In a process for the combined production of a) a hydrogen-enriched gas and a carbon monoxide-enriched gas and/or b) a mixture of hydrogen and carbon monoxide by cryogenic distillation and scrubbing, a still liquor is extracted from a scrubbing column and sent to a stripping column, a still liquor is extracted from the stripping column and sent to a separating column for carbon monoxide and methane and a cooling fluid is used at a pressure greater than that of the head of the separating column for cooling at least one fluid extracted at an intermediate level from the scrubbing column.

The present invention relates to a cold box cycle which allows for independent control of the heat supplied for reboilers associated with the separation columns. More specifically, the invention relates to the tight control of the hydrogen removal separation, thus avoiding the possibility of excess reboiling in this separation. Optimal reboiling also results in a lower temperature of the hydrogen depleted liquid from this separation. As this stream is used to provide a portion of the cooling at the cold end of the primary heat exchanger, lower temperatures facilitate cooling of the incoming syngas feed, reducing carbon monoxide (CO) losses into the crude hydrogen stream from the high pressure separator. Lower CO in the crude hydrogen allows for smaller hydrogen purification equipment.

The present invention is directed to a method and system of separating carbon monoxide from syngas mixtures with high methane content by cryogenic means where a partial condensation cycle is generally employed, and more specifically towards combining the methane-rich liquid exiting the distillation column with a lower-boiling mixture so that the boiling point of the combined stream is lower than the boiling point of the methane-rich liquid.

The present invention is directed to a method of separating carbon monoxide from syngas mixtures by cryogenic means where a partial condensation cycle is generally employed, and more specifically varying refrigeration generation based on income feed composition of the hydrocarbon feedstock being processed.

Process for the combined production of a mixture of hydrogen and nitrogen, and of carbon monoxide by cryogenic distillation and cryogenic scrubbing, wherein a methane-rich liquid is introduced at a first intermediate level of a scrubbing column as first scrubbing liquid and at least one nitrogen-rich liquid is introduced at a level higher than the first level of the scrubbing column as second scrubbing liquid and a mixture of hydrogen and nitrogen is drawn off as overhead gas from the scrubbing column.

The present invention is directed to a method and system of separating carbon monoxide from syngas mixtures with low methane content by cryogenic means where a partial condensation cycle is generally employed, and more specifically towards providing a methane slip stream to the feed in order to reduce the potential for any carbon dioxide entering the cold box to freeze, thereby preventing plugging of the cold box heat exchanger.

The invention relates to a method for separating a synthesis gas comprising hydrogen and carbon monoxide by cryogenic distillation, according to which the synthesis gas (1, 5) is cleaned and cooled to a cryogenic temperature, the cooled synthesis gas is separated by a first means (15) in order to produce a hydrogen-depleted liquid (33), the hydrogen-depleted liquid is introduced into the upper part of a stripping column (25) and a hydrogen-enriched gas (27) is drawn off at the head of the stripping column, at least partially condensed and sent back to the upper part of the stripping column.

In a process for separating a mixture containing carbon monoxide, hydrogen and carbon dioxide, the mixture cooled in a heat exchanger is contacted by a stream of liquid methanol at a temperature below 40 C. to produce carbon dioxide enriched methanol and a carbon dioxide depleted gas relative to the cooled mixture, the carbon dioxide depleted gas is cooled in the heat exchanger and is sent to a separation unit to produce a carbon monoxide enriched stream and a hydrogen enriched stream and the streams enriched in carbon monoxide and hydrogen are heated in the heat exchanger by exchanging heat with the mixture.

In a method for producing a gaseous mixture of CO and H.sub.2, a first gas comprising at least 50% CO is compressed in a first compressor to form a first compressed gas cooled to a first temperature and mixes with a second gas comprising at least 50% hydrogen in order to form the gaseous mixture, at least one of the first and second gases originating from a cryogenic distillation separation unit in which a feed gas containing H.sub.2 and CO cools in a first heat exchanger and is separated in at least one distillation column and at least one part of the second gas heats in the separation unit to a third temperature lower than the first temperature and is then sent to mix with the first gas.

In a process of the separation of a mixture of carbon monoxide, hydrogen and methane, the mixture is sent to a scrubbing column, a bottom liquid withdrawn at the bottom of the scrubbing column is depleted in hydrogen with respect to the mixture and is sent to a stripping column, a bottom liquid from the stripping column is sent to a separation column and a liquid enriched in methane withdrawn from the bottom of the separation column is vaporized in order to form a final product.