The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li.sub.7La.sub.3Zr.sub.2O.sub.12.

The instant disclosure sets forth multiphase lithium-stuffed garnet electrolytes having secondary phase inclusions, wherein these secondary phase inclusions are material(s) which is/are not a cubic phase lithium-stuffed garnet but which is/are entrapped or enclosed within a lithium-stuffed garnet. When the secondary phase inclusions described herein are included in a lithium-stuffed garnet at 30-0.1 volume %, the inclusions stabilize the multiphase matrix and allow for improved sintering of the lithium-stuffed garnet. The electrolytes described herein, which include lithium-stuffed garnet with secondary phase inclusions, have an improved sinterability and density compared to phase pure cubic lithium-stuffed garnet having the formula Li.sub.7La.sub.3Zr.sub.2O.sub.12.

A solid electrolyte is composed of a compound represented by the general formula Li.sub.xM.sub.2(PO.sub.4).sub.z where M represents at least one element having a valence of one to four, x represents a number that satisfies 0.800≤x≤1.900, and z represents a number that satisfies 2.600≤z≤2.800.

A solid electrolyte is composed of a compound represented by the general formula Li.sub.xM.sub.2(PO.sub.4).sub.z where M represents at least one element having a valence of one to four, x represents a number that satisfies 0.800≤x≤1.900, and z represents a number that satisfies 2.600≤z≤2.800.

The fabrication of single-crystalline ionically conductive materials and related articles and systems are generally described.

The fabrication of single-crystalline ionically conductive materials and related articles and systems are generally described.

It is described a Zn—Fe quasi-solid redox battery (QSRB) making use of low cost and earth abundant materials as reactive species, comprising: —a first half-cell comprising a first quasi-solid electrolyte in which are dissolved Zn.sup.2+ ions or a first quasi-solid electrolyte in which are dispersed organic and/or inorganic electroactive particles containing zinc ions in different oxidation states, and a current collector and an electrode disposed within the first half-cell; —a second half-cell comprising a second quasi-solid electrolyte in which are dissolved Fe.sup.2+ and Fe.sup.3+ ions or a second quasi-solid electrolyte in which are dispersed organic and/or inorganic electroactive particles containing Fe.sup.2+ and Fe.sup.3+ ions, and a current collector and an electrode disposed within the second half-cell; and —a separator between the two half-cells.

It is described a Zn—Fe quasi-solid redox battery (QSRB) making use of low cost and earth abundant materials as reactive species, comprising: —a first half-cell comprising a first quasi-solid electrolyte in which are dissolved Zn.sup.2+ ions or a first quasi-solid electrolyte in which are dispersed organic and/or inorganic electroactive particles containing zinc ions in different oxidation states, and a current collector and an electrode disposed within the first half-cell; —a second half-cell comprising a second quasi-solid electrolyte in which are dissolved Fe.sup.2+ and Fe.sup.3+ ions or a second quasi-solid electrolyte in which are dispersed organic and/or inorganic electroactive particles containing Fe.sup.2+ and Fe.sup.3+ ions, and a current collector and an electrode disposed within the second half-cell; and —a separator between the two half-cells.

A mixed powder for an all-solid-state lithium-ion battery, which is composed of a positive electrode active material for a lithium-ion battery and a solid electrolyte, wherein the positive electrode active material for a lithium-ion battery is composed of particles containing crystals of a lithium metal composite oxide, and the lithium metal composite oxide has a layered structure and contains at least Li and a transition metal, wherein the positive electrode active material for a lithium-ion battery has a particle diameter distribution that satisfies the following Formula (1), and wherein the solid electrolyte has a particle diameter distribution that satisfies the following Formula (2):

[00001]$\left(\text{D90-D10}\right)/\text{D50}\le \text{1}\text{.5}$

[00002]$\left(\text{D90-D10}\right)/\text{D50}\le 2.0$

A mixed powder for an all-solid-state lithium-ion battery, which is composed of a positive electrode active material for a lithium-ion battery and a solid electrolyte, wherein the positive electrode active material for a lithium-ion battery is composed of particles containing crystals of a lithium metal composite oxide, and the lithium metal composite oxide has a layered structure and contains at least Li and a transition metal, wherein the positive electrode active material for a lithium-ion battery has a particle diameter distribution that satisfies the following Formula (1), and wherein the solid electrolyte has a particle diameter distribution that satisfies the following Formula (2):

[00001]$\left(\text{D90-D10}\right)/\text{D50}\le \text{1}\text{.5}$

[00002]$\left(\text{D90-D10}\right)/\text{D50}\le 2.0$