Patent classifications
H01M2008/1095
ELECTRODE CATALYST LAYER FOR FUEL CELL, AND SOLID POLYMER-TYPE FUEL CELL COMPRISING SAID ELECTRODE CATALYST LAYER
An electrode catalyst layer for a fuel cell includes a catalyst/support composite including a support and a catalyst supported thereon. The support contains a titanium oxide. The surface of the catalyst/support composite has an oxide of at least one element selected from the group consisting of niobium, tantalum, zirconium, and silicon. The ratio A2/A1 is from 0.35 to 1.70, wherein A1 is the atomic ratio of titanium on a surface of the catalyst layer and A2 is the atomic ratio of a total of niobium, tantalum, zirconium, and silicon on the surface of the catalyst layer, A1 and A2 being measured by X-ray photoelectron spectroscopy. The titanium oxide preferably has a composition TiOx (0.5 ≤ x < 2).
MEMBRANE ELECTRODE AND FRAME ASSEMBLY FOR FUEL CELL STACKS AND METHOD FOR MAKING
Simple membrane electrode and frame assemblies for a solid polymer electrolyte fuel cell stack and improved methods for making them are disclosed which involve the use of a single adhesive layer. Using an appropriate design, the single adhesive layer can provide multiple bonds, including a bond between one of the gas diffusion layers and a catalyst coated membrane assembly, between the catalyst coated portion of the catalyst coated membrane assembly and the frame, and between either the other of the gas diffusion layers and the frame, or between an uncoated portion of the catalyst coated membrane assembly and the frame.
SEPARATOR FOR FUEL CELL AND SINGLE CELL FOR FUEL CELL
A separator for a fuel cell includes a facing surface configured to face a power generating unit of the fuel cell. Groove passages and ribs that protrude toward the power generating unit are provided on the facing surface. At least one of the ribs includes at least one recess in a center of the rib in an arrangement direction of the groove passages. The recess includes a bottom surface, which faces the power generating unit, and two inner side surfaces, which rise from opposite ends in the arrangement direction of the bottom surface. The two inner side surfaces are inclined such that a given point on each inner side surface separates further away from the bottom surface in the arrangement direction as that point approaches the power generating unit in a direction in which the power generating unit and the separator face each other.
LAMINATE, GASKET, AND FUEL CELL
The present invention provides: a laminate for a gasket of a fuel cell, the laminate including a heat seal layer, having excellent moisture and heat resistance, and being suitable for a gasket of a fuel cell; a gasket; a membrane electrode junction including the gasket; and a fuel cell. A laminate includes a base material and a heat seal layer arranged on the base material. The heat seal layer is a reaction product of a heat sealant containing an amorphous polyester polyol (A), an epoxy resin (B), and an isocyanate compound (C). The amorphous polyester polyol (A) is a reaction product of a polyvalent carboxylic acid and a polyhydric alcohol. An amount of aromatic polyvalent carboxylic acid in the polyvalent carboxylic acid is 95% by mass or more. A glass transition temperature of the amorphous polyester polyol (A) is −20° C. or more and 40° C. or less.
ELECTRODES COMPRISING LIQUID/GAS DIFFUSION LAYERS AND SYSTEMS AND METHODS FOR MAKING AND USING THE SAME
The presently disclosed subject matter relates to devices, systems, and methods for fabricating a solid polymer electrolyte electrode assembly are provided. One or more electrode for a solid polymer electrolyte electrode assembly includes a porous substrate configured as a liquid/gas diffusion layer and an ionomer-free catalyst coated on the substrate.
Catalyst layer, membrane electrode assembly, and polyelectrolyte fuel cell
A catalyst layer comprising an interface to a polyelectrolyte membrane, the catalyst layer includes a layer forming material, which includes a catalytic substance, a conductive carrier which supports the catalytic substance, a polyelectrolyte, and a fibrous material, and a plurality of pores which contain no layer forming material. A pore area ratio which is a total area ratio of the plurality of pores to an area of a cross-section orthogonal to the interface is 25.0% or more and 35.0% or less in a cross-sectional image captured by a scanning electron microscope.
Elastomeric cell frame for fuel cell, manufacturing method of the same and unit cell using the same
An elastomeric cell frame for a fuel cell includes an insert which includes: a membrane electrode assembly including a polymer electrolyte membrane and a pair of electrode layers respectively disposed on opposite sides of the polymer electrolyte membrane; and a pair of gas diffusion layers disposed and bonded on upper and lower surfaces of the membrane electrode assembly, respectively. The insert further includes an elastomeric frame disposed in an external region of the insert. The elastomeric frame surrounds one of opposite edge surfaces of the insert and a side surface of the insert, the elastomeric frame being interface-bonded, through thermal bonding, to portions of the polymer electrolyte membrane and the electrode layers exposed at the one of opposite edge surfaces of the insert and the side surface of the insert.
Electrode ink deposition system for high-throughput polymer electrolyte fuel cell
Systems for creating electrodes for polymer electrolyte membrane fuel cells include an XY stage having a heated vacuum table physically coupled to the XY stage. The vacuum table has a working face with a plurality of channels formed therein to communicate vacuum pressure from a port coupled to a vacuum source to the channels. A sheet of perforated heat-conductive material has staggered holes configured to evenly distribute the vacuum pressure from the channels through the perforated sheet. A heat-conductive wire mesh is placed over the perforated sheet, and has openings smaller than the staggered holes such that a membrane material placed on the wire mesh is not deformed by the vacuum pressure. A nanopipette or micropipette coupled to a pump is configured to deposit electrode ink onto an exposed surface of the membrane material as the controller device causes the XY stage to move the vacuum table to control deposition of the electrode ink onto the surface of the membrane material.
Fuel cell system
A fuel cell system configured to enhance the life of a fuel cell is provided. The fuel cell system a fuel cell, an oxidant gas supplier configured to supply oxygen-containing oxidant gas to a cathode of the fuel cell, a fuel gas supplier configured to supply hydrogen-containing fuel gas to an anode of the fuel cell, an oxygen partial pressure estimator configured to estimate an oxygen partial pressure of the cathode of the fuel cell, a hydrogen partial pressure estimator configured to estimate a hydrogen partial pressure of the anode of the fuel cell, and a controller, wherein the controller calculates a target hydrogen partial pressure by a given equation (1), and wherein the controller controls the hydrogen partial pressure of the anode to the target hydrogen partial pressure.
Electrochemical hydrogen pump
An electrochemical hydrogen pump includes an electrolyte membrane, an anode catalyst layer, a cathode catalyst layer, an anode gas diffusion layer, a cathode gas diffusion layer, an anode separator, a cathode separator, a first end plate and a second end plate that are disposed on the respective ends of at least one hydrogen pump unit in which the electrolyte membrane, the catalyst layers, the gas diffusion layers, and the separators are stacked on each other, a fastener that fastens the end plates and at least one hydrogen pump unit, and a voltage applier. The electrochemical hydrogen pump transfers hydrogen from the anode catalyst layer to the cathode catalyst layer and pressurizes hydrogen when the voltage applier applies the voltage. The cathode gas diffusion layer includes a water-repellent carbon fiber layer in a main surface thereof that is on a side of the cathode catalyst layer, and is compressed by the fastener.