A method of producing graphene sheets from coke or coal powder, comprising: (a) forming an intercalated coke or coal compound by electrochemical intercalation conducted in an intercalation reactor, which contains (i) a liquid solution electrolyte comprising an intercalating agent; (ii) a working electrode that contains the powder in ionic contact with the liquid electrolyte, wherein the coke or coal powder is selected from petroleum coke, coal-derived coke, meso-phase coke, synthetic coke, leonardite, lignite coal, or natural coal mineral powder; and (iii) a counter electrode in ionic contact with the electrolyte, and wherein a current is imposed upon the working electrode and the counter electrode for effecting electrochemical intercalation of the intercalating agent into the powder; and (b) exfoliating and separating graphene planes from the intercalated coke or coal compound using an ultrasonication, thermal shock exposure, mechanical shearing treatment, or a combination thereof to produce isolated graphene sheets.

A method of producing graphene sheets from coke or coal powder, comprising: (a) forming an intercalated coke or coal compound by electrochemical intercalation conducted in an intercalation reactor, which contains (i) a liquid solution electrolyte comprising an intercalating agent; (ii) a working electrode that contains the powder in ionic contact with the liquid electrolyte, wherein the coke or coal powder is selected from petroleum coke, coal-derived coke, meso-phase coke, synthetic coke, leonardite, lignite coal, or natural coal mineral powder; and (iii) a counter electrode in ionic contact with the electrolyte, and wherein a current is imposed upon the working electrode and the counter electrode for effecting electrochemical intercalation of the intercalating agent into the powder; and (b) exfoliating and separating graphene planes from the intercalated coke or coal compound using an ultrasonication, thermal shock exposure, mechanical shearing treatment, or a combination thereof to produce isolated graphene sheets.

A method of producing graphene sheets from coke or coal powder, comprising: (a) forming an intercalated coke or coal compound by electrochemical intercalation conducted in an intercalation reactor, which contains (i) a liquid solution electrolyte comprising an intercalating agent; (ii) a working electrode that contains the powder in ionic contact with the liquid electrolyte, wherein the coke or coal powder is selected from petroleum coke, coal-derived coke, meso-phase coke, synthetic coke, leonardite, lignite coal, or natural coal mineral powder; and (iii) a counter electrode in ionic contact with the electrolyte, and wherein a current is imposed upon the working electrode and the counter electrode for effecting electrochemical intercalation of the intercalating agent into the powder; and (b) exfoliating and separating graphene planes from the intercalated coke or coal compound using an ultrasonication, thermal shock exposure, mechanical shearing treatment, or a combination thereof to produce isolated graphene sheets.

The present invention relates to the electrolytic splitting of water using a carbon-supported manganese oxide (MnO.sub.x) composite. Specifically, the present electrolytic splitting of water is carried under neutral electrolyte conditions with a high electrolytic activity, while using an oxygen evolution reaction (OER)-electrode comprising the present carbon-supported MnO.sub.x composite. Next, the present invention relates to a process for producing such a carbon-supported MnO.sub.x composite as well as to a composite obtainable by the present process for producing the same and to an OER-electrode comprising the carbon-supported MnO.sub.x composite obtainable by the present process.

Photocatalytic device to dissociate an aqueous phase to product hydrogen gas, said device being set up in such a way that at least one photocatalytic system in contact with said aqueous phase can be irradiated by a light source to produce—through an oxidation reaction in said aqueous phase—oxygen gas, electrons and protons at a means of electron capture, said device comprising: a first zone comprising said aqueous phase, and a means for reducing said protons set up to carry out a reduction reaction on said protons by said electrons in order to generate hydrogen gas.
said device being characterised in that said means for proton reduction is a proton exchange interface with a front side facing said means of electron capture, and a back side, with only said back side of said proton exchange interface bearing at least one catalyst and/or at least one catalytic system.

Photocatalytic device to dissociate an aqueous phase to product hydrogen gas, said device being set up in such a way that at least one photocatalytic system in contact with said aqueous phase can be irradiated by a light source to produce—through an oxidation reaction in said aqueous phase—oxygen gas, electrons and protons at a means of electron capture, said device comprising: a first zone comprising said aqueous phase, and a means for reducing said protons set up to carry out a reduction reaction on said protons by said electrons in order to generate hydrogen gas.
said device being characterised in that said means for proton reduction is a proton exchange interface with a front side facing said means of electron capture, and a back side, with only said back side of said proton exchange interface bearing at least one catalyst and/or at least one catalytic system.

A method for oxidizing water including fabricating a working electrode using an electrocatalyst, preparing an electrochemical cell by putting the working electrode, a counter electrode, and a reference electrode in an electrolyte, and performing an oxygen evolution reaction (OER) by applying an electrical potential between the working electrode and the counter electrode. The electrocatalyst includes a nickel-calcium-iron layered double hydroxide (NiCaFe-LDH) nanoparticle, the NiCaFe-LDH nanoparticle has a formula of [Fe.sub.x)NiCa(.sub.1-x](OH).sub.2(NO.sub.3).sub.x.nH.sub.2O, where: 0.2≤x≤0.4 and 0≤n≤2.5.

A method for oxidizing water including fabricating a working electrode using an electrocatalyst, preparing an electrochemical cell by putting the working electrode, a counter electrode, and a reference electrode in an electrolyte, and performing an oxygen evolution reaction (OER) by applying an electrical potential between the working electrode and the counter electrode. The electrocatalyst includes a nickel-calcium-iron layered double hydroxide (NiCaFe-LDH) nanoparticle, the NiCaFe-LDH nanoparticle has a formula of [Fe.sub.x)NiCa(.sub.1-x](OH).sub.2(NO.sub.3).sub.x.nH.sub.2O, where: 0.2≤x≤0.4 and 0≤n≤2.5.

The invention relates to a device, including: a channel including an inlet at a first end of the channel and an outlet at a second end of the channel; a cathode arranged in the channel, which cathode includes a first segment selected from titanium, stainless steel and titanium provided with a mixed metal oxide coating layer including ruthenium oxide and/or iridium oxide and a second segment including carbon, such as a carbon (felt) segment, arranged downstream of the first segment, an anode, arranged in the channel, selected from titanium or, stainless steel and titanium provided with a mixed metal oxide coating layer including ruthenium oxide and/or iridium oxide, which coating layer faces the cathode; and a power source electrically connected to the cathode and the anode. The invention further relates to a method for the production of chlorine dioxide.

The invention relates to a device, including: a channel including an inlet at a first end of the channel and an outlet at a second end of the channel; a cathode arranged in the channel, which cathode includes a first segment selected from titanium, stainless steel and titanium provided with a mixed metal oxide coating layer including ruthenium oxide and/or iridium oxide and a second segment including carbon, such as a carbon (felt) segment, arranged downstream of the first segment, an anode, arranged in the channel, selected from titanium or, stainless steel and titanium provided with a mixed metal oxide coating layer including ruthenium oxide and/or iridium oxide, which coating layer faces the cathode; and a power source electrically connected to the cathode and the anode. The invention further relates to a method for the production of chlorine dioxide.