A carbon dioxide production system 10A includes: a fuel cell stack 16; a separation unit 20 that separates anode off-gas into a non-fuel gas including at least carbon dioxide and water and a regenerative fuel gas; a second heat exchanger 32 that separates water from the non-fuel gas; a water tank 42; and a carbon dioxide recovery tank 48 that recovers the carbon dioxide after the water has been separated.

The present invention relates to a protective reformer device (10) for the protection of an anode section (112) of a fuel cell stack (110) against oxidizing damage during a heating-up process, having a gas duct (20) with a gas inlet (22) and a gas outlet (24) for conducting fuel gas from an anode feed section (120) of the fuel cell stack (110), wherein a catalytic converter section (30) is arranged in the gas duct (20) for a catalytic oxidation of at least part of the fuel gas into a protective gas for feeding to the anode section (112), wherein, furthermore, the gas duct (20) has a temperature control device (40) in thermally transmitting contact with the catalytic converter section (30) for an active temperature control of the catalytic converter section (30).

A fuel cell system includes: a reformer which generates a reformed gas containing hydrogen by reacting hydrocarbon and moisture with each other; a fuel cell stack which generates electric energy through electrochemical reaction of the reformed gas and an oxidant; an ejector which, using steam as a drive fluid, sucks either a raw fuel containing the hydrocarbon or a recycled gas recovered from an anode exhaust gas, and supplies a resultant gas to the reformer; and a vaporizer which generates the steam by vaporizing water, wherein an operation temperature of the fuel cell stack is higher than a boiling point of water at an operation pressure, and the vaporizer generates the steam through heat exchange with the anode exhaust gas.

A fuel cell system includes a fuel feeder that supplies fuel, a fuel cell stack that generates power through an electrochemical reaction using air and a hydrogen-containing gas generated from the fuel, a temperature sensor that senses the temperature of the fuel cell stack, and a controller. The fuel cell stack has a membrane electrode assembly including an electrolyte membrane through which protons can pass, a cathode on one side of the electrolyte membrane, and an anode on the other side of the electrolyte membrane. The controller defines an upper limit of current output from the fuel cell stack on the basis of the temperature of the fuel cell stack and the supply of the fuel and keeps the current output from the fuel cell stack at or below the upper limit.

A fuel cell system includes a fuel cell having an anode and a cathode configured to output cathode exhaust. The fuel cell is configured to generate waste heat. The fuel cell system further includes a reformer configured to partially reform a feed gas using the waste heat and output a hydrogen-containing stream. The fuel cell system further includes a reformer-electrolyzer-purifier (“REP”) having an REP anode configured to receive a first portion of the hydrogen-containing stream and an REP cathode.

A fuel cell system including: a first fuel cell performing power generation using a fuel gas; a separation membrane separating at least one of carbon dioxide or water vapor from an anode off gas discharged from the first fuel cell; a second fuel cell disposed in the downstream of the separation membrane and performing power generation using the anode off gas, the anode off gas having at least one of carbon dioxide or water vapor separated therefrom; and a distribution channel disposed on a permeation side of the separation membrane and distributing any of the following: a raw material gas serving as the fuel gas to be reformed and used for the power generation of the first fuel cell, a cathode gas including oxygen to be used for the power generation of the first fuel cell, an anode off gas discharged from the second fuel cell, a cathode off gas discharged from the first fuel cell and to be supplied to the second fuel cell, or a cathode off gas discharged from the second fuel cell, in which at least one of permeability coefficient ratio α1 of the separation membrane or permeability coefficient ratio α2 of the separation membrane is 30 or higher.

A reaction device comprising: a first flow path to which a fuel gas is supplied; a second flow path to which a gas containing oxygen is supplied; a hydrogen permeable membrane that separates the first flow path and the second flow path and allows hydrogen contained in the fuel gas supplied to the first flow path to permeate toward the second flow path; and a catalyst that is provided in the second flow path and promotes oxidation reaction between the oxygen and hydrogen passing through the hydrogen permeable membrane, wherein the hydrogen permeable membrane comprises a barium zirconium oxide membrane.

Disclosed is a carbon dioxide utilization system capable of recharging and undergoing reactions. The system includes a cathode unit provided with a first aqueous solution accommodated in a first accommodation space, and a cathode at least a part of which is submerged in the first aqueous solution; an anode unit provided with an alkaline second aqueous solution accommodated in a second accommodation space, and a metal anode at least a part of which is submerged in the second aqueous solution; and a connection unit provided with a connection channel connecting the first and second accommodation spaces in open communication, and a porous ion transfer member, disposed in the connection channel, for blocking the movement of the first and second aqueous solutions but allowing the movement of ions.

A fuel cell system comprising (i) at least one fuel cell stack (30) comprising at least one intermediate-temperature solid oxide fuel cell, and having an anode inlet (41) and a cathode inlet (61) and (ii) a reformer (70) for reforming a hydrocarbon fuel to a reformate, and a reformer heat exchanger (160); and defining: an anode inlet gas fluid flow path from a fuel source (90) to said reformer (70) to said fuel cell stack anode inlet (41); a cathode inlet gas fluid flow path from an oxidant inlet (140, 140′, 140″) through at least one cathode inlet gas heat exchanger (110, 150) to said reformer heat exchanger (160) to said fuel cell stack cathode inlet (61); wherein said at least one cathode inlet gas heat exchanger (110, 150) is arranged to heat relatively low temperature cathode inlet gas by transfer of heat from at least one of (i) an anode off-gas fluid flow path and (ii) a cathode off-gas fluid flow path; wherein said reformer heat exchanger is arranged for heating said anode inlet gas from said relatively high temperature cathode inlet gas to a temperature T.sub.3 at the anode inlet that is below a temperature T.sub.1 at the cathode inlet; and wherein oxidant flow control means (200) for controlled mixing of low temperature oxidant from the or each oxidant inlet (140, 140′, 140″) with high temperature cathode inlet gas to control a temperature T.sub.1 at the cathode inlet (61) relative to a temperature T.sub.3 at the anode inlet (41) and at a level higher than T.sub.3.

A method of maintaining a thermal balance in a solid oxide reversible fuel cell system comprising a solid oxide reversible fuel cell, an air intake for providing air to the solid oxide reversible fuel cell, and a steam reformer fluidly coupled to the solid oxide fuel cell for providing fuel to the solid oxide reversible fuel cell. The method comprising operating the solid oxide reversible fuel cell system in a forward mode in which the steam former receives natural gas and produces hydrogen gas and carbon monoxide to be provided to the solid oxide reversible fuel cell, and operating the solid oxide reversible fuel cell system in a reverse mode in which the steam reformer receives hydrogen gas and carbon dioxide from the solid oxide reversible fuel cell and produces natural gas and water.