Methods and systems directed to recovery of lithium (e.g., lithium salts) from liquid streams are provided. In some embodiments, methods relate to obtaining lithium (e.g., as a solid lithium salt) by removing at least a portion of liquid from a feed stream to form a concentrated stream with respect to solubilized lithium cations. Liquid removal may include transporting at least a portion of the feed stream to an osmotic unit and/or a humidifier. Some methods include removing impurities (e.g., non-lithium cations) from the concentrated stream (e.g., via precipitation and/or crystallization). In some embodiments, solutions containing solubilized lithium cations and anions are electrochemically-treated such that first solubilized anions are replaced with second, different anions. In some embodiments, solid lithium salt containing at least a portion of the lithium cations and the second anions is obtained (e.g., via precipitation and/or crystallization following concentration of the electrochemically-treated solution in a humidifier).

A process for the separation of electrolyte from the carbon in a solid carbon/electrolyte cathode product formed at the cathode during molten carbonate electrolysis. The processes allow for easy separation of the solid carbon product from the electrolyte without any observed detrimental effect on the structure and/or stability of the resulting solid carbon nanomaterial.

Methods and systems for production of lithium hydroxide and lithium carbonate are described. One or more embodiments of the method include producing lithium hydroxide from potassium chloride, lithium chloride, and water. One or more embodiments of the method include producing lithium carbonate from potassium chloride, lithium chloride, water, and a carbon dioxide source. One or more embodiments of the method include producing lithium carbonate from sodium chloride, lithium chloride, water, and a carbon dioxide source.

The method for operating a water electrolysis device for generating hydrogen and oxygen from water has a PEM electrolyser (1), to which water for generating the hydrogen and the oxygen is supplied together with water for cooling. The cooling water is conducted in the circuit and treated by means of an ion exchanger unit (17). Only part of the water conducted in the circuit is supplied to the ion exchanger unit (17) and another part is supplied to the PEM electrolyser (1) via a bypass (13) circumventing the ion exchanger unit (17).

A compressor for a solid oxide electrolyzer cell (SOEC) system, the system including one or more stamps that receives hydrogen input and outputs wet hydrogen, a heat exchanger or condenser that is configured to decrease the temperature of the wet hydrogen, a compressor that is configured to increase the pressure of the wet hydrogen, and a dryer that is configured to reduce the dew point of the wet hydrogen.

An electrolysis system and an electrolysis method wherein the electrolysis system includes a pressure-electrolytic cell and a throttle in the catholyte line, by which the catholyte flow can be divided into a gas and liquid phase. In this way, (by-)products of the electrolysis can be recycled, while the electrolytic cell can be operated effectively at a high pressure.

An electrolytic reaction system for generating gaseous hydrogen and oxygen includes a reaction chamber for accommodating an electrolyte as well as an electrode arrangement, which is formed of anodic and cathodic electrodes. Between lateral surfaces of electrodes arranged to be spaced apart from one another, at least one flow channel for the electrolyte is formed, which extends between a first axial end for admitting the electrolyte into the electrode arrangement and a second axial end for discharging the electrolyte out of the electrode arrangement. The at least one flow channel has at least one first flow cross-section and at least one second flow cross-section, wherein the second flow cross-section has a smaller size than the first flow channel, and the comparatively smaller second flow cross-section is formed in a partial section of the at least one flow channel closest to the second axial end of the electrode arrangement.

A power-to-X system for the utilization of off-gases, includes an electrolyzer for generating hydrogen H2 and oxygen O2, a unit, connected to the electrolyzer, for processing the hydrogen H2, for removing any remaining water H2O and oxygen O2 from the generated stream of hydrogen H2, a compressor, connected to the unit for processing the hydrogen H2, for compressing the hydrogen H2, and a chemical reactor, connected to the compressor, for producing a synthesis gas consisting of hydrogen H2 and carbon dioxide CO2 that can be added. An oxy-fuel combustion system to which non-condensable off-gases from the chemical reactor and oxygen O2 from the electrolyzer can be supplied, and carbon dioxide CO2 generated during the combustion of the off-gases in the oxy-fuel combustion system can be returned to the stream of hydrogen H2 downstream of the electrolyzer via a return line.

One aspect of the present invention provides a sodium hypochlorite producing system, which includes: a first means configured to obtain saturated salt water and purified water; a second means including a anode chamber and a cathode chamber which are partitioned by a separator, the anode chamber allowing the saturated salt water to be converted into a anodic product including chlorine gas and anodic water, and the cathode chamber allowing the purified water to be converted into a cathodic product including sodium hydroxide, hydrogen gas, and hydroxide ions (OH.sup.−); a third means configured to react the anodic product and the cathodic product to produce a mixture including sodium hypochlorite and hydrogen gas; and a fourth means configured to prevent the sodium hydroxide or hydroxide ions (OH.sup.−) of the cathodic product or a combination thereof from moving to the anode chamber through the separator.

An electrolyzer system including a hotbox, one or more stacks disposed within the hotbox, a fuel exhaust conduit that receives fuel exhaust output by the stack, a fuel exhaust separator that separates liquid from the fuel exhaust, and a recycling conduit that fluidly connects the fuel exhaust to the fuel inlet conduit.