A sensor element includes: an element base made of an oxygen-ion conductive solid electrolyte; an internal space provided inside the element base; an electrochemical pump cell configured to pump oxygen in and out between the internal space and outside; a porous thermal shock resistant layer provided to an outermost peripheral part in a predetermined range at one end part of the element base, at which a gas inlet is provided; and a buffer layer adjacent to the thermal shock resistant layer on a pump surface and a heater surface. A thermal diffusion time in a thickness direction of the thermal shock resistant layer is 0.4 sec to 1.0 sec inclusive, and a total thermal diffusion time in a stacking direction of the thermal shock resistant layer and the buffer layer is 0.2 sec to 1.0 sec inclusive.

A sensor element includes an element base made of an oxygen-ion conductive solid electrolyte, an internal space provided inside the element base, an electrochemical pump cell that pumps oxygen in and out between the internal space and outside, and a porous thermal shock resistant layer provided to an outermost peripheral part in a predetermined range at one end part of the element base, at which a gas inlet is provided. A thermal diffusion time in a thickness direction of the thermal shock resistant layer is 0.4 sec to 1.0 sec inclusive. A thermal diffusion time at a leading end part of the thermal shock resistant layer covering the gas inlet at a farthest leading end position at the one end part is longest, and a thermal diffusion time at a pump surface is longer than a thermal diffusion time at a heater surface.

A hydrogen sensor that efficiently detects hydrogen gas at room temperature comprising a gold decorated reduced graphene oxide/zinc oxide (Au/rGO/ZnO) heterostructured composite, methods for making this sensor and a method for sensitive room temperature detection of hydrogen using the sensor.

A mixed-potential type gas sensor capable of preferably determining the concentration of THC including a kind of gas having a large C number is provided. A sensor element composed of an oxygen-ion conductive solid electrolyte is provided with, on its surface, a sensing electrode formed of a cermet of Pt, Au, and an oxygen-ion conductive solid electrolyte, and includes a reference electrode and a porous surface protective layer that covers at least said sensing electrode. An Au abundance ratio on a surface of noble metal particles forming the sensing electrode is 0.3 or more. The surface protective layer has a porosity of 28% to 40%, a thickness of 10 to 50 μm, and an area ratio of a coarse pore having a pore size of 1 μm or larger of 50% or more; or has a porosity of 28% to 40% and a thickness of 10 to 35 μm.

A metal terminal includes a front-side terminal member and a rear-side terminal member. The front-side terminal member includes a female connection portion, and the rear-side terminal member includes a male connection portion. The female connection portion has an insertion port in which the male connection portion is inserted. The insertion port is formed in a shape that prevents the insertion port and the male connection portion from coming into contact with each other when the male connection portion is inserted therein. The female connection portion includes a terminal contact portion which brings the male connection portion and the female connection portion into contact with each other by pressing the male connection portion toward the female connection portion inside the female connection portion.

A NOx sensor element includes: a first pump cell configured to adjust an oxygen concentration in a first measurement chamber; a diffusion resistance portion configured to adjust a diffusion rate of a measurement target gas introduced into the first measurement chamber; and a second pump cell in which a pump current corresponding to a NOx concentration in the measurement target gas after the adjustment of the oxygen concentration, flows. The first pump cell includes: a first solid electrolyte; an inner pump electrode containing a noble metal, and exposed to the first measurement chamber; and an outer pump electrode containing a noble metal, and disposed outside the first measurement chamber. The outer pump electrode contains not less than 22% by mass of a main component of the first solid electrolyte.

A controller of the gas sensor can perform diagnostic processing of diagnosing a situation of control to the gas sensor in a case that the gas sensor in an operation state is determined to satisfy a predetermined diagnostic condition and adjustment processing of adjusting a condition for controlling the gas sensor in accordance with a result of diagnosis. In the diagnostic processing, a main pump voltage and a diagnostic threshold as a value of a voltage not causing decomposition of NOx in the main pump cell are compared. In the adjustment processing, temperature adjustment processing to cause, in a case that the main pump voltage is diagnosed to be equal to the threshold or more, the main pump voltage to be less than the threshold, at least in a way that the heater part increases the element driving temperature in the operation state by a predetermined increase amount is performed.

A carbon dioxide sensor includes: a solid electrolyte layer that is anion conductive; a reference electrode disposed on one surface of the solid electrolyte layer; and a detection electrode disposed on the other surface of the solid electrolyte layer. The detection electrode is made of a mixture containing: (a) one or more metals selected from the group consisting of Au, Ag, Pt, Pd, Rh, Ru, Os, and Ir; (b) a cation conductive carbonate; and (c) an oxide containing Li and at least one of Ce and Sm. The solid electrolyte layer is preferably oxide ion conductive, and the cation conductive carbonate is preferably lithium ion conductive.

A gas sensor includes: a substrate; an insulating layer arranged over the substrate; and a solid electrolyte layer, wherein the substrate is formed with a cavity that penetrates the substrate in a thickness direction of the substrate, wherein the insulating layer has a peripheral portion arranged over the substrate around the cavity, and a membrane portion which is located over the cavity and is connected to the peripheral portion, wherein the membrane portion includes a movable portion, wherein a through-hole, which penetrates the membrane portion around the movable portion in the thickness direction, is formed such that the movable portion is capable of being displaced along the thickness direction, and wherein the solid electrolyte layer is arranged over the movable portion.

There is provided a carbon dioxide gas sensor that includes a flow path including an inlet into which a detected target gas is introduced; and a first element and at least one second element arranged in the flow path. The first element includes a first solid electrolyte layer, a first cathode, and a first anode, the first solid electrolyte layer being interposed between the first cathode and the first anode. The at least one second element includes a second solid electrolyte layer, a second cathode, and a second anode, the second solid electrolyte layer being interposed between the second cathode and the second anode. The first solid electrolyte layer and the second solid electrolyte layer are formed of an oxygen ion conductor. The first cathode is inside the flow path. The second cathode and the second anode are inside the flow path and outside the flow path, respectively.