LIGHT VALVE FILMS LAMINATED BETWEEN THIN GLASS AND PLASTIC SUBSTRATES

Abstract

A laminated light valve film comprising: (a) a film having first and second opposed outer surfaces; (b) a first layer of a polymeric interlayer material upon at least a portion of each opposed outer surface; (c) a first pair of substrates, one of which is adhered to the interlayer material upon the first outer opposed surface of the light valve film and the second is adhered to the interlayer material upon the second outer opposed surface of the light valve film, these substrates being formed from plastic or glass; (d) a second layer of polymeric interlayer material applied to at least a portion of an outer surface of each one of the first pair of substrates; and (e) a second pair of substrates, one being adhered to the interlayer upon the outer surface of one of the first pair of substrates and a second one adhered to the interlayer material on the outer surface of a second one of the first pair of substrates, the second pair of substrates being formed from plastic or glass, with the proviso that when the first pair of substrates is formed of plastic, the second pair of substrates is formed of glass, and vice-versa.

Claims

1. A laminated light valve film forming a light-modulating element of a light valve, said laminated film comprising: a) a light valve film having first and second opposed outer surfaces; b) a first layer of a polymeric interlayer material applied to at least a portion of each said first and said second opposed outer surface of said light valve film; c) a first pair of substrates, wherein one of said first pair is applied upon and adhered to the interlayer material applied upon said first outer opposed surface of said light valve film and a second one of said first pair is applied upon and adhered to the interlayer material applied upon said second outer opposed surface of the light valve film, said pair of substrates being formed of a material selected from the group consisting of plastic and glass; d) a second layer of polymeric interlayer material applied to at least a portion of an outer surface of each one of said first pair of substrates; and e) a second pair of substrates, wherein one of said second pair is applied upon and adhered to the interlayer applied upon the outer surface of one of said first pair of substrates and a second one of said second pair is applied upon and adhered to the interlayer material applied upon the outer surface of a second one of said first pair of substrates, said second pair of substrates being formed of a material selected from the group consisting of plastic and glass, with the proviso that when said first pair of substrates is formed of plastic, the second pair of said substrates is formed of glass, and vice-versa.

2. The laminated light valve film according to claim 1, wherein the film comprises: a) a cured suspended particle device emulsion having a plurality of uncrosslinked droplets of a liquid light valve suspension distributed throughout the cured emulsion; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured emulsion wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured emulsion, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured emulsion.

3. The laminated light valve film according to claim 1, wherein the film comprises: a) droplets containing liquid crystals dispersed in a cured polymer; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured polymer wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured polymer, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured polymer.

4. The laminated light valve film according to claim 1, wherein the light valve film further comprises a conductive material affixed to the electrodes such that the material extends beyond the perimeter of the laminated light valve film to permit connection of said film to a suitable voltage source.

5. The laminated light valve film according to claim 1, wherein the first pair of substrates is formed of glass and the second pair of substrates is formed of plastic.

6. The laminated light valve film according to claim 1, wherein the first pair of substrates is formed of plastic and the second pair of substrates is formed of glass.

7. The laminated light valve film according to claim 1, wherein the glass used in forming said substrates is selected from the group consisting of tempered glass, annealed glass, low iron glass, low e glass, UV blocking glass, chemically strengthened glass and antimicrobial glass.

8. The laminated light valve film according to claim 1, wherein the thickness of each glass substrate ranges from 0.55 mm to 2.0 mm.

9. The laminated light valve film according to claim 8, wherein the thickness of each glass substrate ranges from 0.55 mm to 1.10 mm.

10. The laminated light valve film according to claim 1, wherein the plastic used in forming said substrates is selected from the group consisting of polycarbonate, polymethyl methacrylate, polystyrene and polypropylene.

11. The laminated light valve film according to claim 1, wherein the thickness of each plastic substrate ranges from 1.0 mm to 10.0 mm.

12. The laminated light valve film according to claim 11, wherein the thickness of each plastic substrate ranges from 1.0 mm to 5.0 mm.

13. The laminated light valve film according to claim 1, wherein the glass substrates and the plastic substrates each have a thickness ranging from 0.10 mm to 0.55 mm to permit bending of the laminated light valve film for use in curved applications without damage to said film.

14. The laminated light valve film according to claim 1, wherein the material used in forming the plastic substrates has a softening point at least 10° C. higher than that of the polymeric interlayer material.

15. The laminated light valve film according to claim 14, wherein the polymeric interlayer material is selected from the group consisting of ethylene vinylacetate (EVA), polyvinyl butyral (PVB) and polyurethane.

16. A laminated light valve film forming a light modulating element of a light valve, said laminated film comprising: a) a light valve film having first and second opposed outer surfaces; b) a layer of a polymeric interlayer material applied to at least a portion of said first and said second opposed outer surfaces of said light valve film; and c) a pair of substrates wherein one of said pair is applied upon and adhered to the interlayer material applied upon the first outer opposed surface of said light valve film and a second one of said substrates is applied upon and adhered to the interlayer material applied upon the second opposed surface of the light valve film, said substrates each formed of a plastic coated on one or both sides with at least one layer of glass, said glass coatings ranging in thickness from 0.5 microns to 2.4 microns.

17. The laminated light valve film according to claim 16 wherein a plastic portion of each of said substrates has a thickness ranging between 1.0 mm to 10.0 mm.

18. The laminated light valve film according to claim 17 wherein the plastic portion of each of said substrates has a thickness ranging from 1.0 mm to 5.0 mm.

19. The laminated light valve film according to claim 16, wherein the glass coating on each said substrate has a thickness ranging from 0.5 microns to 1.5 microns.

20. The laminated light valve film according to claim 16, wherein the film comprises: a) a cured suspended particle device emulsion having a plurality of uncrosslinked droplets of a liquid light valve suspension distributed throughout the cured emulsion; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured emulsion wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured emulsion, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured emulsion.

21. The laminated light valve film according to claim 16, wherein the film comprises: a) droplets containing liquid crystals dispersed in a cured polymer; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured polymer wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured polymer, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured polymer.

22. The laminated light valve film according to claim 16, wherein the light valve film further comprises a conductive material affixed to the electrodes such that the material extends beyond the perimeter of the laminated light valve film to permit connection of said film to a suitable voltage source.

23. The laminated light valve film according to claim 16, wherein the glass used in coating said plastic is selected from the group consisting of tempered glass, annealed glass, low iron glass, low e glass, UV blocking glass, chemically strengthened glass and antimicrobial glass.

24. The laminated light valve film according to claim 16, wherein the plastic used in forming the substrates is selected from the group consisting of polycarbonate, polymethyl methacrylate, polystyrene and polypropylene.

25. The laminated light valve film according to claim 16, wherein the material used in forming the plastic substrates has a softening point of at least 10° C. higher than that of the polymeric interlayer material.

26. The laminated light valve film according to claim 25, wherein the polymeric interlayer material is selected from the group consisting of ethylene vinylacetate (EVA), polyvinyl butyral (PVB) and polyurethane.

27. A laminated light valve film forming a light modulating element of a light valve, said laminated film comprising: a) a light valve film having first and second opposed outer surfaces; b) a layer of a polymeric interlayer material applied to at least a portion of said first and said second opposed outer layers of said light valve film; and c) a pair of substrates wherein one of said pair is applied upon and adhered to the interlayer material applied upon the first outer opposed surface of said light valve film and a second one of said substrates is applied upon and adhered to the interlayer material applied upon the second opposed surface of the light valve film, said substrates each formed of glass coated on one or both sides with at least one layer of plastic, the glass of each said substrate ranging in thickness from 0.55 mm to 2.0 mm.

28. The laminated light valve film according to claim 27, wherein the plastic coating on either side of the glass may have the same thickness or wherein the thickness on one side may be different from the thickness of the coating on the other side.

29. The laminated light valve film according to claim 27, wherein the plastic coating on each said substrate has a thickness ranging from 1 micron to 25 microns.

30. The laminated light valve according to claim 29, wherein the plastic coating on each said substrate has a thickness ranging from 10 microns to 25 microns.

31. The laminated light valve film according to claim 27, wherein the film comprises: a) a cured suspended particle device emulsion having a plurality of uncrosslinked droplets of a liquid light valve suspension distributed throughout the cured emulsion; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured emulsion wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured emulsion, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured emulsion.

32. The laminated light valve film according to claim 27, wherein the film comprises: a) droplets containing liquid crystals dispersed in a cured polymer; and b) first and second plastic sheets, said sheets located outwardly from and sandwiching said cured polymer wherein, located upon an inner surface of each said first and said second plastic sheet, adjacent said cured polymer, is a layer of a thin, transparent, electrically conductive coating, said coatings serving as an electrode to permit passage of an applied electric field through said cured polymer.

33. The laminated light valve film according to claim 27, wherein the light valve film further comprises a conductive material affixed to the electrodes such that the material extends beyond the perimeter of the laminated light valve film to permit connection of said film to a suitable voltage source.

34. The laminated light valve according to claim 27, wherein the glass used in forming the substrates is selected from the group consisting of tempered glass, annealed glass, low iron glass, low e glass UV blocking glass, chemically strengthened glass and antimicrobial glass.

35. The laminated light valve film according to claim 27, wherein the plastic is formed from a material selected from the group consisting of polycarbonate, polymethyl methacrylate, polystyrene and polypropylene.

36. The laminated light valve film according to claim 27, wherein the plastic material used in coating the substrates has a softening point of at least 10° C. higher than that of the polymeric interlayer material.

37. The laminated light valve film according to claim 36, wherein the polymeric interlayer material is selected from the group consisting of ethylene vinylacetate (EVA), polyvinyl butyral (PVB) and poly urethane.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0027] Glass sheets with thicknesses of 0.55 mm and 1.10 mm were obtained from Corning Glass, Corning, N.Y., under the trade name of Gorilla® Glass. Furthermore, acrylic plastic sheets, 3.175 mm thick, sold under the trade name Acrylite® OP-2, were obtained from Evonik Performance Materials, Parsippany, N.J. Impact-resistant clear polycarbonate plastic sheets, 1.5875 mm thick, were obtained from McMaster-Carr, Dayton, N.J. Glass NMR tubes with a thickness of 0.24 mm were obtained from Wilmad Glass, Vineland, N.J. Standard glass sheets with a thickness of 2.38 mm were used for the control laminations.

[0028] Initial heat/high humidity tests were performed on the NMR glass tubes, standard 2.38 mm thick glass laminates and laminates prepared with the glass and plastic substrates described above to determine the ability of these samples to prevent moisture penetration. The laminates so prepared incorporated a moisture-sensitive indicator strip into the lamination stack that was positioned adjacent to the SPD film within the laminate. The indicator strips were also sealed inside of the NMR tubes. The strips used for these laminations were Humidity Detection strips, 20%-80%, Part#33813-2080 obtained from Indigo Instruments, www.indigo.com.

[0029] Standard SPD light valve laminates were prepared as described in the aforementioned U.S. Pat. No. 7,361,252 patent. A non-limiting summary of the procedure for laminating SPD films is found in U.S. Pat. No. 7,361,252, assigned to the assignee of the present invention, involves creating a “stack” comprising in sequence a first glass sheet, a first sheet of interlayer, the SPD film comprising cured SPD emulsion sandwiched between two ITO-coated PET substrate sheets with copper foil bus bars attached to and protruding from the ITO coatings, a second sheet of interlayer and a second glass sheet, all positioned substantially congruent to one another. The stack was placed in a vacuum bag within a Carver Press and a strong vacuum was applied (greater than 29 inches of mercury). The platens of the press were then arranged to touch the outsides of the unlaminated stack and their temperature elevated to affect melting of the interlayers within the stack. The platens were then cooled to solidify the interlayers which adheres the stack into an SPD laminate.

[0030] In addition, laminates formed with glass and plastic substrates were also prepared. A non-limiting example of the layup for one of these laminates would be thin glass/interlayer/plastic/interlayer/SPD film/interlayer/plastic/interlayer/thin glass. As used herein a “thin” glass sheet means a glass sheet with a thickness of <1.10 mm.

[0031] In order to prevent moisture from entering through the edge of the sample laminates, frames of polyisobutylene (PM) were incorporated into the laminate, as described in US Publication No. US 2016/0282645 A1. The frames of the polyisobutylene moisture-resistant material were incorporated into the stack beginning at the outer edge of the glass to a position adjacent to the SPD film within the laminate. Taking into account, then, the presence of the PM frames, any moisture penetration into the laminate would thus be attributable to moisture entering the laminate through the face of the laminate, not through the edge of the laminate. Two frames are used so that the copper foil protruding outside the laminate is surrounded on both sides by the PIB material.

[0032] The initial ΔT or visible transmittance range (ON state transmittance-OFF state transmittance) of each SPD light valve laminate was measured with The Color Sphere Visible Spectrophotometer, manufactured by Byk-Gardner, by applying an electric field of 100V/60 Hz to the protruding busbars of the laminate to obtain the ON-state transmittance. These optical measurements were repeated periodically during the humidity test.

[0033] The procedure used to test the samples in a high temperature/humidity environment, as disclosed in US Publication No. US 2016/0282645 A1, assigned to the assignee of the present invention, is as follows: SPD laminates, laminates without SPD film and other samples with different configurations were placed in an upper portion of a desiccator that had a reservoir of water in the lower section thereof. A ceramic plate with holes prevented the samples from coming in direct contact with the water in the bottom section of the desiccator. Placing this desiccator in a 60° C. oven creates a high temperature, high humidity environment that SPD films and SPD laminates would not normally be exposed to in the field. However, these extreme conditions were created so that meaningful test results would be obtained in a reasonable period of time. The moisture-saturated desiccator containing the samples was placed in a 60° C. oven and the samples were periodically evaluated for one or more of 1) the presence of moisture within the laminate as detected by the moisture indicator strips, 2) the change in the appearance of the clear interlayer within the laminate from clear to cloudy/hazy and 3) the AT change of the SPD film within the laminate. A positive (+) ΔT change indicates that the range of light transmission for the SPD film has increased during exposure to the 60° C. temperature during the test. This is due to the improved dispersion of the polyiodide particles within the SPD film and should not be viewed as a loss in functionality.

RESULTS AND DISCUSSION

[0034]

TABLE-US-00001 TABLE 1 Results of 60° C. High Humidity Test (glass, glass/plastic laminates) Days of Clear 60° C., Moisture Inter- High Indicated layer Humidity From Became Laminate Details Exposure Strip Hazy NMR tube 0.24 mm, flame sealed, 435 No — indicator only Gorilla ® Glass 0.55 lam, indicator 247 Yes Yes only Gorilla ® Glass 1.10 lam, indicator 247 Yes Yes only Standard glass/Standard glass lam, 260 Yes Yes indicator only (Leads) Gorilla ® Glass 0.55-Standard Glass 284 Yes Yes lam, indicators only (thin-thick) Acrylite ®/Acrylite ® lam, 6 Yes Yes indicator only Polycarbonate/Polycarbonate 2 Yes Yes lam, indicator only Gorilla ® Glass 0.55/Acrylite ®/ 163 Yes Yes Acrylite ®/Gorilla ® Glass 0.55 lam, indicator only Gorilla ® Glass 0.55/Acrylite ®/ 181 Yes Yes Acrylite ®/Gorilla ® Glass 0.55 lam, indicator only (Leads)

[0035] All laminations (lam) are PM frame protected

“Gorilla® Glass 0.55-Regular Glass lam” is also marked as “thin-thick glass lam”.
“Gorilla® Glass 0.55” is Gorilla® Glass of 0.55 mm thickness.
“Gorilla® Glass 1.10” is Gorilla® Glass of 1.10 mm thickness.
“Standard glass” is 2.38 mm thickness
“Acrylite®” is acrylic plastic of 3.175 mm thickness
“Polycarbonate” plastic is 1.5875 mm thick

[0036] Table 1 provides the 60° C. high humidity test results for non-SPD film containing laminates and other samples. The tests with the NMR glass tubes show that glass thicknesses as low as 0.24 mm are still very effective as moisture barriers. For example, the flame sealed 0.24 mm thick NMR glass tube has been in the 60° C. high humidity chamber for 435 days with no color change observed for the moisture strip and the test continues.

[0037] Two laminates made with Gorilla® Glass substrates, 0.55 mm thick and 1.10 mm thick, were exposed in the 60° C. high humidity chamber for 247 days before a color change was observed and the moisture strip and the clear interlayer in these laminates became hazy. The laminate in Table 1 labeled, “(thin-thick)” is comprised of 0.55 mm thin glass and 2.38 mm standard glass and a separate moisture indicator strip was placed adjacent to each of the glass substrates. If moisture passes through the thin glass substrate first, the moisture strip adjacent to the thin glass will change color before the moisture strip adjacent to the thick glass substrate changes color. This laminate was exposed in the 60° C. high humidity chamber for 284 days before a color change was observed for both moisture strips. Conversely, the indicator strip within the laminates made with acrylic substrates)(Acrylite®/Acrylite®) and polycarbonate substrates (polycarbonate/polycarbonate) turned color after 6 days and 2 days of exposure in the 60° C. high humidity chamber respectively. The clear interlayer in both of these laminates turned hazy. This demonstrates that plastic substrates of varying thicknesses allow moisture penetration after a short time.

[0038] Finally, the acrylic and glass hybrid laminates made with the following configuration: Gorilla® Glass 0.55/Acrylite®/Acrylite®/Gorilla® Glass 0.55, were exposed in the 60° C. high humidity chamber for 163 days and 181 days respectively before color change was observed for the moisture strip and the clear interlayer in these laminates became hazy. One of the hybrid laminates described above also had copper foil busbars protruding from the laminate to simulate the presence of an SPD film inside the laminate. As mentioned above, this laminate had been in the 60° C. high humidity chamber for 181 days before a color change was observed for the moisture strip. A double frame of PM was used on this laminate to prevent moisture from entering the edge of the laminate where the copper foil exits the laminate. The data clearly shows that the 60° C. temperature and high humidity environment of this test allowed moisture to pass through the face of the plastic substrate laminates after only several days of exposure. The fact that the thinnest all-glass 0.24 mm NMR tube sample tested lasted over 435 days without allowing moisture penetration confirms that glass is ideal for moisture prevention. Although the laminates made with glass alone or glass and plastic eventually showed the presence of moisture within the laminates, the fact that a minimum of 161 days was required for detection by the moisture strips strongly suggests that the moisture entered the laminates through the edges of the laminates. Although, as described above, PIB frames were incorporated into the laminates to prevent moisture ingress via the edge of the laminates, the severity of the test conditions likely allowed the moisture to eventually pass between the substrates and through the edge of the laminates. The same explanation also applies to the applicable results below for Table 2.

TABLE-US-00002 TABLE 2 Results of 60° C. High Humidity Test (SPD: glass, glass/plastic laminates) Moisture ΔT Indicated Cloudy change- from Interlayer days Laminate Details Strip Appearance and status Std. Glass/SPD/ No No +5.60, Std. Glass, lam 306 days Yes Yes −14.02, 392 days Acrylite ®/SPD/ 6 days Yes −6.50, Acrylite ® lam 27 days Yes Yes Malfunction, discontinued at 83 days Gorilla ® Glass 0.55/ No No +4.18, Acrylite/SPD/ 141 days Acrylite ®/Gorilla ® Yes Yes +5.30, Glass 0.55 lam 212 days Yes Yes Malfunction, discontinued at 227 days, Acrylite ®/Gorilla ® No Yes −2.82, Glass 0.55/SPD/ 55 days Gorilla ® Glass 0.55/ No Yes −8.70, Acrylite ® lam, (reverse) 306 days Yes Yes Malfunction, discontinued at 392 days

[0039] All laminations (lam) were double PM frame protected and had copper leads protruding from the edge

“Gorilla® Glass 0.55” is Gorilla® Glass of 0.55 mm thickness.
“Gorilla® Glass 1.10” is Gorilla® Glass of 1.10 mm thickness.
“Std. Glass” is a standard glass of 2.38 mm thickness
“Acrylite®” is acrylic plastic of 3.175 mm thickness

[0040] Table 2 provides the 60° C. high humidity test results for SPD film-containing laminates. The results are similar to those obtained for the non-SPD-containing laminates in Table 1. For example, the SPD laminate made with glass substrates (Glass/SPD/Glass) exposed in the 60° C. high humidity chamber for 306 days had no color change observed for the moisture strip, the clear interlayer in these laminates had not become hazy and the SPD film within the laminates has gained 5.60 transmittance points. After 392 days of exposure, a color change was observed for the moisture strip, the clear interlayer in the laminate became hazy and the SPD film within the laminate lost 14.02 transmittance points. As described for the Table 1 results above, moisture entering through the edge of the laminate was responsible for the 392 day exposure results.

[0041] The glass and acrylic hybrid laminate made with the following configuration: Gorilla® Glass 0.55/Acrylite®/SPD/Acrylite®/Gorilla® Glass 0.55, had been in the 60° C. high humidity chamber for 141 days with no color change observed for the moisture strip, the clear interlayer in the laminate did not become hazy and the SPD film within the laminate gained 4.18 transmittance points. After 212 days of exposure color change was observed for the moisture strip, the clear interlayer in the laminate became hazy but the SPD film within the laminate still had gained 5.30 transmittance points. Finally, after 227 days of exposure, the SPD film within the laminate no longer functioned when the voltage was applied. It is believed that the moisture present inside the laminate for 15 days eventually caused a malfunction, such as a short-circuit, which rendered the SPD sample inoperable and had we been able to measure the visible transmittance of the SPD film there would have been a significant loss of transmittance points.

[0042] In the case of the acrylic and glass hybrid laminate made with the following configuration: Acrylite®/Gorilla® Glass 0.55/SPD/Gorilla® Glass 0.55/Acrylite®, the laminate had been in the 60° C. high humidity chamber for 55 days and no color change was observed for the moisture strip, but the clear interlayer in the laminate became hazy and the SPD film within the laminate lost 2.82 transmittance points. Since this laminate has Acrylite® plastic as the outermost substrates, moisture was able to penetrate through the Acrylite® and cause the clear interlayer between the Acrylite® and the Gorilla® Glass to become cloudy, which is believed to be responsible for the measured loss of transmission for the SPD film. However, the Gorilla® Glass prevented the moisture from penetrating any further into the laminate where the SPD film is positioned. After 306 days of exposure still no color change was observed for the moisture strip, the clear interlayer in the laminate remained hazy and the SPD film within the laminate now lost 8.70 transmittance points. Finally, after 392 days of exposure, color change was observed for the moisture strip and the SPD film within the laminate no longer functioned when the voltage was applied presumably due to a short-circuit. For applications where an SPD laminate with an impact and scratch resistant outer surface is desired this configuration is preferred.

[0043] Finally, for an Acrylite®/SPD/Acrylite® laminate, after just 6 days of exposure in the 60° C. high humidity chamber, color change was observed for the moisture strip, the clear interlayer in the laminate became hazy and after 27 days of exposure the SPD film within the laminate had lost 6.50 transmittance points. This confirms that SPD laminates made with only plastic substrates quickly allow moisture to pass through the face of substrates and adversely affect the appearance and performance of the SPD laminate. These results show that SPD laminates made with a combination of thin glass and plastic laminates protect the SPD film from degradation due to moisture exposure while, at the same time, providing, light weight, strength, impact resistance and UV protection.