Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

Solid-state branching and/or crosslinking of aliphatic polyamide or polyester articles is achieved using a topical approach. A surface of the article is coated with a composition that includes a polyene and a free radical initiator. The article and applied coating are then heated to induce branching and/or crosslinking in the polyamide or polyester. This is performed below the crystalline melting temperature of the polyamide or polyester, or in the case of a fabric, below the melting temperature of the fibers in the fabric. Fabrics treated in this manner exhibit reduced or even no dripping in vertical flame tests.

The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.

The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.

The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.

The invention relates to novel and improved halogen-free flame retardant compounds having the structure of Formula (I): wherein: R.sup.1 and R.sup.2 are independently hydrogen, C.sub.1-C.sub.6 alkyl, P(O)(OR.sup.3).sub.2, P(O)OR.sup.3R.sup.4, or P(O)R.sup.3.sub.2, wherein R.sup.3 and R.sup.4 are independently C.sub.1-C.sub.4 alkyl, C.sub.6-C.sub.12 aryl, C.sub.7-C.sub.15 aralkyl or C.sub.7-C.sub.15 alkaryl; or R.sup.1 and R.sup.2 taken together form an unsaturated cyclic ring, which is optionally substituted by an alkyl group; each k is independently an integer from 1 to 2; each X is independently oxygen (O) or sulphur (S); v is 0 or 1; each Y is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene, C.sub.7-C.sub.15 alkarylene, oxygen (O), nitrogen (NR), wherein R is H or C.sub.1-C.sub.4 alkyl; n is 0, 1 or 2 with the proviso that n is 1 when Y is oxygen (O) or nitrogen (NR); each Z is independently C.sub.1-C.sub.4 alkylene, C.sub.6 arylene, C.sub.7-C.sub.15 aralkylene or C.sub.7-C.sub.15 is alkarylene; m is independently 0, 1 or 2; with the proviso that when Y is oxygen (O) or nitrogen (N), m cannot be 0; each Q is independently C.sub.1-C.sub.4 alkylene; t is an integer from 1 to 2; W is oxygen (O) or sulphur (S). The compounds are particularly suited as flame retardant additives for thermoplastic polyesters.