A method for producing a nano-porous membrane with one or up to four graphene layers, pores in the membrane having an average pore size in the range of 0.2-50 or 0.3-10 nm, wherein the method involves the following steps: a) generation of a contiguous, essentially non-porous membrane with one or up to four graphene layers; b) distributed point wise defect creation in the non-porous membrane with one or up to four graphene layers by way of irradiation; c) generation and successive growth of the pores at the defects generated in step b) by thermal annealing in the gas phase, e.g. under 02 at a temperature in the range of 250° C. to less than 400° C.

The invention relates to a process for the combined production of hydrogen and carbon dioxide from a hydrocarbon mixture, in which the residual gas of a PSA H.sub.2 (12) is separated by permeation in order to reduce the hydrocarbon content thereof and the hydrocarbon-purified gas is separated at a low temperature to produce a carbon dioxide-rich liquid (22).

Various illustrative embodiments of a system and process for recovering high-quality biomethane and carbon dioxide product streams from biogas sources and utilizing or sequestering the product streams are provided. The system and process synergistically yield a biomethane product which meets gas pipeline quality specifications and a carbon dioxide product of a quality and form that allows for its transport and sequestration or utilization and reduction in greenhouse gas emissions. The system and process result in improved access to gas pipelines for products, an improvement in the carbon intensity rating of the methane fuel, and improvements in generation of credits related to reductions in emissions of greenhouse gases.

Method for separating gaseous carbon dioxide from air, in particular from ambient atmospheric air (1), by cyclic adsorption/desorption using a sorbent material (3), wherein said sorbent material (3) is a solid inorganic or organic, non-polymeric or polymeric support material functionalized on the surface with amino functionalities capable of reversibly binding carbon dioxide, with a specific BET surface area, preferably measured by nitrogen adsorption, in the range of 1-20 m2/g.

A CO.sub.2 separation/recover method in cement production exhaust gas has a step of harmful component removal that removes an acidic component and a harmful component from exhaust gas discharged from a cement production facility; and a step of CO.sub.2 separation and recover that separates and recovers CO.sub.2 by bringing the exhaust gas from which the acidic component and the harmful component are removed into contact with a CO.sub.2 absorption material, so that the acidic component and the harmful component are removed before separating and recovering CO.sub.2, resulting in deterioration of the absorbing ability of the CO.sub.2 absorption material being suppressed; and the cement production exhaust gas can be appropriately disposed.

The invention relates to dispersions of porous solids in liquids selected from deep eutectic solvents, liquid oligomers, bulky liquids, liquid polymers, silicone oils, halogenated oils, paraffin oils or triglyceride oils, as well as to their methods of preparation. In embodiments of the invention, the porous solids are metal organic framework materials (MOFs), zeolites, covalent organic frameworks (COFs), porous inorganic materials, Mobil Compositions of Matter (MCMs) or a porous carbon. The invention also relates to the use of porous materials to form dispersions, and to assemblages of such dispersions with a gas or gases. The dispersions can exhibit high gas capacities and selectivities.

An analysis method and apparatus are disclosed for analysing an absorption filtering medium that filters volatile organic substances in a process gas in a plant for dehumidifying polymer granules, with a fan that generates a flow of gas through the S filtering medium, an analyzer of the total concentration of the organic carbon, a sensor to detect the pressure downstream of the filtering medium, in which the saturation state and/or the absorbent capacity and/or the deterioration over time of the filtering medium is determined by a comparison of the measured concentrations of total organic carbon in the flow of gas upstream and downstream of the filtering medium.

Generating methane by adding hydrogen to CO.sub.2 in exhaust gas discharged a from cement production facility or CO.sub.2 that is separated and recovered from the exhaust gas, and using the methane as an alternative fuel to fossil fuel such as coal, petroleum, natural gas and the like, by methanation of CO.sub.2 in the exhaust gas from the cement production facility that includes exhaust gas originated from lime stone not from the fossil oil and effectively utilizing it, it is possible to reduce usage of the fossil fuel, suppress CO.sub.2 originated from energy, and improve an effect of reducing greenhouse gas.

A system for removing methane oxidation catalyst (MOC) poisons from an exhaust gas including a methane abatement unit that may receive the exhaust gas having methane (CH.sub.4)and the MOC poisons. The methane abatement unit includes a guard bed that may remove the MOC poisons from the exhaust gas and may generate an intermediate exhaust gas having the CH.sub.4 and devoid of the MOC poisons. The guard bed includes a MOC poisons capturing component having a first transition metal oxide, an aluminum oxide (Al.sub.2O.sub.3) support material, and a dolomite-derived support material. The methane abatement unit also includes a MOC bed fluidly coupled to and positioned downstream from the guard bed. The MOC bed includes a MOC and may remove CH.sub.4 from the intermediate exhaust gas to generate a treated exhaust gas having less than approximately 200 parts per million volume (ppmv) CH.sub.4.

A separation and purification coupled process with a high helium yield and diversified products is provided. The process is as follows. Firstly, a low-concentration helium-containing gas after being pressurized and pre-treated enters a two-stage and two-section membrane separation unit to produce a helium product with a medium concentration by concentrating stage by stage through the membrane separation unit. A part of the helium with medium concentration enters an adsorption unit for further concentration to produce a helium product above grade A.