Patent classifications
F25J1/001
Active magnetic regenerative processes and systems employing hydrogen as heat transfer fluid and process
A system including: an active magnetic regenerative refrigerator apparatus that includes a high magnetic field section in which a hydrogen heat transfer fluid can flow from a cold side to a hot side through at least one magnetized bed of at least one magnetic refrigerant, and a low magnetic field or demagnetized section in which the hydrogen heat transfer fluid can flow from a hot side to a cold side through the demagnetized bed; a first conduit fluidly coupled between the cold side of the low magnetic field or demagnetized section and the cold side of the high magnetic field section; and a second conduit fluid coupled to the first conduit, an expander and at least one liquefied hydrogen storage module.
METHOD FOR LARGE HYDROGEN LIQUEFACTION SYSTEM
A method for the liquefaction of hydrogen is provided. The can include the steps of: precooling a hydrogen feed stream in a precooling cold box having a heat exchanger disposed therein to form a cooled hydrogen stream, wherein the heat exchanger is configured to cool down the feed stream within the precooling cold box by indirect heat exchange between the hydrogen feed stream and a precooling refrigerant; and withdrawing the cooled hydrogen stream from the precooling cold box; introducing the cooled hydrogen stream to a plurality of liquefaction cold boxes, wherein the cooled hydrogen stream liquefies within the plurality of liquefaction cold boxes by indirect heat exchange against a liquefaction refrigerant to form a product hydrogen stream in each of the plurality of liquefaction cold boxes, wherein the product hydrogen stream is in liquid form or pseudo-liquid form wherein there are M total precooling cold boxes and N total liquefaction cold boxes, wherein M is less than N.
Photoelectric hydrogen production energy storage and cold energy recovery coupled dry ice production device and use method
A photoelectric hydrogen production energy storage and cold energy recovery coupled dry ice production device and a use method are disclosed. The device comprises a photoelectric conversion liquid hydrogen energy storage unit, photoelectricity participates in electrolysis of water in the storage unit to prepare hydrogen, and surplus hydrogen meeting downstream process requirements is liquefied in the unit; liquid hydrogen is output, so that intermittent photoelectric energy is converted into hydrogen energy to be stored. When hydrogen production through electrolysis of water is insufficient but industrial hydrogen is continuously used, high-grade and low-grade cold energy of low-temperature liquid hydrogen serving as cold sources in the unit is recovered from industrial tail gas purified CO.sub.2 and air separation nitrogen, liquid nitrogen and liquid CO.sub.2 are output and used for the storage unit and dry ice production respectively, and the liquid hydrogen is reheated and supplied to a downstream process.
APPARATUS FOR PRECOOLING HYDROGEN FOR LIQUEFACTION USING EXTERNAL LIQUID NITROGEN AND HIGH PRESSURE GASEOUS NITROGEN
An integrated industrial unit is provided, which can include: a nitrogen source comprising an air separation unit that is configured to provide pressurized gaseous nitrogen and liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 70K and 100K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.
Method and system for liquifying a gas
A method and system for producing liquid air wherein liquid refrigerant is cycled between two core tanks maintained at a temperature sufficient to liquify compressed air passed through condensing tubing in the interior of the core tanks. Liquid refrigerant is cycled by alternating high pressure gas from a high pressure tank to one of the core tanks, which forces liquid refrigerant from this tank through an expansion device to expand a portion of the liquid refrigerant to absorb heat in the other core tank, the resulting refrigerant gas being driven into a low pressure tank. A compression device transfers the refrigerant gas from the low pressure tank to the high pressure tank and maintains the pressure in the high pressure tank. Connections between the low and high pressure tanks and the core tanks are reversed with each cycle.
Hydrogen Liquefaction System and Method
A system and method for liquefying a hydrogen gas feed stream uses a pre-cooling refrigerant for pre-cooling the feed stream, where the pre-cooling refrigerant is compressed, cooled and then separated to provide high pressure mixed refrigerant vapor and liquid streams. The high pressure vapor stream is cooled and directed to a cold vapor separator where cold separator liquid and vapor streams are formed. The cold separator vapor stream is cooled and expanded to provide a pre-cool refrigeration stream in a heat exchanger system. The high pressure pre-cooling refrigerant liquid and cold separator liquid streams are cooled and expanded and directed to the pre-cool refrigeration stream. A high pressure primary refrigerant steam, after compression and cooling, is further cooled in the heat exchanger system and then expanded using warm and cold expanders, with the resulting expanded primary refrigerant streams used to liquefy the pre-cooled hydrogen feed stream via heat exchange in the heat exchanger system.
Method and facility for storing and distributing liquefied hydrogen
The invention relates to a method for storing and distributing liquefied hydrogen using a facility that comprises a store of liquid hydrogen at a predetermined storage pressure, a source of hydrogen gas, a liquefier comprising an inlet connected to the source and an outlet connected to the liquid hydrogen store, the store comprising a pipe for drawing liquid, comprising one end connected to the liquid hydrogen store and one end intended for being connected to at least one mobile tank, the method comprising a step of liquefying hydrogen gas supplied by the source and a step of transferring the liquefied hydrogen into the store characterized in that the hydrogen liquefied by the liquefier and transferred into the store has a temperature lower than the bubble temperature of hydrogen at the storage pressure.
PLANT AND METHOD FOR LIQUEFYING GAS
Plant and method for liquefying a flow of gas, comprising a cooling circuit which is provided with an upstream end which is intended to be connected to a source of pressurised gas to be liquified and a downstream end which is intended to be connected to a user member, the plant comprising, between the upstream and downstream ends, a set of members which are intended to liquefy the gas and comprise at least one exchanger for cooling the gas, and at least one expansion turbine which is mounted on a rotary axle which is supported by at least one bearing of the gas-static type, the cooling circuit comprising a pressurised gas injection conduit having an upstream end which is intended to receive pressurised gas supplied by the source and a downstream end which is connected to the bearing in order to provide support to the rotary axle, the plant comprising a conduit for recovering the gas which has been used in the bearing, the conduit for recovering the gas comprising an upstream end which is connected to the bearing and a downstream end, characterised in that the downstream end of the conduit for recovering the as is connected to the cooling circuit between the upstream and downstream ends thereof in order to recycle at that location at least a portion of the gas which has been used to support the rotary axle of the bearing with a few to liquefying said gas.
Gas expansion system
The amount of consumption of gas is reduced when the gas is expanded to be cooled by using a plurality of expansion turbines. A high-pressure expansion turbine includes: a gas supply passage through which bearing gas is supplied to a bearing portion; and a gas discharge passage through which the bearing gas which has been supplied from the gas supply passage to the bearing portion is discharged from the bearing portion. A low-pressure expansion turbine includes: a gas supply passage through which the bearing gas is supplied to a bearing portion; and a gas discharge passage through which the bearing gas which has been supplied from the gas supply passage to the bearing portion is discharged from the bearing portion. The bearing gas discharged from the gas discharge passage of the high-pressure expansion turbine is supplied to the gas supply passage of the low-pressure expansion turbine.
INTEGRATION PROCESS PRINCIPLES FOR MAXIMIZING THE BOIL OFF RECOVERY ON A H2 LIQUEFIER PLANT
A method for recovering boil-off gas from a system including one or more liquefaction trains including transport trucks or loading bays, a gaseous hydrogen feed stream, a lower-temperature cold box, and a low-pressure hydrogen compressor. The method including collecting a boil-off gas stream from the transport trucks or loading bays, determining the pressure of the boil-off gas stream, and depending on the pressure, recycling the boo-off gas stream to predetermined destinations. Wherein the boil-off gas stream has either a low-pressure, having a pressure of less than 2 bara, or a medium-pressure, having a pressure equal to or greater than 2 bara.