A dye mixture comprising at least one dye of formula (formula) and at least one dye of formula (formula), wherein R.sub.1 is hydrogen or C.sub.1-C.sub.4alkyl, R.sub.2 is hydrogen or C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.4alkoxy or sulfo, Q.sub.1 is a fibre-reactive radical of formula —(CH.sub.2).sub.2-3—SO.sub.2—Y.sub.2 (3a) or —(CH.sub.2).sub.2-3—O—(CH.sub.2).sub.2-3—SO.sub.2—Y.sub.3 (3b), Q.sub.2 has the meaning of Q.sub.1, or is hydrogen or C.sub.1-C.sub.4alkyl, X.sub.1 and X.sub.2 are each independently of the other halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y.sub.1, Y.sub.2 and Y.sub.3 are each independently of the others vinyl or a radical —CH.sub.2—CH.sub.2—U and U is a group removable under alkaline conditions, Z.sub.1 and Z.sub.2 are each independently of the other —S0.sub.2-Y, wherein Y is vinyl or a radical —CH.sub.2—CH.sub.2—U and U is a group removable under alkaline conditions, M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, k and n are each independently of the other the number 0, 1 or 2, I and q are each independently of the other the number 0 or 1, m is the number 0 or 1, and wherein the diazo component of the dye of formula (1) and the diazo component of the dye of formula (2) each independently of the other are a benzene radical or a naphthyl radical, are suitable especially for the dyeing or printing of cellulosic fibre materials, exhibit a good build-up, a good fixation rate and good washing off properties of the unfixed dyes, and good all-round fastness properties.

##STR00001##

A dye mixture comprising at least one dye of formula (formula) and at least one dye of formula (formula), wherein R.sub.1 is hydrogen or C.sub.1-C.sub.4alkyl, R.sub.2 is hydrogen or C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.4alkoxy or sulfo, Q.sub.1 is a fibre-reactive radical of formula —(CH.sub.2).sub.2-3—SO.sub.2—Y.sub.2 (3a) or —(CH.sub.2).sub.2-3—O—(CH.sub.2).sub.2-3—SO.sub.2—Y.sub.3 (3b), Q.sub.2 has the meaning of Q.sub.1, or is hydrogen or C.sub.1-C.sub.4alkyl, X.sub.1 and X.sub.2 are each independently of the other halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y.sub.1, Y.sub.2 and Y.sub.3 are each independently of the others vinyl or a radical —CH.sub.2—CH.sub.2—U and U is a group removable under alkaline conditions, Z.sub.1 and Z.sub.2 are each independently of the other —S0.sub.2-Y, wherein Y is vinyl or a radical —CH.sub.2—CH.sub.2—U and U is a group removable under alkaline conditions, M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, k and n are each independently of the other the number 0, 1 or 2, I and q are each independently of the other the number 0 or 1, m is the number 0 or 1, and wherein the diazo component of the dye of formula (1) and the diazo component of the dye of formula (2) each independently of the other are a benzene radical or a naphthyl radical, are suitable especially for the dyeing or printing of cellulosic fibre materials, exhibit a good build-up, a good fixation rate and good washing off properties of the unfixed dyes, and good all-round fastness properties.

##STR00001##

An ink jet textile printing ink composition according to the invention contains Li.sup.+, Na.sup.+, and a compound represented by the following formula (1):

##STR00001##

An ink jet textile printing ink composition according to the invention contains Li.sup.+, Na.sup.+, and a compound represented by the following formula (1):

##STR00001##

An ink jet ink composition for textile printing including a dye and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 15 to 80 degrees.

An ink jet ink composition for textile printing including a dye and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 15 to 80 degrees.

The present invention pertains to an aqueous ink containing mixtures of solvent dyes and disperse dyes suitable for printing on hydrophobic textile substrates.

The present invention pertains to an aqueous ink containing mixtures of solvent dyes and disperse dyes suitable for printing on hydrophobic textile substrates.

Disclosed are reactive dyes and preparation methods thereof. The reactive dye may be prepared using heterocyclic primary amine as a diazo component, 4,4-diamino-2,2-stilbenedisulfonic acid, s-triazine, or ethylenediamine as a bridging group, and a dimonochlortriazine group as an active group. The color-changing compound is covalently bonded into the fiber chemical structure by nucleophilic substitution reaction between monochlorotriazine and the hydroxyl group in a textile structure, and the size of the conjugated system and the range of electron delocalization of the dye are changed by a reversible isomerization reaction of the hydroxyl group adjacent to the diazo group and the diazo group under different pH regulations. Moreover, the dye has a double color changing structure, which improves the capability of the dye combined with H/OH. The pH value range that can cause color changes in the dye is effectively expanded to include weak alkali, weak acid or even neutral conditions.

Disclosed are reactive dyes and preparation methods thereof. The reactive dye may be prepared using heterocyclic primary amine as a diazo component, 4,4-diamino-2,2-stilbenedisulfonic acid, s-triazine, or ethylenediamine as a bridging group, and a dimonochlortriazine group as an active group. The color-changing compound is covalently bonded into the fiber chemical structure by nucleophilic substitution reaction between monochlorotriazine and the hydroxyl group in a textile structure, and the size of the conjugated system and the range of electron delocalization of the dye are changed by a reversible isomerization reaction of the hydroxyl group adjacent to the diazo group and the diazo group under different pH regulations. Moreover, the dye has a double color changing structure, which improves the capability of the dye combined with H/OH. The pH value range that can cause color changes in the dye is effectively expanded to include weak alkali, weak acid or even neutral conditions.