A reaction device comprising: a first flow path to which a fuel gas is supplied; a second flow path to which a gas containing oxygen is supplied; a hydrogen permeable membrane that separates the first flow path and the second flow path and allows hydrogen contained in the fuel gas supplied to the first flow path to permeate toward the second flow path; and a catalyst that is provided in the second flow path and promotes oxidation reaction between the oxygen and hydrogen passing through the hydrogen permeable membrane, wherein the hydrogen permeable membrane comprises a barium zirconium oxide membrane.

A method of maintaining a thermal balance in a solid oxide reversible fuel cell system comprising a solid oxide reversible fuel cell, an air intake for providing air to the solid oxide reversible fuel cell, and a steam reformer fluidly coupled to the solid oxide fuel cell for providing fuel to the solid oxide reversible fuel cell. The method comprising operating the solid oxide reversible fuel cell system in a forward mode in which the steam former receives natural gas and produces hydrogen gas and carbon monoxide to be provided to the solid oxide reversible fuel cell, and operating the solid oxide reversible fuel cell system in a reverse mode in which the steam reformer receives hydrogen gas and carbon dioxide from the solid oxide reversible fuel cell and produces natural gas and water.

A fuel cell system includes a fuel cell stack, a fuel inlet conduit configured to provide a fuel to a fuel inlet of the fuel cell stack, an electrochemical pump separator containing an electrolyte, a cathode, and a carbon monoxide tolerant anode, a fuel exhaust conduit that operatively connects a fuel exhaust outlet of the fuel cell stack to an anode inlet of the electrochemical pump separator, and a product conduit which operatively connects a cathode outlet of the electrochemical pump separator to the fuel inlet conduit.

An electrochemical hydrogen pump includes: at least one hydrogen pump unit including an electrolyte membrane, an anode, a cathode, an anode separator, and a cathode separator; an anode end plate disposed on the anode separator positioned in a first end in a stacking direction, the first end is one end and the second end is another end; a cathode end plate disposed on the cathode separator positioned in a second end in the stacking direction; a fixing member that prevents at least members from the cathode end plate to the cathode separator positioned in the second end from moving in the stacking direction; a first gas flow channel through which hydrogen generated in the cathode is supplied to a first space disposed between the cathode end plate and the cathode separator positioned in the second end; and a first pressure transmitting member disposed in the first space.

A fuel cell system includes a fuel cell having a cathode and an anode configured to receive a portion of a hhydrocarbon feed and to output an anode exhaust stream comprising carbon dioxide, hydrogen, and water; and an electrolyzer cell having a cathode and an anode. The anode of the electrolyzer cell is configured to receive a first portion of the anode exhaust stream and another portion of the hydrocarbon feed, and to generate a hydrogen stream.

A fuel cell system includes a fuel cell stack, a fuel inlet conduit configured to provide a fuel to a fuel inlet of the fuel cell stack, an electrochemical pump separator containing an electrolyte, a cathode, and a carbon monoxide tolerant anode, a fuel exhaust conduit that operatively connects a fuel exhaust outlet of the fuel cell stack to an anode inlet of the electrochemical pump separator, and a product conduit which operatively connects a cathode outlet of the electrochemical pump separator to the fuel inlet conduit.

Fuel cell systems configured for efficient byproduct recovery and reuse are disclosed herein. In one embodiment, a fuel cell system includes a reformer configured to reform a fuel containing methane (CH.sub.4) with steam to produce a reformed fuel having methane (CH.sub.4), carbon monoxide (CO), and hydrogen (H.sub.2). The fuel cell system also includes a fuel cell configured to perform an electrochemical reaction between a first portion of the reformed fuel and oxygen (O.sub.2) to produce electricity and an exhaust having carbon dioxide (CO.sub.2), water (H.sub.2O), and a second portion of the reformed fuel. The fuel cell system further includes an oxygen enricher configured to generate an oxygen enriched gas and a combustion chamber configured to combust the second portion of the reformed fuel with the oxygen enriched gas.

A fuel cell system including: an electrochemical pump including a first anode, a first cathode, and a first electrolyte membrane including a proton conductive oxide, the electrochemical pump separating hydrogen from a gas containing the hydrogen, and a solid oxide fuel cell that includes a second anode, a second cathode, and a second electrolyte membrane including a solid oxide electrolyte, and that generates electricity by reacting a fuel gas and an oxidant gas with each other.

A fuel cell system and method, the system including a hotbox, a fuel cell stack disposed in the hotbox, an anode tail gas oxidizer (ATO) disposed in the hotbox, and a fuel exhaust processor fluidly connected to the hotbox. The fuel exhaust processor includes a first hydrogen pump configured to extract hydrogen from the anode exhaust received from the fuel cell stack and to output the hydrogen to a first hydrogen stream provided to the fuel cell stack, a second hydrogen pump configured to extract hydrogen from anode exhaust output from the first hydrogen pump and to output the hydrogen to the first hydrogen stream, and a third hydrogen pump configured to extract hydrogen from anode exhaust output from the second hydrogen pump and to output the hydrogen to a second hydrogen stream provided to the ATO.

A fuel cell system includes at least one hot box including a fuel cell stack and producing an anode exhaust product, at least one hydrogen pump, at least one product conduit fluidly connecting an anode exhaust product outlet of the hot box to an inlet of the at least one hydrogen pump, a compressed hydrogen product conduit connected to a compressed hydrogen product outlet of the at least one hydrogen pump, and at least one effluent conduit connected to an unpumped effluent outlet of the at least one hydrogen pump. Additional embodiments include a fuel cell system in which the anode exhaust product stream is provided to at least one carbon dioxide pump to generate a compressed carbon dioxide product and an unpumped effluent that may be recycled to the at least one hot box of the fuel cell system. In various embodiments, the fuel cell system may use or recapture essentially all of the hydrogen content and nearly all of the carbon content of the input fuel that is provided to the fuel cell system.