A clad porous metal substrate for use in a metal-supported electrochemical cell, wherein a metal support layer of defined porosity is clad on top and bottom sides with a layer containing a metal and/or a metal oxide. A metal-supported electrochemical half-cell and a metal-supported electrochemical cell are also described.

A wastewater to chemical fuel conversion device is provided that includes a housing having a first chamber and a second chamber, where the first chamber includes a bio-photoanode, where the second chamber includes a photocathode, where a backside of the bio-photoanode abuts a first side of a planatized fluorine doped tin oxide (FTO) glass, where a backside of the photocathode abuts a second side of the FTO glass, where a proton exchange membrane separates the first chamber from the second chamber, where the first chamber includes a wastewater input and a reclaimed water output, where the second chamber includes a solar light input and a H.sub.2 gas output, where the solar light input is disposed for solar light illumination of the first chamber and the second chamber.

A wastewater to chemical fuel conversion device is provided that includes a housing having a first chamber and a second chamber, where the first chamber includes a bio-photoanode, where the second chamber includes a photocathode, where a backside of the bio-photoanode abuts a first side of a planatized fluorine doped tin oxide (FTO) glass, where a backside of the photocathode abuts a second side of the FTO glass, where a proton exchange membrane separates the first chamber from the second chamber, where the first chamber includes a wastewater input and a reclaimed water output, where the second chamber includes a solar light input and a H.sub.2 gas output, where the solar light input is disposed for solar light illumination of the first chamber and the second chamber.

Electrocatalytic apparatus for the simultaneous conversion of methane and CO.sub.2 into methanol via an elctrochemical reactor operating at ambient temperature and pressure, said electrochemical reactor simultaneously converts CO.sub.2 to methanol by surficial catalytic reaction on the cathode, and methane to methanol by surficial catalytic reaction on the anode. The electrochemical reactor futher works with an electrolyte consisting of electrolytic complexes of water-soluable transition metals and small molecules as co-catalyst of the electrocatalytic reactions and facilitator of ionic transfer and solubility of CO.sub.2 and CH.sub.4 molecules in the electrolyte. The electrochemical reactor is further equipped with zero-gap membrane electrocatalytic electrode assemlics, the cathode and anode comprising two electrocatalytic mesoporous surfaces and being tubular and coaxial, delineating two regions, which are separated one from the other by an ion exchange membrane (27). The tubular electrodes pack vertically together, the external gaps being filled by an insulating material. The packed electrodes are electronically connected to the power source in a parallel electrical circuit.

Electrocatalytic apparatus for the simultaneous conversion of methane and CO.sub.2 into methanol via an elctrochemical reactor operating at ambient temperature and pressure, said electrochemical reactor simultaneously converts CO.sub.2 to methanol by surficial catalytic reaction on the cathode, and methane to methanol by surficial catalytic reaction on the anode. The electrochemical reactor futher works with an electrolyte consisting of electrolytic complexes of water-soluable transition metals and small molecules as co-catalyst of the electrocatalytic reactions and facilitator of ionic transfer and solubility of CO.sub.2 and CH.sub.4 molecules in the electrolyte. The electrochemical reactor is further equipped with zero-gap membrane electrocatalytic electrode assemlics, the cathode and anode comprising two electrocatalytic mesoporous surfaces and being tubular and coaxial, delineating two regions, which are separated one from the other by an ion exchange membrane (27). The tubular electrodes pack vertically together, the external gaps being filled by an insulating material. The packed electrodes are electronically connected to the power source in a parallel electrical circuit.

An electrolysis electrode includes a conductive substrate, a catalyst layer and a tantalum oxide layer. The conductive substrate includes at least titanium. The catalyst layer is provided on the conductive substrate. The catalyst layer includes platinum and iridium oxide. The tantalum oxide layer is provided on the catalyst layer. In the electrolysis electrode, the catalyst layer is partially exposed.

An article comprising a first gas distribution layer (100), a first gas dispersion layer (200), or a first electrode layer, having first and second opposed major surfaces and a first adhesive layer having first and second opposed major surfaces, wherein the second major surface (102) of the first gas distribution layer (100), the second major surface (202) of the first gas dispersion layer (200), or the first major surface of the first electrode layer, as applicable, has a central area, wherein the first major surface of the first adhesive layer contacts at least the central area of the second major surface of the first gas distribution layer, the second major surface of the first gas dispersion layer, or the first major surface of the first electrode layer, as applicable, and wherein the first adhesive layer comprises a porous network of first adhesive including a continuous pore network extending between the first and second major surfaces of the first adhesive layer. The articles described herein are useful, for example, in membrane electrode assemblies, unitized electrode assemblies, and electrochemical devices (e.g., fuel cells, redox flow batteries, and electrolyzers).

Provided are an electrochemical catalyst and a preparation method therefor. The preparation method for an electrochemical catalyst may comprise the steps of preparing a base metal aqueous solution containing a base metal, hydrothermally synthesizing a base structure containing an oxide of the base metal by using the base metal aqueous solution, and using a heat treatment method for the base structure in a sulfur (S)-containing reactive gas atmosphere, exchanging oxygen (O) on the surface of the base structure with sulfur (S) of the reactive gas to form a catalyst structure which has a core structure containing the oxide of the base metal and a shell structure containing a sulfide of the base metal.

Provided are an electrochemical catalyst and a preparation method therefor. The preparation method for an electrochemical catalyst may comprise the steps of preparing a base metal aqueous solution containing a base metal, hydrothermally synthesizing a base structure containing an oxide of the base metal by using the base metal aqueous solution, and using a heat treatment method for the base structure in a sulfur (S)-containing reactive gas atmosphere, exchanging oxygen (O) on the surface of the base structure with sulfur (S) of the reactive gas to form a catalyst structure which has a core structure containing the oxide of the base metal and a shell structure containing a sulfide of the base metal.

Electrochemical cells for the oxidation of 5-hydroxymethylfurfural are provided. Also provided are methods of using the cells to carry out the oxidation reactions. The electrochemical cells and methods use catalytic copper-based anodes to carry out the electrochemical oxidation reactions.