Compounds, compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, using a corrosion-inhibiting composition comprising a dispersant having the structure of Formula 1 and a corrosion inhibitor having the structure of Formula 2

##STR00001##

wherein X.sub.1 is hydroxyl, —OC(O)R.sub.1; X.sub.2 is hydroxyl, or —OC(O)R.sub.2; X.sub.3 is hydroxyl or —OC(O)R.sub.3; R.sub.1, R.sub.2, and R.sub.3 are independently C.sub.10 to C.sub.30 alkyl or alkenyl; m, n, and o are independently integers from 1 to 10; R.sub.20 , R.sub.21, R.sub.22, R.sub.23, and R.sub.24 are independently hydrogen or —C(O)—R.sub.31; R.sub.31 is C.sub.10 to C.sub.30 alkyl or alkenyl; p is an integer of 0 or 1; q is an integer of 1 to 4; r is an integer of 0 or 1; s is an integer of 0 or 1; t is an integer from 1 to 4; and p1, q1, r1, r2, s1, and t1 are independently integers from 1 to 6; wherein when p, r, and s are 0, q+t is an integer from 4 to 8 and at least one of R.sub.20 , R.sub.21, R.sub.22, R.sub.23, and R.sub.24 is —C(O)—R.sub.31.

Compounds, compositions and methods are provided for reducing, inhibiting, or preventing corrosion of a surface, using a polyester polyamine compound. The polyester polyamine compound having a structure corresponding to Formula 1 or 2, or a salt thereof:

##STR00001##

wherein R.sub.1 is independently alkylene; R.sub.2 is independently hydrogen or —COR.sub.4; R.sub.3 is independently alkyl, alkenyl, aryl, or alkaryl; R.sub.4 is independently alkyl or alkenyl; R.sub.10 and R.sub.11 are each independently hydrogen, alkyl, or alkaryl; m is an integer from 1 to 10; n is an integer from 3 to 10; and wherein at least one R.sub.2 is —COR.sub.4.

The present disclosure provides a bis-quaternary ammonium salt of Formula I ##STR00001##
wherein A is selected from O, NH, S, C(O), C(NH) or C(S); R.sub.1 and R.sub.2 are independently selected from C.sub.1-3 alkyl or H; R.sub.3 is C.sub.1-16 alkyl, C.sub.13-20 aralkyl or C.sub.2-16 allyl; X.sup.− is selected from chloro, bromo, iodo, hydroxide, nitrate or sulphate; and n and m are independently 1 to 6. Furthermore, a corrosion inhibition formulation comprising said bis-quaternary ammonium salt is revealed. Also, convenient processes for the preparation of the salt of Formula I and the formulation are provided.

Disclosed are oleyl propylenediamine-based compounds used in compositions and methods for inhibiting corrosion. The method comprises introducing into a fluid source a composition comprising one or more oleyl propylenediamine-based compounds comprising Formula I:

##STR00001##

wherein Y.sub.1, Y.sub.2, and Y.sub.3 independently are hydrogen or a substituent of Formula (II):

##STR00002##

wherein V is —O— or —NH—, W is optionally present and is a linear or branched C.sub.1-10 aliphatic group, X is —H, —NZ.sub.3.sup.+, —COOH, —SO.sub.3H, —OSO.sub.3H.sub.2, —PO.sub.3H, —OPO.sub.3H.sub.2, or a salt thereof, each Z independently is hydrogen or a linear or branched C.sub.1-20 aliphatic group optionally interrupted or substituted with one or more oxygen atoms, and R is hydrogen or methyl, provided that at least one of Y.sub.1, Y.sub.2, or Y.sub.3 is a substituent of Formula (II).

A corrosion inhibiting composition is provided which comprises a salt of a fatty acid-amine condensate and an aromatic solvent. The composition can be used in reducing, inhibiting or preventing corrosion of a metal surface used in recovery, transportation, refining or storage of a hydrocarbon fluid containing elemental sulfur or polysulfide.

Pitting corrosion of stainless steel occurs in solutions of organic acid, such as tartaric acid, in an electrolyte solution with methanol. However, methanolic solutions containing at least one organic halide and at least one organic hydroxyacid and some water provide reduced pitting corrosion of stainless steel. The organic hydroxyacid may be a hydroxy acid containing 2 to 10 carbon atoms with at least one hydroxyl group and at least one carboxylic acid group, in a non-limiting example, glycolic acid. The pH of the methanolic solution may range from about 3.5 to about 8.

Disclosed are oleyl propylenediamine-based compounds used in compositions and methods for inhibiting corrosion. The method comprises introducing into a fluid source a composition comprising one or more oleyl propylenediamine-based compounds comprising Formula I: ##STR00001## wherein Y.sub.1, Y.sub.2, and Y.sub.3 independently are hydrogen or a substituent of Formula (II): ##STR00002## wherein V is —O— or —NH—, W is optionally present and is a linear or branched C.sub.1-10 aliphatic group, X is —H, —NZ.sub.3.sup.+, —COOH, —SO.sub.3H, —OSO.sub.3H.sub.2, —PO.sub.3H, —OPO.sub.3H.sub.2, or a salt thereof, each Z independently is hydrogen or a linear or branched C.sub.1-20 aliphatic group optionally interrupted or substituted with one or more oxygen atoms, and R is hydrogen or methyl, provided that at least one of Y.sub.1, Y.sub.2, or Y.sub.3 is a substituent of Formula (II).

Disclosed are oleyl propylenediamine-based compounds used in compositions and methods for inhibiting corrosion. The method comprises introducing into a fluid source a composition comprising one or more oleyl propylenediamine-based compounds comprising Formula I:

##STR00001##

wherein Y.sub.1, Y.sub.2, and Y.sub.3 independently are hydrogen or a substituent of Formula (II):

##STR00002##

wherein V is —O— or —NH—, W is optionally present and is a linear or branched C.sub.1-10 aliphatic group, X is —H, —NZ.sub.3.sup.+, —COOH, —SO.sub.3H, —OSO.sub.3H.sub.2, —PO.sub.3H, —OPO.sub.3H.sub.2, or a salt thereof, each Z independently is hydrogen or a linear or branched C.sub.1-20 aliphatic group optionally interrupted or substituted with one or more oxygen atoms, and R is hydrogen or methyl, provided that at least one of Y.sub.1, Y.sub.2, or Y.sub.3 is a substituent of Formula (II).

The present disclosure relates to a corrosion inhibitor formulation comprising: a) at least one quaternary ammonium salt; b) at least one fatty acid methyl ester; c) at least one viscosity reducing agent; and d) at least one solubilizing agent, wherein the at least one quaternary ammonium salt to the at least one fatty acid methyl ester weight ratio is in the range of 1:0.2-1:5.0. The instant disclosure further relates to the process of preparation of the corrosion inhibitor formulation.

The present disclosure provides a bis-quaternary ammonium salt of Formula I

##STR00001##

wherein A is selected from O, NH, S, C(O), C(NH) or C(S); R.sub.1 and R.sub.2 are independently selected from C.sub.1-3 alkyl or H; R.sub.3 is C.sub.1-16 alkyl, C.sub.13-20 aralkyl or C.sub.2-16 allyl; X.sup.− is selected from chloro, bromo, iodo, hydroxide, nitrate or sulphate; and n and m are independently 1 to 6. Furthermore, a corrosion inhibition formulation comprising said bis-quaternary ammonium salt is revealed. Also, convenient processes for the preparation of the salt of Formula I and the formulation are provided.