A fabric treatment agent that is used in textile printing with a sublimable color material includes a color-material scavenging compound having an Rf value of 0.7 or less according to paper chromatography performed under following conditions. In Procedure 1, cellulose filter paper is impregnated with a 10% solution of the color-material scavenging compound and then dried to prepare a carrier. In Procedure 2, a 0.1% solution of a sublimable color material in tetrahydrofuran is spotted on the carrier and then dried to prepare a development sample. In Procedure 3, the development sample is developed using acetonitrile as a solvent for 3 minutes at 25° C. In Procedure 4, the Rf value is calculated by a following formula:

[00001]$Rf=\frac{\left(\mathrm{distance}\mathrm{travelled}\mathrm{by}\mathrm{the}\mathrm{sublimable}\mathrm{color}\mathrm{material}\right)}{\left(\mathrm{distance}\mathrm{travelled}\mathrm{by}\mathrm{acetonitrile}\right)}.$

Provided are a textile printing ink set including a pretreatment liquid including a quaternary ammonium cation having a molecular weight of 3000 or less, and an ink composition including a water-insoluble dye, a dispersing agent, and water, wherein a content of the quaternary ammonium cation relative to a total amount of the pretreatment liquid is 5 mass % to 20 mass %; and a textile printing method.

Provided are pretreatment compositions, pretreated fabrics, and methods of pretreating fabrics for improved printing quality. Pretreated fabrics include natural fiber fabric having a polymer coating. Methods of pretreating fabrics include spraying natural fiber fabric with a pretreatment composition that comprises one or more latex polymers, a coalescing agent composition, a surfactant composition, an ultraviolet stabilizer composition, an antioxidant composition, and a solvent.

Provided are pretreatment compositions, pretreated fabrics, and methods of pretreating fabrics for improved printing quality. Pretreated fabrics include natural fiber fabric having a polymer coating. Methods of pretreating fabrics include spraying natural fiber fabric with a pretreatment composition that comprises one or more latex polymers, a coalescing agent composition, a surfactant composition, an ultraviolet stabilizer composition, an antioxidant composition, and a solvent.

A fabric treatment agent that is used in textile printing with a sublimable color material includes a color-material scavenging compound having an Rf value of 0.7 or less according to paper chromatography performed under following conditions. In Procedure 1, cellulose filter paper is impregnated with a 10% solution of the color-material scavenging compound and then dried to prepare a carrier. In Procedure 2, a 0.1% solution of a sublimable color material in tetrahydrofuran is spotted on the carrier and then dried to prepare a development sample. In Procedure 3, the development sample is developed using acetonitrile as a solvent for 3 minutes at 25 C. In Procedure 4, the Rf value is calculated by a following formula: $Rf=\frac{\left(\mathrm{distance}\mathrm{travelled}\mathrm{by}\mathrm{the}\mathrm{sublimable}\mathrm{color}\mathrm{material}\right)}{\left(\mathrm{distance}\mathrm{travelled}\mathrm{by}\mathrm{acetonitrile}\right)}.$

A compound of formula ##STR00001##
wherein V, W, X and Y represent N or CH, at least one of V, W, X and Y being N and at least two of V, W, X and Y being CH; R.sub.1, R.sub.2 and R.sub.3 are each independently of the other hydrogen, C.sub.1-C.sub.8 alkyl, C.sub.1-C.sub.8 alkoxy, nitro, cyano, trifluoromethyl, halogen or hydroxy; and the compound provides good lightfastness properties to textile fibre materials, in particular PES fibre materials.

Provided are a textile printing ink set including a pretreatment liquid including a quaternary ammonium cation having a molecular weight of 3000 or less, and an ink composition including a water-insoluble dye, a dispersing agent, and water, wherein a content of the quaternary ammonium cation relative to a total amount of the pretreatment liquid is 5 mass % to 20 mass %; and a textile printing method.