A redox flow battery system includes an anolyte having chromium ions in solution, wherein at least a portion of the chromium ions form a chromium complex with at least one of the following: NH.sub.3, NH.sub.4.sup.+, CO(NH.sub.2).sub.2, SCN.sup.−, or CS(NH.sub.2).sub.2; a catholyte having iron ions in solution; a first half-cell including a first electrode in contact with the anolyte; a second half-cell including a second electrode in contact with the catholyte; and a first separator separating the first half-cell from the second half-cell.

The invention relates to electrochemical current sources, more particularly to metal-air current sources, and even more particularly to lithium-air current sources and their electrodes. A cathode comprises a base made of a porous electrically conducting material that is permeable to molecular oxygen, the working surface of which has a copolymer applied thereto, which is produced by the copolymerization of a monomeric transition metal coordination complex having a Schiff base and a thiophene group monomer. The monomeric transition metal coordination complex having a Schiff base can be, for example, a compound of the [M(R,R-Salen)], [M(R,R-Saltmen)] or [M(R,R-Salphen)] type, and the thiophene group monomer can be a compound selected from a thiophene group consisting of 3-alkylthiophenes, 3,4-dialkylthiophenes, 3,4-ethylenedioxythiophene or combinations thereof. A current source comprises the described cathode and an anode made from an active metal, in particular lithium, wherein the cathode and the anode are separated by an electrolyte containing ions of the metal from which the anode is made. It has been established that in this system, the copolymer exhibits the properties of an effective catalyst. The technical result is an increase in the specific energy, specific power and number of charge and discharge cycles of a metal-air current source.

A method and a device for producing bipolar plates for fuel cells. A bipolar plate is formed by joining an anode plate to a cathode plate, wherein the anode plate and the cathode plate are formed by forming a substrate plate. In order to provide a cost-effective and automated method, it is proposed that a plate already provided with a reactive coating or catalyst coating, which is transported, automatically driven, via a transport device from the forming device to the joining device, is used as substrate plate.

A metal foil including on at least one of its sides a layer of a material including: a metal or a metal alloy, carbon, hydrogen, and optionally oxygen, the atomic percentage of the metal or of the metals of the alloy in the material ranging from 10 to 60%, the atomic percentage of carbon in the material ranging from 35 to 70%, the atomic percentage of hydrogen in the material ranging from 2 to 20%, and the atomic percentage of oxygen if present in the material being less than or equal to 10%. The metal foil can be used in the manufacture of a cathode of a lithium-ion electrochemical cell. The deposition of this layer reduces the internal resistance of the cell.

The invention relates to electrochemical current sources, more particularly to metal-air current sources, and even more particularly to lithium-air current sources and their electrodes. A cathode comprises a base made of a porous electrically conducting material that is permeable to molecular oxygen, the working surface of which has a copolymer applied thereto, which is produced by the copolymerization of a monomeric transition metal coordination complex having a Schiff base and a thiophene group monomer. The monomeric transition metal coordination complex having a Schiff base can be, for example, a compound of the [M(R,R′-Salen)], [M(R,R′-Saltmen)] or [M(R,R′-Salphen)] type, and the thiophene group monomer can be a compound selected from a thiophene group consisting of 3-alkylthiophenes, 3,4-dialkylthiophenes, 3,4-ethylenedioxythiophene or combinations thereof. A current source comprises the described cathode and an anode made from an active metal, in particular lithium, wherein the cathode and the anode are separated by an electrolyte containing ions of the metal from which the anode is made. It has been established that in this system, the copolymer exhibits the properties of an effective catalyst. The technical result is an increase in the specific energy, specific power and number of charge and discharge cycles of a metal-air current source.

Systems and methods are provided for mechanical pretreatment of bipolar plates, for example, for plating electrodes in redox flow batteries. In one example, a method for disrupting surfaces of a bipolar plate may include pressing the bipolar plate between imprint plates, and removing the pressed bipolar plate from the imprint plates prior to use in a redox flow battery. In some examples, the pressed bipolar plate may include negative indentations from at least one of the imprint plates. In some examples, the imprint plates may be patterned meshes, such that the negative indentations may include patterns of asymmetric protrusions. In this way, the bipolar plate may be pretreated via pressing so as to reduce wear to manufacturing equipment (relative to other mechanical pretreatment processes, for example) while maintaining electrochemical performance of the redox flow battery.

The invention relates to a stack of electrochemical cells (10A, 10B), divided up into at least two groups (A, B), each cell comprising a distribution circuit for a reactive species, and each group of cells comprising a separate supply collector (2A; 2B). At least one cell (10B) comprises a homogenization compartment (60B) comprising: a plurality of longitudinal conduits (61B) designed to receive the flow of the reactive species coming from the supply collector (2B) of the corresponding group and to distribute it over the inlet (51B) of the distribution circuit for the cell; and, a transverse conduit (62B) for homogenization connecting the longitudinal conduits (61B) to one another in a fluid sense.

The invention relates to a bipolar plate assembly (1) for forming an electrolysis or fuel cell stack and to the use of a bipolar plate assembly and an electrolysis or fuel cell stack with a plurality of bipolar plate assemblies.

A method of preparing a bipolar plate for a fuel cell is disclosed. The method includes (a) using an electrically conductive filler and a polymer binder to prepare a bipolar plate blank, (b) vacuum-sealing the bipolar plate blank in a metal foil bag, (c) applying hot isostatic pressing to the bipolar plate blank vacuum-sealed in the metal foil bag at a pressure greater than 100 MPa and a temperature of 150-400° C., and (d) peeling the bipolar plate blank that has undergone the hot isostatic pressing from the metal foil bag, and thereby obtaining the bipolar plate. A bipolar plate prepared by the method is also disclosed.

A bipolar plate for a fuel cell for generation of electrical power has a bipolar plate body having a first surface. The bipolar plate body has at least one gas flow channel on the first surface, the gas flow channel defining a first gas flow channel side wall and an opposite second gas flow channel side wall, and the gas flow channel running in a first direction to expose the electrode to the reactant. The bipolar plate also has at least one electrical conductor to run at least partly parallel to the first direction within the bipolar plate body behind the first gas flow channel side wall and/or the second gas flow channel side wall, such that, when a voltage is applied to the electrical conductor, the electrical conductor forms an electromagnetic field, the electromagnetic field to accelerate the reactant at least partly in the direction of the electrode.