An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.

A fuel cell system includes a fuel cell having an anode and a cathode configured to output cathode exhaust. The fuel cell is configured to generate waste heat. The fuel cell system further includes a reformer configured to partially reform a feed gas using the waste heat and output a hydrogen-containing stream. The fuel cell system further includes a reformer-electrolyzer-purifier (“REP”) having an REP anode configured to receive a first portion of the hydrogen-containing stream and an REP cathode.

An electrochemical apparatus includes: a reformer that produces a first hydrogen-containing gas by reforming a raw material; a combustor that heats the reformer; an electrochemical device that includes an anode and a cathode, the electrochemical device operating by using the first hydrogen-containing gas supplied to the anode; a first flow rate controller that controls a flow rate of the first hydrogen-containing gas supplied to the anode and a flow rate of a second hydrogen-containing gas supplied from a supply source, the second hydrogen-containing gas being different from the first hydrogen-containing gas; a second flow rate controller that controls a flow rate at which an anode-off gas exhausted from the anode is recycled to the anode and a flow rate at which the anode-off gas is supplied to the combustor; and a controller that controls the first flow rate controller and the second flow rate controller.

The present invention provides a methanol solid oxide fuel cell and a power generation system comprising the same, wherein the fuel cell is a tubular SOFC cell stack, the tubular SOFC cell stack comprises a plurality of tubular SOFC single cells, and a side wall of an inner pipe of the tubular SOFC single cell at a fuel inlet is of a porous layer structure; an inner wall of the inner pipe is coated with a methanol pyrolysis catalyst layer, and the thickness of the catalyst layer gradually increases along a moving direction of the fuel in the inner pipe. The methanol solid oxide fuel cell can effectively relieve carbon deposition of the anode of the methanol SOFC, and can ensure that the temperature of the whole cell is more uniform and the cell performance is more stable.

A reforming element for a molten carbonate fuel cell stack and corresponding methods are provided that can reduce or minimize temperature differences within the fuel cell stack when operating the fuel cell stack with enhanced CO.sub.2 utilization. The reforming element can include at least one surface with a reforming catalyst deposited on the surface. A difference between the minimum and maximum reforming catalyst density and/or activity on a first portion of the at least one surface can be 20% to 75%, with the highest catalyst densities and/or activities being in proximity to the side of the fuel cell stack corresponding to at least one of the anode inlet and the cathode inlet.

A reformer assembly for a fuel cell includes a vortex tube receiving heated fuel mixed with steam. A catalyst coats the inner wall of the main tube of the vortex tube and a hydrogen-permeable tube is positioned in the middle of the main tube coaxially with the main tube.

A module of the present invention is formed by housing, in a housing container, a cell stack device that includes cell stacks comprising an arrangement of a plurality of cells. The housing container includes a housing chamber that houses the cell stack device; a first gas introduction section provided in a lower portion of the housing chamber and configured to introduce a first gas supplied into the housing chamber; and a first gas circulation section provided on a side of the housing chamber and connected to the first gas introduction section. The width of the first gas circulation section is narrower than the width of the first gas introduction section.

A reactor containing a heat exchanger is disclosed, which can be operated with co-current or counter-current flow. Also disclosed is a system that includes a reactor having a reformer and a vaporizer, a fuel supply, and a water supply. The reactor includes a source of combustion gas, a reformer operative to receive reformate, and a vaporizer operative to receive water. The reformer and vaporizer each include a stack assembly formed by a combination of separator shims and channel shims. The separator shims and channel shims are stacked in a regular pattern to form two sets of channels within the stack assembly. One set of channels will have vertical passageways at either end and a horizontal flowpath between them, while the other set of channels has only a horizontal flowpath.

An apparatus can include a housing, a plurality of electrochemical devices disposed within the housing, and a heat exchanger disposed within the housing. The heat exchanger can be faced with an oxidant-containing gas outlet surface of at least one of the plurality of electrochemical devices. The electrochemical devices can include a stack of solid oxide fuel cells, a battery, or a solid oxide electrolyzer cell.