A process for estimating catalyst performance of catalyst used in refinery reforming processes for converting naphtha to gasoline. More in particular, the catalyst to be investigated is subjected to analysis in parallel over time at a temperature to achieve a desired RON on yield of e.g. C5+, for at least two different reaction times. The reactions are terminated after which coke deposition is determined, and relationships of coke deposition and yield, both as a function of reaction temperature for the catalyst used are established, thereby enabling comparison of catalyst performance as determined by a yield-temperature relationship at a given coke deposition degree.

A process for estimating catalyst performance of catalyst used in refinery reforming processes for converting naphtha to gasoline. More in particular, the catalyst to be investigated is subjected to analysis in parallel over time at a temperature to achieve a desired RON on yield of e.g. C5+, for at least two different reaction times. The reactions are terminated after which coke deposition is determined, and relationships of coke deposition and yield, both as a function of reaction temperature for the catalyst used are established, thereby enabling comparison of catalyst performance as determined by a yield-temperature relationship at a given coke deposition degree.

An apparatus and a method are used for investigating the naphtha reforming process in catalyst test devices with reactors arranged in parallel. The apparatus has a plurality of reactors arranged in parallel with reaction chambers (R1, R2, . . . ), a product fluid supply, a process control, and at least one analysis unit. Each individual reactor has an outlet line for the product fluid stream, wherein the analysis unit is operatively connected to each outlet line for the product fluid stream and the apparatus is functionally connected to the control of the apparatus. In carrying out the method, naphtha-containing reactant fluid streams are brought into contact with catalysts in the individual reactors and the product fluid streams are subsequently supplied to the online analysis unit from the respective outlet lines of the individual reactors and analyzed. Using the evaluation of the online analytical characterization data, the process parameters of the respective reactor unit are adapted. The process steps of analytical characterization, evaluation, and adaptation of process parameters are repeated for the duration of the investigation.

An apparatus and a method are used for investigating the naphtha reforming process in catalyst test devices with reactors arranged in parallel. The apparatus has a plurality of reactors arranged in parallel with reaction chambers (R1, R2, . . . ), a product fluid supply, a process control, and at least one analysis unit. Each individual reactor has an outlet line for the product fluid stream, wherein the analysis unit is operatively connected to each outlet line for the product fluid stream and the apparatus is functionally connected to the control of the apparatus. In carrying out the method, naphtha-containing reactant fluid streams are brought into contact with catalysts in the individual reactors and the product fluid streams are subsequently supplied to the online analysis unit from the respective outlet lines of the individual reactors and analyzed. Using the evaluation of the online analytical characterization data, the process parameters of the respective reactor unit are adapted. The process steps of analytical characterization, evaluation, and adaptation of process parameters are repeated for the duration of the investigation.

A catalytic reaction analysis dual reactor system and a method for measuring the catalytic activity of a catalyst by correcting for non-catalytic effects with the catalytic reaction analysis dual reactor system. The dual reactor system contains a first reactor comprising a first catalyst on a first catalyst support, and a second reactor comprising a second catalyst support, wherein the particle size and amount of the first catalyst and the second catalyst support are substantially the same, and the effect of the catalyst is isolated by correcting the result obtained from the first reactor containing the catalyst with the result obtained from the second reactor containing the catalyst support.

A catalytic reaction analysis dual reactor system and a method for measuring the catalytic activity of a catalyst by correcting for non-catalytic effects with the catalytic reaction analysis dual reactor system. The dual reactor system contains a first reactor comprising a first catalyst on a first catalyst support, and a second reactor comprising a second catalyst support, wherein the particle size and amount of the first catalyst and the second catalyst support are substantially the same, and the effect of the catalyst is isolated by correcting the result obtained from the first reactor containing the catalyst with the result obtained from the second reactor containing the catalyst support.

The invention relates to an apparatus for analyzing heterogeneously catalyzed reactions comprising at least one reactor (3) through which a particulate catalyst flows and at least one reactant feed, wherein arranged downstream of each reactor (3) is a separation apparatus (17) for separating the particulate catalyst from a reaction product comprising condensable gases and arranged downstream of the separation apparatus (17) is a liquid separator (31) for separating liquid constituents from the reaction product, wherein the liquid separator (31) comprises a metallic tube (103) and a deflection body (119), wherein the metallic tube (103) is closed at its ends and the deflection body (119) is accommodated in the metallic tube (103) and the metallic tube (103) comprises a side feed (135) at a first end (105) and a gas outlet (113) at a second end (107) and the gas outlet (113) is connected to at least one sample vessel (37). The invention further relates to a process for analyzing heterogeneously catalyzed reactions in the apparatus.

The invention relates to an apparatus for analyzing heterogeneously catalyzed reactions comprising at least one reactor (3) through which a particulate catalyst flows and at least one reactant feed, wherein arranged downstream of each reactor (3) is a separation apparatus (17) for separating the particulate catalyst from a reaction product comprising condensable gases and arranged downstream of the separation apparatus (17) is a liquid separator (31) for separating liquid constituents from the reaction product, wherein the liquid separator (31) comprises a metallic tube (103) and a deflection body (119), wherein the metallic tube (103) is closed at its ends and the deflection body (119) is accommodated in the metallic tube (103) and the metallic tube (103) comprises a side feed (135) at a first end (105) and a gas outlet (113) at a second end (107) and the gas outlet (113) is connected to at least one sample vessel (37). The invention further relates to a process for analyzing heterogeneously catalyzed reactions in the apparatus.

A method that determines a cause for the impaired performance of a catalytic configuration of the exhaust gas of a combustion engine (231), the method including determining (s410) a course of a NOx-conversion ratio; determining (s420) a prevailing temperature of the catalytic configuration; increasing (s430) the temperature of the catalytic configuration from a prevailing temperature below a predetermined temperature value (Te) to a temperature (TSred) above the predetermined temperature value above which sulphur is removed from the catalytic configuration; and/or decreasing (s440) the temperature of the catalytic configuration from a prevailing temperature (TSred) above the predetermined temperature value (Te) to a temperature below the predetermined temperature value so as to impair the performance of the catalytic configuration in case sulphur is present; and determining (s450) one cause out of a set of causes on the basis of the course of the NOx-conversion ratio thus determined.

A method that determines a cause for the impaired performance of a catalytic configuration of the exhaust gas of a combustion engine (231), the method including determining (s410) a course of a NOx-conversion ratio; determining (s420) a prevailing temperature of the catalytic configuration; increasing (s430) the temperature of the catalytic configuration from a prevailing temperature below a predetermined temperature value (Te) to a temperature (TSred) above the predetermined temperature value above which sulphur is removed from the catalytic configuration; and/or decreasing (s440) the temperature of the catalytic configuration from a prevailing temperature (TSred) above the predetermined temperature value (Te) to a temperature below the predetermined temperature value so as to impair the performance of the catalytic configuration in case sulphur is present; and determining (s450) one cause out of a set of causes on the basis of the course of the NOx-conversion ratio thus determined.