Method for thinning solid body layers provided with components
10978311 · 2021-04-13
Assignee
Inventors
- Wolfram Drescher (Dresden, DE)
- Marko Swoboda (Dresden, DE)
- Ralf Rieske (Dresden, DE)
- Christian Beyer (Freiberg, DE)
- Jan Richter (Dresden, DE)
Cpc classification
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
H01L29/66053
ELECTRICITY
H01L21/302
ELECTRICITY
H01L21/02422
ELECTRICITY
H01L21/324
ELECTRICITY
International classification
B23K26/00
PERFORMING OPERATIONS; TRANSPORTING
H01L21/304
ELECTRICITY
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
H01L21/324
ELECTRICITY
Abstract
The present invention relates to a method for separating at least one solid-body layer (4) from at least one solid body (1). Thereby, the method as claimed in the invention comprises the steps: creating a plurality of modifications (9) by means of laser beams within the interior space of the solid body (1) to form a detachment plane (8), producing a composite structure by arranging or producing layers and/or components (150) on or above an initially exposed surface (5) of the solid body (1), wherein the exposed surface (5) is an integral part of the solid-body layer (4) to be separated, introducing an external force into the solid body (1) for generating tensions within the solid body (1), wherein the external force is so strong that the tensions initialize a crack propagation along the detachment plane (8), wherein the modifications for forming the detachment plane (8) are created before producing the composite structure.
Claims
1. A method for separating a solid-body layer from a solid body, the method comprising: creating a plurality of modifications by means of laser beams within an interior space of the solid body to form a detachment plane; after creating the plurality of modifications, producing a composite structure by arranging or producing layers and/or components on or above an initially exposed surface of the solid body, the exposed surface being an integral part of the solid-body layer to be separated; and introducing an external force into the solid body for generating tensions within the solid body, the external force causing the tensions to initialize a crack propagation along the detachment plane, wherein introducing the external force comprises: thermally applying a receiving layer comprising a polymer material on an exposed surface of the composite structure or the solid-body layer to be separated, so that the tensions are mechanically generated; and cooling the receiving layer to a temperature under ambient temperature, so that the polymer material of the receiving layer completes a glass transition and a crack in the solid body spreads along the detachment plane due to the mechanically generated tensions, the crack separating the solid-body layer from the solid body.
2. The method of claim 1, wherein the receiving layer is thermally applied to a surface of the solid body opposite from the surface at which the layers and/or components for forming the composite structure are arranged.
3. The method of claim 1, wherein the receiving layer comprises a polymer material having a glass transition between −130° C. and 0° C. or a polymer-hybrid material which forms a polymer matrix with a filler in the polymer matrix.
4. The method of claim 1, wherein the receiving layer is cooled to a temperature between −130° C. and −10° C. via nebulized nitrogen, a nitrogen bath or by a nitrogen spray.
5. The method of claim 1, further comprising: forming a stabilization layer on an exposed layer or exposed components of the composite structure, the stabilization layer limiting deformations of the exposed layer or of the exposed components which result from the mechanically generated tensions.
6. The method of claim 5, wherein the stabilization layer comprises a ceramic material and/or comprises a polymer material.
7. The method of claim 5, wherein the stabilization layer is formed in-situ or provided as a film, and/or wherein the stabilization layer infuses the exposed layer or the exposed components, and/or wherein the stabilization layer is removed from the exposed layer or the exposed components by applying a solvent or by dipping into a solvent.
8. The method of claim 5, wherein the stabilization layer is a glass wafer or a glass wafer is arranged on the stabilization layer.
9. The method of claim 1, further comprising: before creating the detachment plane, treating the solid body using a high-temperature method executed at a temperature between 70° C. and the melting temperature or evaporation temperature of the solid body, wherein the high-temperature method is an epitaxy method, a doping method or a plasma method, wherein at least one layer is produced on the solid body by the high-temperature method, wherein the at least one produced layer has predefined parameters, at least one of the predefined parameters being a maximum degree of breakage and/or absorption and/or reflection of laser-light waves, the degree of breakage and/or absorption and/or reflection is under 5%.
10. The method of claim 1, wherein pressure tensions in the solid body are generated by the modifications and at least components of the modifications generating the pressure tensions remain on the solid-body layer when separating the solid-body layer from the solid body.
11. The method of claim 10, further comprising: producing, by sputtering or electrochemical deposition, a metal layer on a surface exposed by separation of the solid-body layer from the solid body.
12. The method of claim 11, wherein the metal layer is produced on the solid-body layer in a first physical state and at a temperature above room temperature and is at room temperature in a second physical state, and wherein due to a transition from the first physical state into the second physical state, the metal layer impinges the solid-body layer for at least partial compensation of the deformation caused by the pressure tensions of the modification components remaining on the solid-body layer.
13. The method of claim 11, wherein the metal layer is produced on the solid-body layer at a temperature range having a minimum temperature of at least 100° C. above room temperature and a maximum temperature of 2,000° C. or lower than the melting or evaporation temperature of the solid-body material.
14. The method of claim 1, wherein creating the plurality of modifications comprises: creating a plurality of basic modifications using predefined process parameters; and creating initialization modifications to initialize subcritical cracks, at least one process parameter for creating the initialization modifications being different from at least one of the process parameters for creating the basic modifications.
15. The method of claim 14, wherein the initialization modifications are created in one direction which is inclined towards or spaced away from a progression of a line along which the basic modifications are created.
16. The method of claim 14, wherein the subcritical cracks spread in the solid body between 5 μm and 200 μm.
17. The method of claim 14, wherein sections crack between regions having a plurality of lines in which the subcritical cracks have propagated.
18. The method of claim 1, wherein the solid-body material is silicon or SiC.
19. A method for creating electrical components, the method comprising: creating a plurality of modifications by means of laser beams within an interior space of a solid body to form a detachment plane, so that pressure tensions within the solid body are generated by the plurality of modifications, producing a composite structure by arranging or producing layers and/or components on or above an initially exposed surface of the solid body, the exposed surface being an integral part of a solid-body layer to be separated from the solid body; separating the solid-body layer from the solid body along the detachment plane, wherein at least components of the plurality of modifications which generate the pressure tensions remain on the solid-body layer, wherein so many modifications are created that the solid-body layer separates from the solid body or an external force is introduced into the solid body for generating other tensions within the solid body, the external force causing the tensions to form a crack propagation along the detachment plane formed by the plurality of modifications; and producing a metal layer on a surface exposed by the separation of the solid-body layer from the solid body, to at least partially compensate for the pressure tensions caused by modification components, wherein the external force is introduced into the solid body by: thermally applying a receiving layer comprising a polymer material on an exposed surface of the composite structure or the solid-body layer to be separated, so that the pressure tensions are mechanically generated; and cooling the receiving layer to a temperature under ambient temperature, so that the polymer material of the receiving layer completes a glass transition and a crack in the solid body spreads along the detachment plane due to the mechanically generated is introduced into the solid body tensions, the crack separating the solid-body layer from the solid body.
20. The method of claim 19, wherein the electrical components are Schottky diodes and/or transistors, wherein the metal layer forms an ohmic contact and/or an interface for heat dissipation, and wherein on average, per cm.sup.2 of a level surface side of the solid-body layer, at least 4 electrical components are produced.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The figures show:
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DETAILED DESCRIPTION
(12)
(13) In accordance with
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(17) Between the step of creating the modifications and attaching the receiving layer, preferably an arrangement or a creation of other layers 150 and/or components 150 takes place on the surface 5 or on another layer 145 already created on it during an upstream high-temperature method.
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(20) A unit consisting of a separated solid-body layer and a stabilization layer and/or protective layer 142 arranged on it and, possibly, a stabilization device arranged on it, is then preferably further treated to remove stress. Being particularly preferred, the stabilization layer 142 or the stabilization device forms a holding device, by means of which the separated solid-body layer is fixable for a material removal treatment with relation to a material removal device, in particular, a grinding and/or polishing device. By means of the material removal device, the modification portions remaining on the separated solid-body layer are then removed, in particular, removed by machining.
(21) Within the context of the invention, the solid-body layer is preferably always thinner than the remaining solid-body portion. Furthermore, it is conceivable that the receiving layer is not arranged or produced on a surface of the later solid-body layer, but on a surface of the remaining solid-body portion. If the solid-body material is silicon, then, with relation to the remaining solid body, the separated solid-body layer preferably has a level less than 40% of the level of the remaining solid body, in particular, less than 30% or 20% of the level of the remaining solid body. In the case of silicon, preferably, predetermined parameters for the modification creation are provided; the numerical aperture is preferably between 0.5 and 0.8, in particular at 0.65, the radiation depth is between 150 μm and 1000 μm, in particular, at 300 μm, the pulse interval is between 1 μm and 5 μm, in particular at 2 μm, the line spacing is between 1 μm and 5 μm, in particular at 2 μm, the pulse duration is between 50 ns and 400 ns, in particular, at 300 ns and the pulse energy is between 3 μJ and 30 μJ, in particular at 10 μJ.
(22) If the material is SiC, then, with relation to the remaining solid body, the separated solid-body layer preferably has a level less than 50% of the level of the remaining solid body, in particular, less than 45% or 40% or 35% or 30% or 25% of the level of the remaining solid body. In the case of SiC, preferably, predetermined parameters for the modification creation are provided; the numerical aperture is preferably between 0.4 and 0.8, in particular at 0.4, the radiation depth is between 50 μm and 500 μm, in particular, at 180 μm, the pulse interval is between 0.1 μm and 3 μm, in particular, at 1 μm, the line spacing is between 10 μm and 100 μm, in particular, at 75 μm, the pulse duration is preferably between 1 fs and 10 ns, in particular, at 3 ns and the pulse energy is between 0.5 μJ and 30 μJ, in particular at 7 μJ.
(23) Also, in
(24) Furthermore,
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(26)
(27) Here,
(28) With relation to the solid body 1 shown in
(29) With relation to the illustration in
(30) With relation to
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(37) Arrows 170, 172 represent the laser feed direction, the black circles represent the various laser shots or modifications 9, which do not overlap here with their harmful effect within the material. Thereby, it is preferred if the laser initially moves into one direction and creates modifications 9 before it reverses and writes modifications 9 in the second (lower) direction.
(38)
(39) Thereby, the cooling device 174 is preferably used to cool the receiving layer 140, 146 to a temperature between −130° C. and −10° C., in particular, to a temperature between −80° C. an −50° C.
(40) In accordance with
(41) In accordance with the embodiments in
(42) In accordance with
(43) The substrate or the solid body 1 or the solid-body arrangement 176 preferentially rests over the chamber bottom in order to avoid nitrogen settling at the bottom of the chamber.
(44) In accordance with
(45) The substrate or the solid body 1 or the solid-body arrangement 176 preferentially rests over the chamber bottom in order to avoid nitrogen settling at the bottom of the chamber.
(46) In accordance with
(47) The substrate or the solid body 1 or the solid-body arrangement 176 preferentially rests over the chamber bottom in order to avoid nitrogen settling at the bottom of the chamber.
(48) The chamber 184 of the cooling device 174 is preferably sealed in order to reduce a temperature gradient as much as possible by means of insulation.
(49)
(50) According to the invention, the modifications are successively created in at least one line or row, wherein the modifications 9 made in a line or row are preferably created at a spacing X and with a height H so that a crack extending between two consecutive modifications, in particular, a crack extending in the crystal lattice direction, the crack propagation direction of which is aligned at an angle W to the detachment plane, connects both modifications to one another. The angle W is preferably between 0° and 6°, in particular, at 4°. Preferably, the crack extends from a region under the center of a first modification towards a region above the center of a second modification. The essential connection here is that the size of the modification can or must be changed depending on the spacing of the modifications and of the angle W.
(51) Furthermore, this method can also entail the step of producing a composite structure by arranging or producing layers and/or components 150 on or above an initially exposed surface 5 of the solid body 1, wherein the exposed surface 5 is preferably an integral part of the solid-body layer 4 to be separated. Being particularly preferred, the modifications for forming the detachment plane 8 are created before creating the composite structure.
(52) In order to introduce the external force, analogously to the previously described method, a receiving layer 140 can be arranged on an exposed surface 5 of the composite structure or of the solid body.
(53) The three
(54) Due to a preferably highest numerical aperture possible, the damage zone can be made smaller along the beam direction as well as laterally on the focal plane. Since only the threshold intensity has to be achieved, a smaller pulse energy level is also sufficient here.
(55) If the damage zone is formed to be smaller in a suitable way, the laser modifications can be set more densely, which allows the saw tooth to run more briefly and, overall, a lower height extension of the modified plane results (first image).
(56) If, in contrast, the damage zone is larger (higher energy and/or lower numerical aperture—
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(59) According to the invention, at a first step, the modifications are created on a line 103 and preferably being at the same spacing to one another. Furthermore, it is conceivable that plurality of these lines created at the first step are created. Being particularly preferred, these first lines are created to be parallel to the crack propagation direction and, preferably to be straight or circularly arched in shape, in particular on the same plane. After creating these first lines, second lines 105 are preferably created to propagate and/or instigate preferably subcritical cracks. These second lines are also preferably created to be straight. Being particularly preferred, the second lines are inclined in relation to the first lines, in particular, being orthogonally oriented. The second lines preferably extend on the same plane as the first lines or, being particularly preferred, on a plane that is parallel to the plane, in which the first lines extend. Then, third lines are preferably created for connecting subcritical cracks.
(60) In particular, this method is useful for the separation of solid-body layers from a solid body comprising SiC or made of SiC.
(61) Furthermore, the modifications can be successively created in at least one line or row, wherein the modifications 9 made in a line or row are preferably created at a spacing X and with a height H so that a crack extending between two consecutive modifications, in particular, a crack extending in the crystal lattice direction, the crack propagation direction of which is aligned at an angle W to the detachment plane, connects both modifications to one another. The angle W is preferably between 0° and 6°, in particular, at 4°. Preferably, the crack extends from a region under the center of a first modification towards a region above the center of a second modification. The essential connection here is that the size of the modification can or must be changed depending on the spacing of the modifications and of the angle W.
(62) Furthermore, this method can also entail the step of producing a composite structure by arranging or producing layers and/or components 150 on or above an initially exposed surface 5 of the solid body 1, wherein the exposed surface 5 is an integral part of the solid-body layer 4 to be separated. Being particularly preferred, the modifications for forming the detachment plane 8 are created before creating the composite structure.
(63) In order to introduce the external force, analogously to the previously described method, a receiving layer 140 can be arranged on an exposed surface 5 of the composite structure or of the solid body.
(64) Thereby during the further course of the laser method according to the invention, lines that are parallel to the crack propagation direction (preferably referred to as transverse lines) are created on SiC (or also other materials) in order to define a plane for the preferred crack initialization before longitudinal lines cause the cracks. Here, the cracks are initially transversely initialized, then longitudinally before a final step sets lines between the longitudinal lines of the second step in order to initialize the cracks across the entire surface. This makes shorter cracking paths possible, which minimizes the final surface roughness. Sample image for cross lines (with the sawtooth) and crack propagation lines (on the sawtooth crests).
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(67) The present invention can thereby relate to a method for providing at least one solid-body layer 4, wherein the solid-body layer 4 is separated from a solid body 1. Thereby, the method according to the invention preferably comprises the steps:
(68) Creating a plurality of modifications 9 by means of laser beams within the interior space of the solid body 1 to form a detachment plane 8, wherein, pressure tensions within the solid body 1 are generated by means of the modifications 9, separation of the solid-body layer 4 by means of the separation of the remaining solid body 1 and of the solid-body layer 4 along the detachment plane 8 formed by the modifications 9, wherein at least components of the modifications 9 generating the pressure tensions remain on the solid-body layer 4, wherein so many modifications 9 are created that the solid-body layer 4 separates from the solid body 1 due to the modifications 9 or wherein an external force is introduced into the solid body 1 for generating other tensions within the solid body 1, wherein the external force is so strong that the tensions cause a crack propagation along the detachment plane 8 formed by the modifications, production of a material layer, in particular, a metal layer, on the surface exposed by the separation of the solid-body layer 4 from the solid body 1 for the at least partial and, preferably predominate and, being particularly preferred, full compensation of a deformation of the solid-body layer 4 caused by the pressure tensions of the remaining modification components or for the at least partial and preferably predominate or full compensation of the pressure tensions.
(69) As an alternative, the present invention can refer to a method for producing electrical components. This method preferably comprises the steps: creating a plurality of modifications 9 by means of laser beams within the interior space of a solid body 1 to form a detachment plane 8, wherein, pressure tensions within the solid body 1 are generated by means of the modifications 9, producing a composite structure by arranging or producing layers and/or components 150 on or above an initially exposed surface 5 of the solid body 1, wherein the exposed surface 5 is an integral part of the solid-body layer 4 to be separated, separation of the solid-body layer 4 by means of the separation of the remaining solid body 1 and of the solid-body layer 4 along the detachment plane 8 formed by the modifications 9, wherein at least components of the modifications 9 generating the pressure tensions remain on the solid-body layer 4, wherein so many modifications 9 are created that the solid-body layer 4 separates from the solid body 1 due to the modifications 9 or wherein an external force is introduced into the solid body 1 for generating other tensions within the solid body 1, wherein the external force is so strong that the tensions cause a crack propagation along the detachment plane 8 formed by the modifications, production of a metal layer 20 on the surface exposed by the separation of the solid-body layer 4 from the solid body 1 for the at least partial and, preferably, predominate and, being particularly preferred, full compensation of the pressure tensions caused by modification components.
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(71) According to the invention, thereby, in addition or as an alternative, a method for separating at least one solid-body layer 4, in particular, a solid-body disk or solid-body layer, is provided by a donor substrate 1 or solid body. Thereby, this method preferably comprises the steps:
(72) Providing a donor substrate 1, creating modifications 9 within the interior space of the donor substrate 1 by means of LASER beams, wherein a detachment region is specified by the modifications 9, along which a separation of the solid-body layer from the donor substrate 1 takes place, removal of the material of the donor substrate 1 starting from a surface extending in the circumferential direction of the donor substrate 1 towards the center (Z) of the donor substrate 1, in particular, for producing a circumferential depression, wherein the detachment region 8 or a detachment plane is exposed due to the material removal, separation of the solid-body layer 4 from the donor substrate 1, wherein the donor substrate is weakened in the detachment region by the modifications in such a way that the solid-body layer 4 detaches from the donor substrate 1 due to the material removal or, after material removal, such a number of modifications 9 are created that the donor substrate 1 is weakened in the detachment region in such a way that the solid-body layer 4 detaches from the donor substrate 1 or a tension generation layer 140 or receiving layer is produced or arranged on a surface of the donor substrate 1 that is aligned towards the circumferential surface in an inclined manner, particularly being level, and mechanical tensions are generated within the donor substrate 1 by a thermal application of the tension generation layer 140, wherein a crack results for separating a solid-body layer 4 due to the mechanical tensions, which spreads starting from the surface of the donor substrate exposed due to the material removal along the modifications 9. Here, it is possible that the modifications 9 are partly or completely created before the material removal or after the material removal. The depression 6 thereby preferably becomes narrower in the direction of the center Z towards a depression end 18. Preferably, the depression extends in a wedge shape, wherein the depression end 18 is preferably precisely on the plane, in which the crack expands or in which the modifications 9 are created. Furthermore, it is possible that a composite structure is created by arranging or producing layers and/or components 150 on or above an initially exposed surface 5 of the solid body 1, wherein the exposed surface 5 is an integral part of the solid-body layer 4 to be separated. Being particularly preferred, the modifications 9 for forming the detachment plane 8 are created before creating the composite structure.
(73) After creating the composite structure, introducing an external force into the solid body 1 preferably takes place for generating tensions within the solid body 1, wherein the external force is so strong that the tensions cause a crack propagation along the detachment plane 8.
(74)
(75) Furthermore, it is pointed out that the material removal on the edge of the solid body, in particular with the subsequent etching step, can be added in the case of each method disclosed with this property rights document.