in an oil or gas field environment by introducing the corrosion inhibitor composition into the acidic medium, such as during acid stimulation operations.

A corrosion inhibitor composition, containing (a) a cinnamaldehyde compound, (b) an alkoxylated fatty amine, and (c) an imidazoline compound, and optionally (d) a surfactant, and (e) a solvent. A method of inhibiting corrosion of metal in contact with an acidic medium in an oil or gas field environment by introducing the corrosion inhibitor composition into the acidic medium, such as during acid stimulation operations.

A method of inhibiting corrosion of metal during acid stimulation of an oil and gas well that involves treating the oil and gas well with an acidic treatment fluid that includes 10 to 28 wt. % of an acid, based on a total weight of the acidic treatment fluid, and a corrosion inhibitor composition containing gelatin, wherein the gelatin is present in the acidic treatment fluid in a concentration of 0.1 to 10% by weight per total volume of the acidic treatment fluid.