A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

A secondary battery separator includes a porous substrate; and a porous layer laminated on at least one surface of the porous substrate, the porous layer comprising fluorine resin particles and inorganic particles; wherein the fluorine resin particles are formed using a fluorine resin having a weight-average molecular weight of 100,000 or more and 5,000,000 or less, and have an average particle size of 0.01 μm or more and 1.00 μm or less; and wherein the inorganic particles have an average particle size of 0.10 μm or more and 5.0 μm or less.

A secondary battery separator includes a porous substrate; and a porous layer laminated on at least one surface of the porous substrate, the porous layer comprising fluorine resin particles and inorganic particles; wherein the fluorine resin particles are formed using a fluorine resin having a weight-average molecular weight of 100,000 or more and 5,000,000 or less, and have an average particle size of 0.01 μm or more and 1.00 μm or less; and wherein the inorganic particles have an average particle size of 0.10 μm or more and 5.0 μm or less.

A battery separator has performance enhancing additives or coatings, fillers with increased friability, increased ionic diffusion, decreased tortuosity, increased wettability, reduced oil content, reduced thickness, decreased electrical resistance, and/or increased porosity. The separator in a battery reduces the water loss, lowers acid stratification, lowers the voltage drop, and/or increases the CCA. The separators include or exhibit performance enhancing additives or coatings, increased porosity, increased void volume, amorphous silica, higher oil absorption silica, higher silanol group silica, reduced electrical resistance, a shish-kebab structure or morphology, a polyolefin microporous membrane containing particle-like filler in an amount of 40% or more by weight of the membrane and ultrahigh molecular weight polyethylene having shish-kebab formations and the average repetition periodicity of the kebab formation from 1 nm to 150 nm, decreased sheet thickness, decreased tortuosity, separators especially well-suited for enhanced flooded batteries.

The invention relates to a method for producing a battery (10) filled with a liquid electrolyte (2, 11), wherein the battery (10) comprises a housing (1) having a top side (3) lying at the top in the normal operation of the battery (10) and a bottom side (4) opposite the top side (3), wherein battery electrodes (6) are arranged in the housing (1) and the housing (1) has at least one filling opening (5) for the liquid electrolyte (2, 11), which filling opening is arranged on the top side (3) of the housing (1) or at least above the center of the housing (1), characterized in that liquid electrolyte (2, 11) is fed through the at least one filling opening (5) in such a way that the topmost point (16) of the battery electrodes (6) with respect to the direction of action of gravity is not completely covered with the liquid electrolyte (2, 11) at any time during the process of filling the battery with liquid electrolyte (2, 11). The invention further relates to a filling vessel designed for performing the method, to a machine, and to a battery.

The invention relates to a method for producing a battery (10) filled with a liquid electrolyte (2, 11), wherein the battery (10) comprises a housing (1) having a top side (3) lying at the top in the normal operation of the battery (10) and a bottom side (4) opposite the top side (3), wherein battery electrodes (6) are arranged in the housing (1) and the housing (1) has at least one filling opening (5) for the liquid electrolyte (2, 11), which filling opening is arranged on the top side (3) of the housing (1) or at least above the center of the housing (1), characterized in that liquid electrolyte (2, 11) is fed through the at least one filling opening (5) in such a way that the topmost point (16) of the battery electrodes (6) with respect to the direction of action of gravity is not completely covered with the liquid electrolyte (2, 11) at any time during the process of filling the battery with liquid electrolyte (2, 11). The invention further relates to a filling vessel designed for performing the method, to a machine, and to a battery.

The invention provides sulfuric acid efficiency electrolytes including a surfactant, preferably an amphoteric or a non-ionic surfactant, and/or phosphoric acid, the sulfuric acid efficiency electrolyte preferably further including at least one of a chelating agent and a crystal growth regulator, and optionally, a filler. The invention further provides sulfuric acid electrolytes including a filler, at least one chelating agent, and at least one water-soluble sulfate salt, wherein the chelating agent comprises an alkali metallated chelating agent and the water-soluble sulfate salt comprises the corresponding cation to the cation present in the alkali metallated chelating agent. The invention further provides lead sulfuric acid batteries including a positive electrode, negative electrode, and the efficiency electrolyte of the invention disposed therebetween.

The invention provides sulfuric acid efficiency electrolytes including a surfactant, preferably an amphoteric or a non-ionic surfactant, and/or phosphoric acid, the sulfuric acid efficiency electrolyte preferably further including at least one of a chelating agent and a crystal growth regulator, and optionally, a filler. The invention further provides sulfuric acid electrolytes including a filler, at least one chelating agent, and at least one water-soluble sulfate salt, wherein the chelating agent comprises an alkali metallated chelating agent and the water-soluble sulfate salt comprises the corresponding cation to the cation present in the alkali metallated chelating agent. The invention further provides lead sulfuric acid batteries including a positive electrode, negative electrode, and the efficiency electrolyte of the invention disposed therebetween.

In accordance with at least certain embodiments of the present invention, a novel concept of utilizing PIMS minerals as a filler component within a microporous lead-acid battery separator is provided. In accordance with more particular embodiments or examples, the PIMS mineral (preferably fish meal, a bio-mineral) is provided as at least a partial substitution for the silica filler component in a silica filled lead acid battery separator (preferably a polyethylene/silica separator formulation). In accordance with at least selected embodiments, the present invention is directed to new or improved batteries, separators, components, and/or compositions having heavy metal removal capabilities and/or methods of manufacture and/or methods of use thereof.

In accordance with at least certain embodiments of the present invention, a novel concept of utilizing PIMS minerals as a filler component within a microporous lead-acid battery separator is provided. In accordance with more particular embodiments or examples, the PIMS mineral (preferably fish meal, a bio-mineral) is provided as at least a partial substitution for the silica filler component in a silica filled lead acid battery separator (preferably a polyethylene/silica separator formulation). In accordance with at least selected embodiments, the present invention is directed to new or improved batteries, separators, components, and/or compositions having heavy metal removal capabilities and/or methods of manufacture and/or methods of use thereof.