The present disclosure provides a polyamide 5X staple fiber, a preparation method and use thereof. The polyamide 5X staple fiber has a denier of 8.0-30.0D, a breaking strength of 2.0-6.0 cN/dtex, and an elongation at break of 30-100%. The polyamide 5X staple fiber has good mechanical properties and softness, and a blended wool yarn for manufacturing carpets with good mechanical properties, dyeability, and wear resistance can be obtained by using the polyamide 5X staple fiber.

An ink jet textile printing ink composition contains a sulfonic acid group-containing dye having a ligand coordinated to a metal atom, the ligand being represented by Formula (1) below: ##STR00001## wherein at least one of R.sub.1 and R.sub.3 represents SO.sub.3.sup.− or SO.sub.3Y, where Y represents a hydrogen atom, an alkali metal atom, or an alkaline earth metal atom; when not representing SO.sub.3.sup.− or SO.sub.3Y, R.sub.1 and R.sub.3 represent a halogen atom or a hydrogen atom; R.sub.2 and R.sub.4 each independently represent a hydrogen atom, a halogen atom, a sulfo group, a nitro group, an aryl group, a sulfonamide group, a carboxy group, an alkyl group of 1 to 4 carbon atoms, SO.sub.2NHR.sub.5, or COOR.sub.5, where R.sub.5 represents a hydrogen atom or an alkyl group; and X represents a metal atom.

A textile dyeing process is described for dyeing a textile material, product or article consisting of animal fibers, comprising the steps of dipping said textile material, product or article into a dyeing bath comprising at least one detergent substance, a wetting substance, a leveling substance and an acidity regulator; adding to the dyeing bath a coloring substance approved for food use; subjecting the dyed textile material, product or article to washes; and finally subjecting the dyed textile material, product or article to a color fixing treatment.

According to the invention there is provided a method of treating textile fibers including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R.sup.2 and R.sup.3 are independently selected from (CR.sup.7R.sup.8).sub.n, or a group CR.sup.9R.sup.10, CR.sup.7R.sup.8CR.sup.9R.sup.10 or CR.sup.9R.sup.10CR.sup.7R.sup.8 where n is 0, 1 or 2, R.sup.7 and R.sup.8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R.sup.9 or R.sup.10 is hydrogen and the other is an electron withdrawing group, or R.sup.9 and R.sup.10 together form an electron withdrawing group, and R.sup.4 and R.sup.5 are independently selected from CH or CR.sup.11 where R.sup.11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X.sup.1 is a group CX.sup.2X.sup.3 where the dotted line bond to which it is attached is absent and a group CX.sup.2 where the dotted line bond to which it is attached is present, Y.sup.1 is a group CY.sup.2Y.sup.3 where the dotted line bond to which it is attached is absent and a group CY.sup.2 where the dotted line bond to which it is attached is present, and X.sup.2, X.sup.3, Y.sup.2 and Y.sup.3 are independently selected from hydrogen, fluorine or other substituents, R.sup.1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R.sup.3-R.sup.5≡Y.sup.1, and R.sup.13 is C(O) or S(O).sub.2; coating the textile fibers with the polymeric precursor; and polymerizing the polymeric precursor so as to produce a polymeric coating on the textile fibers. ##STR00001##

According to the invention there is provided a method of treating textile fibers including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R.sup.2 and R.sup.3 are independently selected from (CR.sup.7R.sup.8).sub.n, or a group CR.sup.9R.sup.10, CR.sup.7R.sup.8CR.sup.9R.sup.10 or CR.sup.9R.sup.10CR.sup.7R.sup.8 where n is 0, 1 or 2, R.sup.7 and R.sup.8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R.sup.9 or R.sup.10 is hydrogen and the other is an electron withdrawing group, or R.sup.9 and R.sup.10 together form an electron withdrawing group, and R.sup.4 and R.sup.5 are independently selected from CH or CR.sup.11 where R.sup.11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X.sup.1 is a group CX.sup.2X.sup.3 where the dotted line bond to which it is attached is absent and a group CX.sup.2 where the dotted line bond to which it is attached is present, Y.sup.1 is a group CY.sup.2Y.sup.3 where the dotted line bond to which it is attached is absent and a group CY.sup.2 where the dotted line bond to which it is attached is present, and X.sup.2, X.sup.3, Y.sup.2 and Y.sup.3 are independently selected from hydrogen, fluorine or other substituents, R.sup.1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R.sup.3-R.sup.5≡Y.sup.1, and R.sup.13 is C(O) or S(O).sub.2; coating the textile fibers with the polymeric precursor; and polymerizing the polymeric precursor so as to produce a polymeric coating on the textile fibers. ##STR00001##

An ink jet recording method performed on a fabric to which a hydrotropic agent is attached includes attaching an ink jet composition for textile printing including a metal complex salt dye, in which a hue angle ∠h° defined in CIELAB color space on printed textiles after printing is in a range of 260° or more and 310° or less, to the fabric using an ink jet method, in which there is a region in which a value of a ratio of a mass of the metal complex salt dye with respect to a total mass of dyes included in the ink jet composition for textile printing is 0.6 or more and 1.0 or less, and a value of a ratio of mass of the metal complex salt dye with respect to a mass of the hydrotropic agent in the fabric is 0.2 or more and 1.0 or less.

An ink jet recording method performed on a fabric to which a hydrotropic agent is attached includes attaching an ink jet composition for textile printing including a metal complex salt dye, in which a hue angle ∠h° defined in CIELAB color space on printed textiles after printing is in a range of 260° or more and 310° or less, to the fabric using an ink jet method, in which there is a region in which a value of a ratio of a mass of the metal complex salt dye with respect to a total mass of dyes included in the ink jet composition for textile printing is 0.6 or more and 1.0 or less, and a value of a ratio of mass of the metal complex salt dye with respect to a mass of the hydrotropic agent in the fabric is 0.2 or more and 1.0 or less.

Dyes of formula (1) ##STR00001##
their production and their use are described.

Dyes of formula (1) ##STR00001##
their production and their use are described.

Dye(s) of formula (I) ##STR00001##
process for their production and their use are described.