An insulated wire, including: a conductor and an insulating film covering the conductor; in which at least one insulating layer constituting the insulating film contains: a thermosetting resin A, and a resin B that is ranked lower than the thermosetting resin A in a tribo-electric series.

The invention relates generally to the field of insulating electrical conductors against partial discharge in the medium- and high-voltage ranges. In particular, the invention relates to an insulating system for an electric machine, in particular a rotating electric machine such as an electric motor and/or a generator. The invention provides for the first time a substitute for the conventionally used mica as a barrier material in an insulating system, such as the main insulation of rotating electric machines such as motors and/or generators. The substitute is based on a polyether-imide/siloxane copolymer, which can be processed two-dimensionally, for example by surface extrusion. In this way, sheets are produced and, after being processed in sheet form or as a laminate, can be used as planar insulating materials, or cut as strips, in insulating systems.

The present invention provides an electrically insulating resin composition comprising a polysulfone resin including a plurality of sulfonyl groups in the molecule and a polyamide resin, wherein the proportion of the polyamide resin is 1 to 45% by mass. The present invention also provides a laminate sheet obtained by bonding a plurality of sheet materials with a resin composition layer interposed therebetween, wherein the resin composition layer comprises a polysulfone resin including a plurality of sulfonyl groups in the molecule and a polyamide resin, and the proportion of the polyamide resin is 1 to 45% by mass.

An insulated wire having at least one layer of coating of the wire, comprising a thermosetting resin layer, at the outer periphery of a conductor, wherein the thermosetting resin layer is comprised of thermosetting resin layers having a laminated structure formed by coating and baking a thermosetting resin varnish; and wherein, in said laminated structure, an innermost layer having contact with the conductor comprises a thermosetting resin having an imide bond and is a layer having an average thickness of more than 5 μm and 10 μm or less; a method of producing the insulated wire; a coil; a rotating electrical machine; and an electrical or electronic equipment.

A silica-blended resin varnish contains a silica sol with a high dispersibility that is dispersed in a ketone organic solvent, in a nitrogen atom-containing polymer. The particles have an average size of 5 to 100 nm and have a carbon-carbon unsaturated bond-containing organic group and an alkoxy group bonded to surfaces thereof. The carbon-carbon unsaturated bond-containing organic group is bonded at 0.5 to 2.0 groups per unit area (nm.sup.2) of the particle surfaces. The alkoxy group is bonded at 0.1 to 2.0 groups per unit area (nm.sup.2) of the particle surfaces. The molar ratio of {(the carbon-carbon unsaturated bond-containing organic group)/(the alkoxy group)} is 0.5 to 5.0. The carbon-carbon unsaturated bond-containing organic group may be a phenyl group-containing organic group or a (meth)acryloyl group-containing organic group. An insulating resin composition contains the silica sol and a nitrogen-containing polymer, which may be polyimide, polyamide, polyamic acid, polyamide-imide, polyetherimide, or polyesterimide.

An optical stack structure includes a metal nanowire layer and an organic polymer layer. A crosslinking degree of the organic polymer layer is greater than or equal to 80% and less than or equal to 100%, and a content of volatile organic compounds in the organic polymer layer is less than or equal to 1%. The content of the volatile organic compounds in the organic polymer layer is defined as a difference between a thermal weight loss of the organic polymer layer measured at a measuring temperature and a water content of the organic polymer layer measured at the measuring temperature.

Provided is a layered body comprising a conductor and an insulation film containing a metal hydroxide hydrate, wherein properties such as electrical characteristics and physical characteristics can be improved while maintaining an erosion suppressing effect against partial discharge, and manufacturing costs can be reduced. The layered body comprises at least a conductor and an insulation film, wherein: the insulation film includes a first insulation film and a second insulation film; the second insulation film is constituted by a resin composition comprising a metal oxide hydrate; in the resin composition, the content of the metal oxide hydrate is 6-50 parts by mass with respect to 100 parts by mass of the resin; the thickness of the second insulation film is 5 μm or more; the ratio of the thickness of the second insulation film is less than 75% of the thickness of the entire insulation film; and in the insulation film, an inorganic insulation layer is formed when the layered body is exposed to a partial discharge generated by an inverter surge.

An assembled wire has a substantially rectangular cross section, and is formed by assembling a plurality of strands. Each strand has a conductor portion and a strand insulating layer covering the conductor portion. At least a part of the assembled plurality of strands in the longitudinal direction is covered with an outer insulating layer. The strand is formed as follows. First, the strand insulating layer is coated on the outer periphery of the conductor portion. A large number of voids are formed in a resin constituting the strand insulating layer. From this state, the strand is formed, for example, by collapsing the strand insulating layer by heating and pressurizing. At this time, it is possible to uniformly collapse the strand insulating layer by crushing the internal voids. Therefore, the voids in the strand are crushed and flattened in the thickness direction of the strand insulating layer over the entire periphery.

A silica-blended resin varnish contains a silica sol with a high dispersibility that is dispersed in a ketone organic solvent, in a nitrogen atom-containing polymer. The particles have an average size of 5 to 100 nm and have a carbon-carbon unsaturated bond-containing organic group and an alkoxy group bonded to surfaces thereof. The carbon-carbon unsaturated bond-containing organic group is bonded at 0.5 to 2.0 groups per unit area (nm.sup.2) of the particle surfaces. The alkoxy group is bonded at 0.1 to 2.0 groups per unit area (nm.sup.2) of the particle surfaces. The molar ratio of {(the carbon-carbon unsaturated bond-containing organic group)/(the alkoxy group)} is 0.5 to 5.0. The carbon-carbon unsaturated bond-containing organic group may be a phenyl group-containing organic group or a (meth)acryloyl group-containing organic group. An insulating resin composition contains the silica sol and a nitrogen-containing polymer, which may be polyimide, polyamide, polyamic acid, polyamide-imide, polyetherimide, or polyesterimide.

The present invention relates to an aluminum-resin composite and provides the aluminum-resin composite which is excellent in adhesive property between metal and resin and is applicable to a continuous production process such as a wire production process. Specifically, the present invention uses the aluminum-resin composite including a metal made of aluminum or an aluminum alloy and resin adhering to the metal via an alumina nanoporous layer formed on a surface of the metal. The alumina nanoporous layer contains alumina nanoparticles of 5 nm to 10 nm in average particle diameter and holes three-dimensionally communicating with one another.