D06M13/328

REINFORCING FIBER BUNDLE AND CARBON FIBER REINFORCED THERMOPLASTIC RESIN MOLDED BODY USING THE SAME, AND METHOD FOR PRODUCING REINFORCING FIBER BUNDLE

Disclosed are a reinforcing fiber bundle composed of a carbon fiber bundle treated with an emulsion; a carbon fiber reinforced thermoplastic resin molded body using the same; and a method for producing a reinforcing fiber bundle; wherein the emulsion contains a modified polyolefin (A1) comprising at least a metal carboxylate bonded to the polymer chain, and 0.1 to 5,000 moles of an amine compound (B) represented by the following general formula (1), per one mole of the carboxylate group in the modified polyolefin (A1);


R—NH.sub.2  (1) wherein the formula (1), R is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.

SIZING-AGENT-COATED CARBON FIBER BUNDLE AND METHOD FOR MANUFACTURING SAME

[Problem] To provide a sizing-agent-coated carbon fiber bundle in which, even when the sizing-agent-coated carbon fiber bundle has superior handling properties, the sizing agent on the sizing-agent-coated carbon fiber bundle exhibits excellent solubility in water and the adhesion amount of remaining sizing agent is reduced. [Solution] A sizing-agent-coated carbon fiber bundle obtained by applying polyethylene glycol and/or a surfactant to a carbon fiber bundle as a sizing agent, wherein all of the following conditions (i)-(iii) are satisfied. (i) The adhesion amount of the sizing agent is 0.15-0.80 parts by mass (inclusive) per 100 mass parts of the sizing-agent-coated carbon fiber bundle 100. (ii) The dry F-F friction coefficient is 0.39 or less. (iii) The adhesion amount of the sizing agent after washing for 50 seconds under the conditions disclosed in the specification is 0.12 parts by mass or less per 100 parts by mass of the sizing-agent-coated carbon fiber bundle 100.

SIZING-AGENT-COATED CARBON FIBER BUNDLE AND METHOD FOR MANUFACTURING SAME

[Problem] To provide a sizing-agent-coated carbon fiber bundle in which, even when the sizing-agent-coated carbon fiber bundle has superior handling properties, the sizing agent on the sizing-agent-coated carbon fiber bundle exhibits excellent solubility in water and the adhesion amount of remaining sizing agent is reduced. [Solution] A sizing-agent-coated carbon fiber bundle obtained by applying polyethylene glycol and/or a surfactant to a carbon fiber bundle as a sizing agent, wherein all of the following conditions (i)-(iii) are satisfied. (i) The adhesion amount of the sizing agent is 0.15-0.80 parts by mass (inclusive) per 100 mass parts of the sizing-agent-coated carbon fiber bundle 100. (ii) The dry F-F friction coefficient is 0.39 or less. (iii) The adhesion amount of the sizing agent after washing for 50 seconds under the conditions disclosed in the specification is 0.12 parts by mass or less per 100 parts by mass of the sizing-agent-coated carbon fiber bundle 100.

AQUEOUS BINDER FOR INORGANIC FIBER HEAT-INSULATING AND SOUND-ABSORBING MATERIAL AND INORGANIC FIBER HEAT-INSULATING AND SOUND-ABSORBING MATERIAL
20230034982 · 2023-02-02 · ·

The present invention relates to an aqueous binder for a heat-insulating and sound-absorbing inorganic fiber material, the aqueous binder comprising a polymer having a carboxy group and a crosslinking agent for the polymer, wherein the crosslinking agent comprises an alkanol monoamine and a polyamine having an imino group, the polyamine has an amine value of 1200 to 1650 mg KOH/g, and a ratio of the total number of moles of amino groups and imino groups in the crosslinking agent with respect to the total number of moles of hydroxyl groups, amino groups, and imino groups in the crosslinking agent is 0.6 or less.

CELLULOSE FIBER COMPOSITE

The invention relates to [1] a cellulose fiber composite excellent in dispersion stability, in which at least one amine selected from a polyamine and a monoamine having a reactive functional group bonds to anion-modified cellulose fibers, and which satisfies at least one of amine introduction ratio of 60% or less (requirement 1) and average polymerization degree of anion-modified cellulose fibers of 300 or less (requirement 2), [2] a dispersion in which the cellulose fiber composite is dispersed in a medium, [3] a resin composition produced by blending the cellulose fiber composite and a resin, [4] a molded article produced by molding the cellulose fiber composite or the resin composition, and [5] a method for producing the cellulose fiber composite.

Method for manufacturing a dye scavenging substrate

A method for manufacturing a dye scavenging substrate which comprises the steps of: (a) providing an absorbent substrate; (b) passing the substrate through a bath containing an alkaline solution of a dye scavenging compound selected from: (i) a N-trisubstituted ammonium-2-hydroxy-3-halopropyl compound having the general formula (I), or (ii) a salt of epoxy propyl ammonium having the general formula (II), or a combination thereof; (c) subjecting the substrate to a pressure of from about 0.04 MPa to about 0.40 MPa; (d) wrapping the substrate in a water impermeable material and rotating the substrate for a period of from about 12 hours to about 60 hours; (e) removing the water impermeable material and passing the substrate through a bath containing an acid solution; (f) subjecting the substrate to a pressure of from about 0.15 MPa to about 0.40 MPa; and (g) drying the substrate.

FIBER SIZING AGENT COMPOSITION, FIBER SIZING AGENT DISPERSION, FIBER SIZING AGENT SOLUTION, METHOD FOR PRODUCING FIBER BUNDLES, COMPOSITE INTERMEDIATE AND FIBER-REINFORCED COMPOSITE MATERIAL
20170284015 · 2017-10-05 · ·

The present invention provides a fiber sizing agent composition containing a polyester resin (A) and a reactive compound (B), wherein the polyester resin (A) is a polyester resin having an HLB of 4 to 18 and a viscosity at 30° C. of 10 to 1,000,000 Pa.Math.s, the reactive compound (B) is at least one reactive compound selected from the group consisting of blocked isocyanates, tertiary amines, tertiary amine salts, quaternary ammonium salts, quaternary phosphonium salts, and phosphine compounds, and the weight ratio of the polyester resin (A) to the reactive compound (B) [(A)/(B)] in the fiber sizing agent composition is 99.9/0.1 to 10/90.

FIBER SIZING AGENT COMPOSITION, FIBER SIZING AGENT DISPERSION, FIBER SIZING AGENT SOLUTION, METHOD FOR PRODUCING FIBER BUNDLES, COMPOSITE INTERMEDIATE AND FIBER-REINFORCED COMPOSITE MATERIAL
20170284015 · 2017-10-05 · ·

The present invention provides a fiber sizing agent composition containing a polyester resin (A) and a reactive compound (B), wherein the polyester resin (A) is a polyester resin having an HLB of 4 to 18 and a viscosity at 30° C. of 10 to 1,000,000 Pa.Math.s, the reactive compound (B) is at least one reactive compound selected from the group consisting of blocked isocyanates, tertiary amines, tertiary amine salts, quaternary ammonium salts, quaternary phosphonium salts, and phosphine compounds, and the weight ratio of the polyester resin (A) to the reactive compound (B) [(A)/(B)] in the fiber sizing agent composition is 99.9/0.1 to 10/90.

Electrochemical grafting of carbon fibers with aliphatic amines for improved composite strength

The surface of a carbon fiber is electrochemically treated by a method to form nitrogen containing groups on the surface of the carbon fiber. The method comprises contacting a carbon fiber surface with an aqueous solution comprised of a non-cyclic aliphatic amine and water soluble inorganic hydroxide with said aqueous solution having a pH of at least 9. A positive electrical bias is then applied to the carbon fibers in the aqueous solution relative to another electrode in contact with the aqueous solution, wherein the positive electrical bias is at a voltage above the oxidation potential of water. The treated carbon fibers are useful for making epoxy reinforced carbon fiber composites.

Electrochemical grafting of carbon fibers with aliphatic amines for improved composite strength

The surface of a carbon fiber is electrochemically treated by a method to form nitrogen containing groups on the surface of the carbon fiber. The method comprises contacting a carbon fiber surface with an aqueous solution comprised of a non-cyclic aliphatic amine and water soluble inorganic hydroxide with said aqueous solution having a pH of at least 9. A positive electrical bias is then applied to the carbon fibers in the aqueous solution relative to another electrode in contact with the aqueous solution, wherein the positive electrical bias is at a voltage above the oxidation potential of water. The treated carbon fibers are useful for making epoxy reinforced carbon fiber composites.