Disclosed is a carbon dioxide utilization system capable of recharging and undergoing reactions. The system includes a cathode unit provided with a first aqueous solution accommodated in a first accommodation space, and a cathode at least a part of which is submerged in the first aqueous solution; an anode unit provided with an alkaline second aqueous solution accommodated in a second accommodation space, and a metal anode at least a part of which is submerged in the second aqueous solution; and a connection unit provided with a connection channel connecting the first and second accommodation spaces in open communication, and a porous ion transfer member, disposed in the connection channel, for blocking the movement of the first and second aqueous solutions but allowing the movement of ions.

The present invention relates to an electrochemical method for converting an amino acid and/or its salts to an amine and/or a nitrile. The total yield and selectivity of amine and nitrile obtained by the method according to the present invention is higher than prior art when the reaction medium has a high concentration of amino acid and/or its salts at the beginning of the reaction.

The present invention relates to an electrochemical method for converting an amino acid and/or its salts to an amine and/or a nitrile. The total yield and selectivity of amine and nitrile obtained by the method according to the present invention is higher than prior art when the reaction medium has a high concentration of amino acid and/or its salts at the beginning of the reaction.

Provided are an electrochemical catalyst and a preparation method therefor. The preparation method for an electrochemical catalyst may comprise the steps of preparing a base metal aqueous solution containing a base metal, hydrothermally synthesizing a base structure containing an oxide of the base metal by using the base metal aqueous solution, and using a heat treatment method for the base structure in a sulfur (S)-containing reactive gas atmosphere, exchanging oxygen (O) on the surface of the base structure with sulfur (S) of the reactive gas to form a catalyst structure which has a core structure containing the oxide of the base metal and a shell structure containing a sulfide of the base metal.

Provided are an electrochemical catalyst and a preparation method therefor. The preparation method for an electrochemical catalyst may comprise the steps of preparing a base metal aqueous solution containing a base metal, hydrothermally synthesizing a base structure containing an oxide of the base metal by using the base metal aqueous solution, and using a heat treatment method for the base structure in a sulfur (S)-containing reactive gas atmosphere, exchanging oxygen (O) on the surface of the base structure with sulfur (S) of the reactive gas to form a catalyst structure which has a core structure containing the oxide of the base metal and a shell structure containing a sulfide of the base metal.

A hydrogen ammonia producing device is configured to produce hydrogen and/or ammonia. The hydrogen ammonia producing device includes an electrochemical cell including an electrode assembly and an electrolyte solution. The electrode assembly has a cathode, a separator and an anode that are sequentially stacked with each other. The anode is in contact with urea. The electrolyte solution is an alkaline aqueous solution. At least one of the anode or the cathode is in contact with the electrolyte solution. The separator is an ion exchange membrane.

A hydrogen ammonia producing device is configured to produce hydrogen and/or ammonia. The hydrogen ammonia producing device includes an electrochemical cell including an electrode assembly and an electrolyte solution. The electrode assembly has a cathode, a separator and an anode that are sequentially stacked with each other. The anode is in contact with urea. The electrolyte solution is an alkaline aqueous solution. At least one of the anode or the cathode is in contact with the electrolyte solution. The separator is an ion exchange membrane.

An electrolytic eluent generator includes an electrolyte reservoir and at least one eluent generation cartridge. The electrolyte reservoir includes a chamber containing an aqueous electrolyte solution; and a first electrode. The at least one eluent generation cartridge includes a platinum mesh electrode; a polymer screen; a plurality of reinforced membranes; a membrane washer; and a spacer including a central post and an annular projection.

An electrolytic eluent generator includes an electrolyte reservoir and at least one eluent generation cartridge. The electrolyte reservoir includes a chamber containing an aqueous electrolyte solution; and a first electrode. The at least one eluent generation cartridge includes a platinum mesh electrode; a polymer screen; a plurality of reinforced membranes; a membrane washer; and a spacer including a central post and an annular projection.

An electrode for electrolytic fluorination contains nickel as a base material with a fluorine content<1,000 ppm. Preferably, in at least a surface portion thereof, the nickel content>99 mass %, the iron content≤400 ppm, the copper content<250 ppm, and the manganese content<1,000 ppm. A method for producing an electrode includes arranging a nickel base material electrode in a nickel plating bath as a cathode, and applying nickel plating to the nickel base material electrode by electrolytic nickel plating, the method including (1) using, as an anode, a nickel component deposited on a cathode, or a nickel component that has settled in a molten salt, in a process of producing nitrogen trifluoride by molten salt electrolysis using a nickel base material anode, or the nickel base material anode; or (2) using, as the cathode, the nickel base material anode.