An electrode catalyst layer for a fuel cell includes a catalyst/support composite including a support and a catalyst supported thereon. The support contains a titanium oxide. The surface of the catalyst/support composite has an oxide of at least one element selected from the group consisting of niobium, tantalum, zirconium, and silicon. The ratio A2/A1 is from 0.35 to 1.70, wherein A1 is the atomic ratio of titanium on a surface of the catalyst layer and A2 is the atomic ratio of a total of niobium, tantalum, zirconium, and silicon on the surface of the catalyst layer, A1 and A2 being measured by X-ray photoelectron spectroscopy. The titanium oxide preferably has a composition TiOx (0.5 ≤ x < 2).

An electrode catalyst layer for a fuel cell includes a catalyst/support composite including a support and a catalyst supported thereon. The support contains a titanium oxide. The surface of the catalyst/support composite has an oxide of at least one element selected from the group consisting of niobium, tantalum, zirconium, and silicon. The ratio A2/A1 is from 0.35 to 1.70, wherein A1 is the atomic ratio of titanium on a surface of the catalyst layer and A2 is the atomic ratio of a total of niobium, tantalum, zirconium, and silicon on the surface of the catalyst layer, A1 and A2 being measured by X-ray photoelectron spectroscopy. The titanium oxide preferably has a composition TiOx (0.5 ≤ x < 2).

Simple membrane electrode and frame assemblies for a solid polymer electrolyte fuel cell stack and improved methods for making them are disclosed which involve the use of a single adhesive layer. Using an appropriate design, the single adhesive layer can provide multiple bonds, including a bond between one of the gas diffusion layers and a catalyst coated membrane assembly, between the catalyst coated portion of the catalyst coated membrane assembly and the frame, and between either the other of the gas diffusion layers and the frame, or between an uncoated portion of the catalyst coated membrane assembly and the frame.

Simple membrane electrode and frame assemblies for a solid polymer electrolyte fuel cell stack and improved methods for making them are disclosed which involve the use of a single adhesive layer. Using an appropriate design, the single adhesive layer can provide multiple bonds, including a bond between one of the gas diffusion layers and a catalyst coated membrane assembly, between the catalyst coated portion of the catalyst coated membrane assembly and the frame, and between either the other of the gas diffusion layers and the frame, or between an uncoated portion of the catalyst coated membrane assembly and the frame.

The presently disclosed subject matter relates to devices, systems, and methods of producing an improved fluid flow assembly and liquid/gas diffusion layer in solid polymer electrolyte electrochemical cells. In one aspect, a fluid flow assembly for a polymer electrolyte water electrolyzer includes a flow field having an inlet, an outlet, and a plurality of discrete lands arranged within the flow field. A liquid/gas diffusion layer is positioned in communication with the flow field between the inlet and the outlet, the liquid/gas diffusion layer having a solid substrate through which a plurality of pores is formed. The disclosed bipolar plate flow field and liquid/gas diffusion layer could work together or separately with other types of porous transport layers or bipolar plates to enhance the water/gas transport. In these configurations, the lands can be arranged and configured such that the plurality of pores are substantially unobstructed by the lands.

In order to prevent injury from hot exhaust gas, water is condensed by a metal net in the exhaust pipe.

A fuel cell flow field plate includes an aluminum substrate plate having a first side and a second side wherein the first side of the aluminum substrate plate defines a plurality of channels for transporting a first fuel cell reactant gas. The flow field plate also includes a first metal interlayer deposited on the first side of the aluminum substrate plate, a second metal interlayer deposited on the second side of the aluminum substrate plate, a first amorphous carbon layer deposited on the first metal interlayer, and a second amorphous carbon layer deposited on the second metal interlayer. The first amorphous carbon layer and second amorphous carbon layer each independently have a density greater than or equal to 1.2 g/cc.

A fuel cell flow field plate includes an aluminum substrate plate having a first side and a second side wherein the first side of the aluminum substrate plate defines a plurality of channels for transporting a first fuel cell reactant gas. The flow field plate also includes a first metal interlayer deposited on the first side of the aluminum substrate plate, a second metal interlayer deposited on the second side of the aluminum substrate plate, a first amorphous carbon layer deposited on the first metal interlayer, and a second amorphous carbon layer deposited on the second metal interlayer. The first amorphous carbon layer and second amorphous carbon layer each independently have a density greater than or equal to 1.2 g/cc.

A fuel cell with high productivity, high power generation performance and high durability is described, along with a gas diffusion electrode base material having a microporous layer on one side of an electrically conductive porous base material, where the electrically conductive porous base material contains carbon fiber and resin carbide and has a density of 0.25 to 0.39 g/cm.sup.3 and a pore mode diameter in a range of 30 to 50 μm. The microporous layer contains a carbonaceous powder and a fluororesin and has a surface roughness of 2.0 to 6.0 μm, a porosity of 50 to 95%, and a pore mode diameter of 0.050 to 0.100 μm.

A fuel cell with high productivity, high power generation performance and high durability is described, along with a gas diffusion electrode base material having a microporous layer on one side of an electrically conductive porous base material, where the electrically conductive porous base material contains carbon fiber and resin carbide and has a density of 0.25 to 0.39 g/cm.sup.3 and a pore mode diameter in a range of 30 to 50 μm. The microporous layer contains a carbonaceous powder and a fluororesin and has a surface roughness of 2.0 to 6.0 μm, a porosity of 50 to 95%, and a pore mode diameter of 0.050 to 0.100 μm.