Methods of making luminescent perovskite-polymer composites are provided and structures using the same. Perovskite-polymer composites made by the method described herein are provided. The perovskite-polymer composite is useful in many applications including downconverters for backlight units (BLU) of liquid crystal displays (LCDs), as well as for and could be used for light emitting devices, lasers or as active absorber or passive luminescent concentrators for solar photovoltaic applications.

The present invention provides a light absorption layer for forming a photoelectric conversion element and a solar cell excellent in photoelectric conversion efficiency, a photoelectric conversion element and a solar cell having the light absorption layer, and a method for manufacturing a light absorption layer having few voids. The light absorption layer of the present invention contains a perovskite compound and a quantum dot containing an aliphatic amino acid.

Disclosed are an organic proton-type ionic liquid, a film with a two-dimensional perovskite pure-phase quantum well structure, a preparation method and use thereof. The chemical formula of the organic proton-type alkylamine acetate ionic liquid is RNH.sub.3.sup.+—RCOO.sup.−, where R represents an alkyl group of C4-8 or a phenyl group, preferably, the chemical formula of the organic proton-type alkylamine acetate ionic liquid is CH.sub.3(CH.sub.2).sub.3NH.sub.3.sup.+—CH.sub.2COO.sup.−. The organic proton-type alkylamino acetate ionic liquid disclosed in the present disclosure can be used to prepare perovskite material, the prepared perovskite film thereby can form a pure-phase single quantum well, and the crystal grain size of the film can reach the level of micrometers or even millimeters.

A solar cell includes a first substrate, a first hole transport layer, a first photoelectric conversion layer containing a perovskite compound, and a second photoelectric conversion layer containing a photoelectric conversion material in this order. A band gap of the perovskite compound is greater than a band gap of the photoelectric conversion material. With respect to an absorption wavelength of the first photoelectric conversion layer 3, a refractive index n.sub.A of the first hole transport layer 2 satisfies refractive index of the first substrate≤n.sub.A≤refractive index of the first photoelectric conversion layer. Further, with respect to a transmission wavelength of the first photoelectric conversion layer 3 and an absorption wavelength of the second photoelectric conversion layer 5, a refractive index n.sub.B of the first hole transport layer 2 satisfies refractive index of the first substrate≤n.sub.B≤refractive index of the first photoelectric conversion layer.

A perovskite-polymer composite comprising a perovskite and a polymer, wherein the polymer has a structural unit comprising a thiourea (—HN(C═S)NH—) fragment and a (—R.sup.1—O—R.sup.2—) fragment, wherein R.sup.1 and R.sup.2 are each independently a C.sub.1-C.sub.6 alkyl or a cycloalkyl linker; a mechanically robust and self-healable solar cell comprising same; and a method of making same.

A semi-transparent perovskite-based photovoltaic cell (or solar cell), wherein the photoactive perovskite layer includes at least one polysaccharide-based inert polymer in an amount ranging between 0.5% by weight and 3.5% by weight, preferably ranging between 1% by weight and 3% by weight, more preferably ranging between 1.5% by weight and 2.8% by weight, with respect to the total weight of the perovskite precursors. The semi-transparent perovskite-based photovoltaic cell (or solar cell) can be advantageously used in various applications that require the production of electricity through the exploitation of light energy, in particular solar radiation energy such as, for example: building integrated photovoltaic (BIPV) systems; photovoltaic windows; greenhouses; photo-bioreactors; noise barriers; lighting; design; advertising; automotive industry. Said semi-transparent perovskite-based photovoltaic cell (or solar cell) can be used either in a “stand alone” mode or in modular systems.

A semi-transparent perovskite-based photovoltaic cell (or solar cell), wherein the photoactive perovskite layer includes at least one polysaccharide-based inert polymer in an amount ranging between 0.5% by weight and 3.5% by weight, preferably ranging between 1% by weight and 3% by weight, more preferably ranging between 1.5% by weight and 2.8% by weight, with respect to the total weight of the perovskite precursors. The semi-transparent perovskite-based photovoltaic cell (or solar cell) can be advantageously used in various applications that require the production of electricity through the exploitation of light energy, in particular solar radiation energy such as, for example: building integrated photovoltaic (BIPV) systems; photovoltaic windows; greenhouses; photo-bioreactors; noise barriers; lighting; design; advertising; automotive industry. Said semi-transparent perovskite-based photovoltaic cell (or solar cell) can be used either in a “stand alone” mode or in modular systems.

This thin film is a thin film for detecting circularly polarized light, and includes a plurality of inorganic layers constituting a layered structure and/or a plurality of inorganic chains constituting a chain structure, which are formed of a perovskite type substance, and chiral molecules incorporated in at least a part of a boundary part between the adjacent inorganic layers and/or between the inorganic chains, wherein the chiral molecules include only one of S-form chiral molecules and R-form chiral molecules or chiral molecules with a higher abundance proportion of one of S-form chiral molecules and R-form chiral molecules than an abundance proportion of the other of S-form chiral molecules and R-form chiral molecules, and wherein the crystal structure of the perovskite type substance is oriented in a predetermined direction.

This thin film is a thin film for detecting circularly polarized light, and includes a plurality of inorganic layers constituting a layered structure and/or a plurality of inorganic chains constituting a chain structure, which are formed of a perovskite type substance, and chiral molecules incorporated in at least a part of a boundary part between the adjacent inorganic layers and/or between the inorganic chains, wherein the chiral molecules include only one of S-form chiral molecules and R-form chiral molecules or chiral molecules with a higher abundance proportion of one of S-form chiral molecules and R-form chiral molecules than an abundance proportion of the other of S-form chiral molecules and R-form chiral molecules, and wherein the crystal structure of the perovskite type substance is oriented in a predetermined direction.

Disclosed is a perovskite precursor solution for improving stability of a perovskite solar cell. Iodoformamidine and cesium iodide are added into a solvent, and bromomethylamine, lead iodide and 3,4-dichloroaniline are added after stirring to obtain the perovskite precursor solution. The perovskite precursor solution is spin-coated on a substrate, obtaining a perovskite thin film by thermal annealing as a light absorption layer of the solar cell. The perovskite precursor solution prepared by the present invention replaces an existing perovskite layer, the defects in the existing perovskite mineralization technology are solved. The perovskite stability improvement leads lower requirements for the process environment and convenient preparation method, realizes the long-time stable performance in a common environment.