SEMICONDUCTOR PACKAGE WITH NICKEL-SILVER PRE-PLATED LEADFRAME
20220208665 · 2022-06-30
Inventors
Cpc classification
H01L2924/00015
ELECTRICITY
H01L2224/29291
ELECTRICITY
H01L2224/29191
ELECTRICITY
H01L2224/2919
ELECTRICITY
H01L2224/2919
ELECTRICITY
H01L2224/85486
ELECTRICITY
H01L2924/20752
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2224/85486
ELECTRICITY
H01L2924/20752
ELECTRICITY
H01L2224/83192
ELECTRICITY
H01L21/4825
ELECTRICITY
H01L24/73
ELECTRICITY
H01L2924/00015
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/29388
ELECTRICITY
H01L2924/20753
ELECTRICITY
H01L2224/29291
ELECTRICITY
H01L2224/29388
ELECTRICITY
H01L2224/85395
ELECTRICITY
H01L2224/83395
ELECTRICITY
H01L2224/2929
ELECTRICITY
H01L2224/2929
ELECTRICITY
H01L2224/83486
ELECTRICITY
H01L2224/29191
ELECTRICITY
H01L2924/20753
ELECTRICITY
H01L2224/83486
ELECTRICITY
H01L2924/00014
ELECTRICITY
H01L2924/00012
ELECTRICITY
H01L2224/92247
ELECTRICITY
H01L2224/48465
ELECTRICITY
International classification
H01L21/48
ELECTRICITY
Abstract
A semiconductor package includes a pad and leads, the pad and leads including a base metal predominantly including copper, a first plated metal layer predominantly including nickel in contact with the base metal, and a second plated metal layer predominantly including silver in contact with the first plated metal layer. The first plated metal layer has a first plated metal layer thickness of 0.1 to 5 microns, and the second plated metal layer has a second plated metal layer thickness of 0.2 to 5 microns. The semiconductor package further includes an adhesion promotion coating predominantly including silver oxide in contact with the second plated metal layer opposite the first plated metal layer, a semiconductor die mounted on the pad, a wire bond extending between the semiconductor die and a lead of the leads, and a mold compound covering the semiconductor die and the wire bond.
Claims
1. A semiconductor package comprising: a pad and leads comprising: a base metal predominantly including copper; a first plated metal layer in contact with the base metal, the first plated metal layer predominantly including nickel, wherein the first plated metal layer has a first plated metal layer thickness of 0.1 to 5 microns; a second plated metal layer in contact with the first plated metal layer, the second plated metal layer predominantly including silver, wherein the second plated metal layer has a second plated metal layer thickness of 0.2 to 5 microns; and an adhesion promotion coating in contact with the second plated metal layer opposite the first plated metal layer, the adhesion promotion coating predominantly including silver oxide; a semiconductor die mounted on the pad; a wire bond extending between the semiconductor die and a lead of the leads; and a mold compound covering the semiconductor die and the wire bond.
2. The semiconductor package of claim 1, wherein the first plated metal layer includes a nickel alloy.
3. The semiconductor package of claim 2, wherein the nickel alloy includes one or more of a group consisting of: cobalt; molybdenum; a lanthanide; and tungsten.
4. The semiconductor package of claim 1, wherein the first plated metal layer is substantially free of nickel oxide.
5. The semiconductor package of claim 1, wherein the first plated metal layer thickness is 0.2 to 4 microns, and wherein the second plated metal layer thickness is 0.5 to 1.5 microns.
6. The semiconductor package of claim 1, wherein the adhesion promotion coating has an adhesion promotion coating thickness of 1.0 to 3.0 nanometers (nm).
7. The semiconductor package of claim 1, wherein the first plated metal layer covers at least 90 percent of a total surface area of the base metal, wherein the second plated metal layer covers at least 90 percent of a total surface area of the first plated metal layer, and wherein the adhesion promotion coating covers at least 90 percent of a total surface area of the second plated metal layer.
8. The semiconductor package of claim 1, wherein the wire bond is a copper wire bond.
9. The semiconductor package of claim 1, wherein the wire bond is an aluminum wire bond.
10. The semiconductor package of claim 1, wherein the wire bond is a gold wire bond.
11. A method for manufacturing a semiconductor package, the method comprising: forming a ball bond of a wire on a semiconductor die attached to a metal pad of a pre-plated leadframe; forming a stitch bond of the wire on a lead of the pre-plated leadframe to complete a wire bond between the semiconductor die and the lead; and covering the semiconductor die and wire bond in a mold compound, wherein the pre-plated leadframe includes: a base metal predominantly including copper; a first plated metal layer in contact with the base metal, the first plated metal layer predominantly including nickel, wherein the first plated metal layer has a first plated metal layer thickness of 0.1 to 5 microns; a second plated metal layer in contact with the first plated metal layer, the second plated metal layer predominantly including silver, wherein the second plated metal layer has a second plated metal layer thickness of 0.2 to 5 microns; and an adhesion promotion coating in contact with the second plated metal layer opposite the first plated metal layer, the adhesion promotion coating predominantly including silver oxide.
12. The method of claim 11, further comprising: cleaning the base metal; immersing the base metal in a first solution containing nickel; electroplating the base metal to form the first plated metal layer on the base metal; immersing the base metal and the first plated metal layer in a second solution containing silver; electroplating the base metal and the first plated metal layer to form the second plated metal layer on the first plated metal layer; and reacting the second plated metal layer to form the adhesion promotion coating including the silver oxide.
13. The method of claim 11, further comprising covering the semiconductor die and the wire bond, and partially covering the pad and lead with a mold compound, with the pad and the lead remaining exposed on an outer surface of the semiconductor package.
14. The method of claim 11, wherein the first plated metal layer includes a nickel alloy.
15. The method of claim 14, wherein the nickel alloy includes one or more of a group consisting of: cobalt; molybdenum; a lanthanide; and tungsten.
16. The method of claim 11, wherein the first plated metal layer is substantially free of nickel oxide.
17. The method of claim 11, wherein the first plated metal layer thickness is 0.2 to 4 microns, and wherein the second plated metal layer thickness is 0.5 to 1.5 microns.
18. The method of claim 11, wherein the adhesion promotion coating has an adhesion promotion coating thickness of 1.0 to 3.0 nanometers (nm).
19. The method of claim 11, wherein the first plated metal layer covers at least 90 percent of a total surface area of the base metal, wherein the second plated metal layer covers at least 90 percent of a total surface area of the first plated metal layer, and wherein the adhesion promotion coating covers at least 90 percent of a total surface area of the second plated metal layer.
20. The method of claim 11, wherein the wire is a copper wire.
21. The method of claim 11, wherein the wire is an aluminum wire.
22. The method of claim 11, wherein the wire is a gold wire.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0015]
[0016]
[0017]
[0018]
[0019]
DETAILED DESCRIPTION
[0020] A number of technical trends have made reliable semiconductor package construction more difficult. As examples, the package dimensions are shrinking, offering less surface for adhesion. Then, the desire to use Pb-free solders pushes the reflow temperature range into the neighborhood of about 260° C., making it more difficult to maintain mold compound adhesion to the leadframes. This is especially true for the very small leadframe surface available in Quad Flat No-lead (QFN) and Small Outline No-lead (SON) devices. Moreover, prices and demand for metals commonly used in pre-plated leadframe finishes, including palladium (Pd), are expected to continue to rise.
[0021] Recognizing the high cost associated with selective plating silver spots, and of pre-plating whole leadframes with stacked Ni—Pd—Au finishes, Applicant has developed novel and innovative techniques for a pre-plated leadframe.
[0022] As disclosed herein, a pre-plated leadframe includes a base metal of predominately copper, a first plated metal layer predominantly including nickel in contact with the base metal, a second plated metal layer predominantly including silver in contact with the first plated metal layer, and adhesion promotion coating in contact with the second plated metal layer opposite the first plated metal layer, the adhesion promotion coating including silver oxide. As referred to herein, an adhesion promotion coating is a coating with stronger mechanical bonding to mold compound than the immediately adjacent layer, in this case, the plated metal layer predominantly including silver.
[0023] The preferred thickness range of the first plated metal layer on the base metal is between about 0.10 and 5.0 μm, and the second plated metal layer between about 0.20 and 5.0 μm. The nickel protects the base metal copper from oxidation, and further protects the silver layer from diffusion in the copper alloy during wire bonding, allowing for a thinner silver layer than is common with selective plating silver spots. The adhesion promotion coating is in contact with the silver layer to promote adhesion between exposed portions of the leadframe and mold compound. One such example of the disclosed techniques is plated metallic leadframe 108, as illustrated in
[0024]
[0025] Leadframe 108 includes a base metal 122 forming the different elements of leadframe 108, including metal pad 110, leads 111 and pad straps 115 (
[0026] In some examples, base metal 122 predominantly includes copper, such as a copper alloy. Examples of suitable copper alloys for base metal 122 include aluminum bronze (copper ninety-two percent by weight, aluminum eight percent by weight), beryllium copper (copper ninety-eight percent by weight, beryllium two percent by weight), cartridge brass (copper seventy percent by weight, zinc thirty percent by weight), cupronickel (copper seventy percent by weight, nickel thirty percent by weight), gunmetal (copper ninety percent by weight, tin ten percent by weight). nickel silver (copper seventy-eight percent by weight, nickel twelve percent by weight, lead ten percent by weight), as well as copper alloys C19210, C19400, and C70250 under the unified numbering system. In other examples, base metal 122 may predominantly include iron-nickel alloys (for instance the so-called “Alloy 42”), or aluminum.
[0027] Plated metal layer 124 is in contact with base metal 122. Plated metal layer 124 predominantly includes nickel, such as a nickel alloy. A thickness 125 of plated metal layer 124 is 0.1 to 5 microns, such as 0.2 to 4 microns, such as 0.5 to 1.5 microns, such as about 1.0 micron. In various example, the nickel alloy may include one or more of: cobalt, molybdenum, a lanthanide, and tungsten (W). The hardness of plated metal layer 124 should be below 500 Vickers. With higher hardness, wire bonding may cause delamination between plated metal layer 124 and plated metal layer 126. As leadframe 108 is a pre-plated leadframe, plated metal layer 124 covers all or a majority of the surfaces of base metal 122, such as at least 90 percent of the total surface area of base metal 122. Uncovered portions of leadframe 108 may occur as a result of package manufacturing processes that include cutting or grinding pre-plated leadframe 108, such as singulation, which may include cutting tie bars of leadframe 108.
[0028] Including an alloy with the nickel in plated metal layer 124 reduces a thickness 125 required to mitigate diffusion of silver of plated metal layer 126 into base metal 122, particularly during wire-bonding. For example, whereas a thickness of up to 5 microns of pure nickel may be required to mitigate diffusion of silver of plated metal layer 126 into base metal 122, a much thinner alloyed nickel, as low as about 0.1 microns may be suitable to mitigate diffusion of silver of plated metal layer 126 into base metal 122 during wire bonding. Thus, utilizing a nickel alloy for plated metal layer 124 may reduce the amount of nickel required, saving on costs, and improve dimensional control compared to using pure nickel for plated metal layer 124.
[0029] Since plated metal layer 126 covers plated metal layer 124, plated metal layer 124 is substantially free of oxidized surface film (nickel oxide). As referred to herein, substantially free means at proportions that do not interfere with the practical function of the base material. For plated metal layer 124, its practical functions include electrical conductivity, mitigating diffusion of silver of plated metal layer 126 into base metal 122 during wire bonding, and absence of delamination at the interfaces of base metal 122 and plated metal layer 126, including during wire bonding.
[0030] Plated metal layer 126 is in contact with plated metal layer 124. Plated metal layer 126 predominantly includes silver, such as a pure silver or a silver alloy. A thickness 127 of plated metal layer 126 is 0.2 to 5 microns, such as 0.5 to 3.0 microns, such as 0.5 to 1.5 microns, such as about 1.0 micron. Plated metal layer 126 protects plated metal layer 124 from oxidation and provides a wire-bondable surface. As leadframe 108 is a pre-plated leadframe, plated metal layer 126 covers all or a majority of the surfaces of plated metal layer 124, such as at least 90 percent of the total surface area of plated metal layer 124.
[0031] An adhesion promotion coating 128 is in contact with plated metal layer 126 opposite plated metal layer 124. Adhesion promotion coating 128 predominantly includes silver oxide. A thickness 129 of adhesion promotion coating 128 is at least about 1.0 nanometer (nm), such as 1.0 to 3.0 nm. Adhesion promotion coating 128 covers all or a majority of the surfaces of plated metal layer 126, such as at least 90 percent of the total surface area of plated metal layer 126.
[0032] While plated metal layer 126 is suitable for wire bonding and solder connections at the exposed ends of leads 111, it may not provide suitable mechanical bonding to a mold compound of a package. Adding adhesion promotion coating 128 over plated metal layer 126 allows wire bonding solder connections to leadframe 108 with improved mechanical bonding to mold compound. For example, adhesion promotion coating 128 may mitigate undesirable sulfurization of plated metal layer 126, which can be detrimental to mechanical bonding to mold compound. As referred to herein, an adhesion promotion coating is a coating with stronger mechanical bonding to mold compound than the immediately adjacent layer, in this case, plated metal layer 126.
[0033] Leadframe 108 is formed on a single thin (about 120 to 250 μm) sheet of metal by stamping or etching. The ductility in this thickness range provides the 5 to 15% elongation that facilitates an intended bending and forming operation. The configuration or structure of the leadframe is stamped or etched from the starting metal sheet Multiple interconnected leadframes may be formed from a single sheet of substrate, the interconnected leadframes referred to as a leadframe strip. Leadframes on the sheet can be arranged in rows and columns. Tie bars, such as pad straps 115 (
[0034] Usually die mounting, die to lead attachment, such as wire bonding, and molding to cover at least part of the leadframe and dies take place while the leadframes are still integrally connected as a leadframe strip. After such processes are completed, the leadframes, and sometimes mold compound of a package, are severed (“singulated” or “diced”) with a cutting tool, such as a saw or laser. These singulation cuts separate the leadframe strip into separate semiconductor packages, each semiconductor package including a singulated leadframe, at least one die, electrical connections between the die and leadframe (such as gold, copper, or aluminum wire bonds) and the mold compound which covers at least part of these structures.
[0035] Tie bars and siderails may be removed during singulation of the packages formed with a single leadframe strip. The term leadframe of represents the portions of the leadframe strip remaining within a package after singulation. As shown in
[0036]
[0037] As shown in
[0038] Semiconductor die 101 may include any combination of semiconductor elements such as transistors and integrated circuits. In various examples of this disclosure, semiconductor die 101 may be implemented using any semiconductor material employed in industry, such as a silicon, gallium arsenide, gallium nitride, silicon germanium, or other semiconductor material. In addition, the techniques of this disclosure may be applied to semiconductor packages with any combination of active and passive components on a leadframe in addition to semiconductor die 101.
[0039] Leadframe 108 includes pad 110 and leads 111 spaced from pad 110 by a gap. Pad 110 is a substrate providing a stable support for firmly positioning semiconductor die 101 within semiconductor package 100. Leads 111 are shaped as cantilevered leads; in other examples, the leads may have other configurations, including but not limited to, the shape of flat leads as used in Quad Flat No-Lead (QFN) devices or in Small Outline No-Lead (SON) devices.
[0040] Leadframe 108 further includes pad straps 115 which extend between pad 110 to an external surface of semiconductor package 100. Pad straps 115 function to support pad 110 within a leadframe strip prior to molding of mold compound 130 and singulation of semiconductor package 100 from an array of semiconductor packages manufactured on a common leadframe strip.
[0041] Semiconductor die 101 is bonded on pad 110 with die attach adhesive 113. Adhesive 113 includes a plurality of components including a resin. The resin may include epoxy resins, polyurethane resins, and/or silicone resins. The resin may be filled or unfilled, and die attach adhesive 113 may further include one or more of the following: hardener, curing agent, fused silica, inorganic fillers, catalyst, flame retardants, stress modifiers, adhesion promoters, and other suitable components. Fillers, if any, may be selected to modify properties and characteristics of the resin base materials. Inert inorganic fillers may be selected to lower CTE, to more closely match semiconductor die 101 for example, increase thermal conductivity, increase elastic modulus of adhesive 113 compared to the resin base. Particulate fillers may be selected to reduce strength characteristics such as tensile strength and flexural strength compared to the resin base materials.
[0042] Semiconductor die 101, pad 110, and wire bonds 103 are covered by mold compound 130. End portions 112 of leads 111, which carry stitch bonds 105, are also covered by mold compound 130, while leads 111 extend to an exterior surface of the mold compound to facilitate electrical connections between package 100 and external components, such as board 140. Mold compound 130 provides a protective outer layer for semiconductor die 101 and wire bonds 103 formed in a molding process. In some examples, mold compound 130 includes an epoxy such as an epoxy-based thermoset polymer.
[0043]
[0044] First, the shape of a leadframe strip is patterned in a base metal, such as a copper sheet (
[0045] Base metal 122 of the leadframe strip is cleaned and immersed in a solution containing nickel, then the leadframe strip is electroplated to form first plated metal layer 124 in contact with base metal 122. Next, the base metal 122 a plated metal layer 124 is immersed in a solution containing silver, then electroplated to form second plated metal layer 126 in contact with first plated metal layer 124 (
[0046] Following the plating steps, plated metal layer 126 is reacted to form adhesion promotion coating 128. As one example, the plated leadframe strip may be reacted with a reactive species to form adhesion promotion coating 128 including silver oxide (
[0047] As shown in
[0048] As shown in
[0049] As shown in
[0050] A wire bonding formation process may begin with positioning semiconductor die 101 on a heated pedestal to raise the temperature to between 150 and 300° C. For copper and aluminum wires, ball formation and bonding may be performed in a reducing atmosphere such as dry nitrogen gas with a few percent hydrogen gas. Such a reducing atmosphere is generally not required for gold wires.
[0051] In a wire bonding process, the wire is strung through the capillary of an automated bonder. A capillary is an elongated tube of an inert material such as a ceramic with a fine bore (the capillary in the strict sense) suitable for guiding a metal wire used to form the gold bumps or wire bonds. At the wire end extruding from the capillary tip, a free air ball may be created by melting the wire end using either a flame or a spark technique. The capillary is moved towards an attachment area of one of bond pads 102.
[0052] Ball bond 104 may be created from a free air ball at the end of wire 107, then flattening this air ball against one of bond pads 102. The air ball has a typical diameter from about 1.2 to 1.6 times diameter of wire 107. The free air ball of melted wire is pressed against the metallization of the attachment area by a compression force, often combined with ultrasonic movement of the ball relative to the attachment area, transmitting ultrasonic energy, in order to attach a ball bond 104 to the underlying metal. The bonding process results in a metal nail head or squashed ball, as shown with respect to ball bonds 104.
[0053] After the ball attachment, the capillary with wire 107 may be lifted in a controlled loop to span an arch from the ball bond, such as ball bond 104, to an attachment area on a substrate or a leadframe, such as a lead stitch area of an end portion 112 of one of leads 111. When the wire touches the attachment area surface, the capillary tip is pressed against the wire in order to flatten it and thus to form a stitch bond, such as stitch bond 105, sometimes referred to as a wedge bond.
[0054] For substrate-based attachment areas, the bonding temperature may be about 160° C.; whereas for leadframe-based attachment areas, the bonding temperature may be between 240 and 260° C. The bonding force may be in the range from about 50 to 150 grams, and the ultrasonic energy may be in the range from about 80 to 180 milliamps. The stitch bond attachment process forms metal interdiffusions or welds.
[0055] The capillary rises again to a height sufficient to display a length of wire with enough metal to form the next ball. Then, a tear method is initiated to break the wire near the end of the stitch bond and leave the exposed wire length dangling from the capillary tip ready for the next ball-forming melting step. Various wire-breaking methods are commonly employed, such as a clamp-tear method and a table-tear method.
[0056] Wire bonding on adhesion promotion coating 128 may require careful selection of wirebond parameters to provide a suitable result, including suitable wire pull force. For example, surface roughness of the capillary may affect the ultrasonic transfer. As another example, a smaller face angle of the capillary may improve the bondability. As another example increasing scrubbing cycles may improve bondability, although that reduces throughput.
[0057] Following the formation of wire bonds 103, the assembly of leadframe 108, semiconductor die 101, adhesive 113, and wire bonds 103 is covered in mold compound 130, with portions of pad 110 and leads 112 remaining exposed on an outer surface of semiconductor package 100 (
[0058] Following molding of mold compound 130, semiconductor package 100 is singulated from the array of interconnected packages manufactured on the leadframe strip (
[0059]
[0060]
[0061] As shown in
[0062]
[0063] As shown in
[0064]
[0065] As shown in
[0066]
[0067] As shown in
[0068] The specific techniques for pre-plated leadframes with a nickel metal layer and silver metal layer over the nickel metal layer, such as described with respect to leadframe 108 of semiconductor package 100, are merely illustrative of the general inventive concepts included in this disclosure as defined by the following claims.