A method includes disposing a device into a borehole in proximity to a subterranean formation where a filter cake has been formed adjacent thereto, the device comprising a support structure and a shape-memory article disposed at the support structure, the shape-memory article comprising a shape-memory polymer, wherein the device is disposed when the shape-memory article is in a compacted shape; exposing the shape-memory article to a fluid system to cause the shape-memory article to expand and conform to a surface of the borehole; exposing the filter cake to the fluid system; and removing the filter cake with the fluid system. The fluid system comprises (i) an acid component, a chelating agent, or a combination thereof; (ii) an activator, (iii) a viscosifier, (iv) water or a brine, and (v) optionally a surfactant.

Methods for the in-situ application of coating agent to production tubing within wellbores using plunger lift systems are provided herein. One method includes shutting in the wellbore, pressurizing the production tubing to displace fluids from the production tubing, and dropping a plunger from the surface into the production tubing such that the plunger travels toward the bottom of the production tubing until landing on a bumper spring. The method also includes pumping a predetermined amount of the coating agent from the surface into the production tubing such that the coating agent flows to the bottom of the production tubing and settles on top of the plunger and utilizing the differential pressure between the production tubing and the annulus to return the plunger and the coating agent to the surface, where the coating agent is applied to the inner diameter of the production tubing as it flows toward the surface.

A chemical stick launcher includes a stack of vertically mounted low voltage electrically operated valves providing spaces between the valves for chemical sticks. The valves are manipulated by a controller to drop sticks from the compartments between the valves after suitable time delays so the launcher can supply chemicals to a hydrocarbon well over a period of time. The stack is insulated to reduce the operating temperature of the launcher and thereby allow a wider variety of chemical compositions to be used. The low voltage electrically operated valves include a front panel providing a visual indicator of whether the valves are open or closed. The valves are mounted on the stack so the front panels face in the same direction so a standing person can see all the indicators from a single position.

A flexible pipe connector for effecting control and forced circulation of corrosion-inhibiting fluids through an annulus between inner and outer sheaths of a flexible pipe having multiple connected segments includes an attachment mechanism for connecting to an end of a segment of flexible pipe and at least two distributing rings for distributing corrosion-inhibiting fluid. The rings are configured to be positioned in the annulus of the flexible pipe, wherein at least one distributing ring has fluidic access to the annulus of the flexible pipe. This distributing ring is configured to be connected fluidically to at least one distributing ring, in an adjacent connector, that does not have fluidic access to the annulus, A distributing ring that does not have fluidic access to the annulus of the flexible pipe is configured to be connected fluidically to at least one distributing ring, in an adjacent connector, that comprises fluidic access to the annulus.

A flexible pipe connector for effecting control and forced circulation of corrosion-inhibiting fluids through an annulus between inner and outer sheaths of a flexible pipe having multiple connected segments includes an attachment mechanism for connecting to an end of a segment of flexible pipe and at least two distributing rings for distributing corrosion-inhibiting fluid. The rings are configured to be positioned in the annulus of the flexible pipe, wherein at least one distributing ring has fluidic access to the annulus of the flexible pipe. This distributing ring is configured to be connected fluidically to at least one distributing ring, in an adjacent connector, that does not have fluidic access to the annulus, A distributing ring that does not have fluidic access to the annulus of the flexible pipe is configured to be connected fluidically to at least one distributing ring, in an adjacent connector, that comprises fluidic access to the annulus.

The subject invention provides compositions and methods for simultaneously enhancing oil recovery, improving the quality of oil and gas through reduction in sulfur-containing compounds, and preventing and/or reducing corrosion of oil and gas production equipment. A multi-functional composition is provided comprising an antimicrobial biosurfactant component, a first ammonium salt, and ammonium hydroxide. In some embodiments, the efficiency of the composition is further enhanced by the addition of a chelating agent, a phenol (e.g., carbolic acid or phenolic acid), and/or an H.sub.2S scavenger. In some embodiments, the composition is further enhanced for use in cold climates by the addition of an antifreeze mixture comprising one or more of a second ammonium salt, sodium chloride and glycerol.

The subject invention provides compositions and methods for simultaneously enhancing oil recovery, improving the quality of oil and gas through reduction in sulfur-containing compounds, and preventing and/or reducing corrosion of oil and gas production equipment. A multi-functional composition is provided comprising an antimicrobial biosurfactant component, a first ammonium salt, and ammonium hydroxide. In some embodiments, the efficiency of the composition is further enhanced by the addition of a chelating agent, a phenol (e.g., carbolic acid or phenolic acid), and/or an H.sub.2S scavenger. In some embodiments, the composition is further enhanced for use in cold climates by the addition of an antifreeze mixture comprising one or more of a second ammonium salt, sodium chloride and glycerol.

This disclosure relates to acidizing retarder compositions and methods of reducing the rate of carbonate dissolution in carbonate acidizing treatments of carbonate formations using the acidizing retarder compositions. The methods may include dissolving one or more retarder compounds in a solution comprising a strong acid to form acidizing retarder compositions, and introducing the acidizing retarder compositions to carbonate formations. The acidizing retarder compositions may include one or more retarder compounds and a strong acid. At least one of the one or more retarder compounds may be a poloxamer. A concentration of the strong acid in the acidizing retarder composition may be 5 weight percent or greater.

This disclosure relates to acidizing retarder compositions and methods of reducing the rate of carbonate dissolution in carbonate acidizing treatments of carbonate formations using the acidizing retarder compositions. The methods may include dissolving one or more retarder compounds in a solution comprising a strong acid to form acidizing retarder compositions, and introducing the acidizing retarder compositions to carbonate formations. The acidizing retarder compositions may include one or more retarder compounds and a strong acid. At least one of the one or more retarder compounds may be a poloxamer. A concentration of the strong acid in the acidizing retarder composition may be 5 weight percent or greater.

Described herein are aqueous composition(s) containing water; a viscoelastic surfactant; an acid; and a water-soluble acid retarding agent. Further described are methods of making and using such compositions.