A method of preparing an electrode for use in a biophotovoltaic device, comprising the steps of: coating a self-assembled film on a substrate using Langmuir-Blodgett technique; and immersing the coated substrate into an microalgae culture, followed by incubating thereof to grow microalgae thereon hence obtaining a biofilm, characterised in that the self-assembled film is derived from graphene.

A simple short-time method for modifying a fluorine resin film so that hydrophilicity is not likely to deteriorate over time. The method for modifying a fluorine resin film is characterized in that the surface of the fluorine resin film is provided with hydrophilicity by bringing the fluorine resin film into contact with a process gas, which contains gas containing fluorine atoms and at least one of gas containing oxygen atoms or inert gas.

This invention describes an affordable, renewable, sustainable (ARS) system to produce electricity, comprising a zinc air fuel cell (ZAFC) and photovoltaic cell. This ZAFC produces electricity operating in the pH range of 6.5-8.5 such that the primary waste species in the electrolyte are zinc cations of Zn.sup.+2 and ZnOH.sup.+. These cations are reduced by electrons from photovoltaic cells, and this ZAFC is easily rechargeable with a photovoltaic cell, and it can be overcharged. Also the electrolyte can be separated from the cell, and plating with photo reduction of zinc occurs rapidly on graphite, copper, or zinc cathodes. The efficiency of the ZAFC is approximately 58%, plus the added efficiency of reclaimed reduced zinc cations to zinc, either through recharging or plating. The electrolyte can be seawater or saline. The raw materials for this ZAFC are sufficiently available such that this system could provide ARS electricity.

A redox flow battery includes positive and negative electrodes respectfully located in half-cells separated by a porous silicon wafer separator formed by MEMS Technology. The first half cell and the second half cell each preferably include a plurality of dividers or barriers configured to create flow channels which introduce turbulence insuring the electrolytes are changing or mixing at surfaces of the electrodes and the membrane. Also disclosed is a solar energy generation and storage system which includes a photovoltaic cell and an electrochemical energy storage battery which share a common electrode. Also disclosed is a membrane-less redox flow electrical energy storage battery, having a cathode electrode; an anode electrode formed of a porous silicon substrate in which surfaces of the pores of the porous silicon substrate are coated at least in part with a metal silicide; and, an electrolyte.

Presented herein is a voltaic cell containing a biofilm for facilitating energy conversion in a bioelectrochemical energy conversion cell where the biofilm includes one or more microbial populations.

The present application relates to a method for manufacturing a photoelectrode, the method comprising steps of impregnating a first transition metal oxide capable of performing photoreaction in an electrolyte, applying a voltage onto the electrolyte to generate an electrochemical oxidation reaction on the surface of the first transition metal oxide, and forming a second transition metal oxide thin film on the surface of the first transition metal oxide by irradiating light onto the first transition metal oxide at the same time as the step of applying the voltage.

An energy conversion device for conversion of various energy forms into electricity. The energy forms may be chemical, photovoltaic or thermal gradients. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The substrate itself can be planar, two-dimensional, or three-dimensional, and possess internal and external surfaces. These substrates may be rigid, flexible and/or foldable. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous conductor material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous conductor material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.

An energy conversion device for conversion of various energy forms into electricity. The energy forms may be chemical, photovoltaic or thermal gradients. The energy conversion device has a first and second electrode. A substrate is present that has a porous semiconductor or dielectric layer placed thereover. The substrate itself can be planar, two-dimensional, or three-dimensional, and possess internal and external surfaces. These substrates may be rigid, flexible and/or foldable. The porous semiconductor or dielectric layer can be a nano-engineered structure. A porous conductor material is placed on at least a portion of the porous semiconductor or dielectric layer such that at least some of the porous conductor material enters the nano-engineered structure of the porous semiconductor or dielectric layer, thereby forming an intertwining region.

Solar electroosmosis power generation devices and methods thereof are disclosed. In some embodiments, a first electrode in transparent inorganic electrolyte solution is provided in a first temperature chamber including a first light-transmitting wall. A second electrode in transparent inorganic electrolyte solution is provided in a second temperature chamber including a second light-tight wall. The first and second temperature chambers are connected by a cation nano-film with nanoparticles on its surface close to the first temperature chamber. An external circuit connects the first and second electrodes. When the nano-film is irradiated through the first wall by sunlight, the temperature of the first temperature chamber is higher than that of the second temperature chamber. In some embodiments, the solar electroosmosis power generation device improves solar energy utilization efficiency, and can be used in the field of solar light-heat-electric conversion.

Microwave radiation may be applied to electrochemical devices for rapid thermal processing (RTP) (including annealing, crystallizing, densifying, forming, etc.) of individual layers of the electrochemical devices, as well as device stacks, including bulk and thin film batteries and thin film electrochromic devices. A method of manufacturing an electrochemical device may comprise: depositing a layer of the electrochemical device over a substrate; and microwave annealing the layer, wherein the microwave annealing includes selecting annealing conditions with preferential microwave energy absorption in the layer. An apparatus for forming an electrochemical device may comprise: a first system to deposit an electrochemical device layer over a substrate; and a second system to microwave anneal the layer, wherein the second system is configured to provide preferential microwave energy absorption in the device layer.