Dissimilar material interface having lattices
10804201 ยท 2020-10-13
Assignee
Inventors
- Archana Venugopal (Dallas, TX, US)
- Benjamin Stassen Cook (Addison, TX, US)
- Nazila Dadvand (Richardson, TX, US)
- Luigi Colombo (Dallas, TX)
Cpc classification
H01L21/76849
ELECTRICITY
H01L23/53238
ELECTRICITY
H01L23/53223
ELECTRICITY
H01L23/5226
ELECTRICITY
H01L21/76838
ELECTRICITY
H01L21/76823
ELECTRICITY
H01L23/53266
ELECTRICITY
International classification
H01L23/522
ELECTRICITY
Abstract
A structure for a semiconductor device includes a dielectric layer and a metal layer. The structure also includes a plurality of unit cells. Each unit cell is formed of interconnected segments. The plurality of unit cells forms a lattice. The lattice is between the dielectric layer and the metal layer.
Claims
1. A semiconductor device comprising: a dielectric layer; a metal layer; and interconnected graphene segments between the dielectric layer and the metal layer, wherein the interconnected graphene segments form a hollow tube.
2. The semiconductor device of claim 1, wherein the dielectric layer and the metal layer are at least part of a back-end-of-line (BEOL) portion of a semiconductor device.
3. The semiconductor device of claim 1, wherein the dielectric layer comprises at least one material selected from the group consisting of SiO2, Al2O3, ZrO2, SiN, Tetraethyl Orthosilicate (TEOS), Polyimide, polybenzoxazole (PBO), benzocyclobutene (BCB), and combinations thereof, and the metal layer comprises at least one element selected from the group consisting of W, Cu, Al, Ni, Pd, Au, Ag, and combinations thereof.
4. The semiconductor device of claim 1, wherein the metal layer has a coefficient of thermal expansion that is different than a coefficient of thermal expansion of the dielectric layer.
5. The semiconductor device of claim 1, wherein the hollow tube is filled with a non-conducting material.
6. A structure for a semiconductor device, the structure comprising: a dielectric layer; a metal-filled via; and a plurality of unit cells, wherein each unit cell is formed of interconnected segments, and wherein the plurality of unit cells forms a lattice; wherein the lattice contacts the dielectric layer and the metal-filled via.
7. The structure of claim 6, wherein the dielectric layer and the metal-filled via are at least part of a back-end-of-line (BEOL) portion of a semiconductor device.
8. The structure of claim 6, wherein the dielectric layer comprises at least one material selected from the group consisting of SiO2, Al2O3, ZrO2, SiN, Tetraethyl Orthosilicate (TEOS), Polyimide, polybenzoxazole (PBO), benzocyclobutene (BCB), and combinations thereof, and the metal-filled via comprises at least one element selected from the group consisting of W, Cu, Al, Ni, Pd, Au, Ag, and combinations thereof.
9. The structure of claim 6, wherein the metal-filled via has a coefficient of thermal expansion that is different than a coefficient of thermal expansion of the dielectric layer.
10. The structure of claim 6, wherein each of the interconnected segments is a hollow tube.
11. The structure of claim 6, wherein each of the interconnected segments is a tube filled with a non-conducting material.
12. A structure for a back-end-of-line (BEOL) portion of an integrated circuit package, the structure comprising: a dielectric layer; a metal layer; a metal-filled via connected to the metal layer; and a plurality of lattices, each lattice comprises a plurality of unit cells, wherein each unit cell is formed of interconnected segments; wherein a first lattice of the plurality of lattices is between the dielectric layer and the metal layer; and wherein a second lattice of the plurality of lattices is between the dielectric layer and the metal-filled via.
13. The structure of claim 12, wherein the metal layer and the metal-filled via have coefficients of thermal expansion that are different than a coefficient of thermal expansion of the dielectric layer.
14. The structure of claim 12, wherein each of the interconnected segments is a hollow tube.
15. The structure of claim 12, wherein each of the interconnected segments is a tube filled with a non-conducting material.
16. A method of forming a structure for a back-end-of-line (BEOL) portion of an integrated circuit package, the method comprising: forming a dielectric layer; forming a metal layer; forming a metal-filled via connected to the metal layer; and forming a plurality of lattices between the dielectric layer and the metal layer, and between the dielectric layer and the metal-filled via, each lattice is formed by: photo-initiating polymerization of a monomer in a pattern of unit cells to form a polymer lattice, wherein each unit cell is formed of interconnected segments; removing the unpolymerized monomer; coating the polymer lattice with a metal; removing the polymer lattice to leave a metal lattice; depositing graphitic carbon on the metal lattice; converting the graphitic carbon to graphene or graphitic tubes; and removing the metal lattice.
17. The method of claim 16, wherein the metal layer and the metal-filled via have coefficients of thermal expansion that are different than a coefficient of thermal expansion of the dielectric layer.
18. The method of claim 16, wherein each of the interconnected segments is a hollow tube.
19. The method of claim 16, wherein each of the interconnected segments is a tube filled with a non-conducting material.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) For a detailed description of various examples, reference will now be made to the accompanying drawings in which:
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DETAILED DESCRIPTION
(11) Certain terms have been used throughout this description and claims to refer to particular system components. As one skilled in the art will appreciate, different parties may refer to a component by different names. This document does not intend to distinguish between components that differ in name but not function. In this disclosure and claims, the terms including and comprising are used in an open-ended fashion, and thus should be interpreted to mean including, but not limited to . . . . Also, the term couple or couples is intended to mean either an indirect or direct wired or wireless connection. Thus, if a first device couples to a second device, that connection may be through a direct connection or through an indirect connection via other devices and connections. The recitation based on is intended to mean based at least in part on. Therefore, if X is based on Y, X may be a function of Y and any number of other factors.
(12) For purposes of this disclosure, the phrase integrated circuit package may alternatively encompass a semiconductor device (and derivatives thereof) and thus, may be used interchangeably.
(13) For purposes of this disclosure, the term lattice may alternatively encompass microlattice, nanolattice, and superlattice (and derivatives thereof) and thus, may be used interchangeably. Similarly, the term structure may alternatively encompass microstructure, nanostructure, and superstructure (and derivatives thereof) and thus, may be used interchangeably.
(14) With reference to the semiconductor device structure 200 of
(15) It has been found that an organic/inorganic superstructure may be used as a template for the formation of a 3D metal superstructure that may then be used to grow graphitic carbon on the surface of the metal. The template may be fabricated through a self-propagating photopolymer waveguide technique (see, e.g., Xiaoyu Zheng et. al., Ultralight, Ultrastiff Mechanical Metamaterials; Science 344 (2014) 1373-1377 and T. A. Schaedler, et al., Ultralight Metallic Microlattices; Science 334 (2011) 962-965) in which an interconnected 3D photopolymer lattice may be produced upon exposure of an appropriate liquid photomonomer to collimated UV light through a specifically designed mask that contains openings with certain spacing and size. The fabricated microlattice may then be then coated with copper or other suitable metal (e.g. Ni, Co, Au, Ag, Cu, and alloys thereof) by an electroless process followed by etching away the organic polymeric matrix (scaffold) leaving behind the metal microlattice. The resulting metal-based microlattice may be then used as a template for the growth of graphitic carbon at some optimal temperature (e.g., between 100 C.-1000 C.) such that the microlattice structure is minimally disturbed. The thickness of the electroless plated metal may be controlled in the range of nanometer to micrometer by adjusting the plating time, temperature, and/or plating chemistry.
(16) The left portion of
(17) The present disclosure employs a periodically structured graphene nanostructure. The graphitic carbon or graphene is grown on the metal microlattice formed by electroless plating mentioned above by a chemical vapor deposition process. In this process the metal microlattice is exposed to a mixture of hydrogen and a hydrocarbon such as methane, ethylene, etc., or oxygen containing hydrocarbons such as ethanol, methanol, etc., at a temperature ranging from 100 C. to 1000 C., the maximum temperature depending upon the device thermal budget. The growth can take place either thermally or in the presence of a plasma. This process will lead to graphene or graphitic films depending upon the metal used for the metal microlattice. It is important to note that in order to ensure that the metal structures do not agglomerate as a result of high metal surface mobility especially at higher temperatures, the surface of the metal can be chemically treated to minimize surface diffusion and agglomeration.
(18) The present process may be used to create a regular array, and a superstructure with various dimensions on demand that we will refer to as a unit cell as shown in
(19) There are several aspects of this procedure that are noteworthy: it provides a regular structure with defined dimensions; it has the ability to form very thin metal (e.g. Ni, Co, Cu, Ag, Au, W, Ti, Zr, Hf, and alloys of these metals) microlattices; and it enables the formation of graphitic carbon on very thin metals, thin metal wires or tubes.
(20) The present process uses a polymeric structure as a template for such fabrication with the subsequent formation of a metal superstructure that may then be exposed to a hydrocarbon (e.g. methane, ethylene, acetylene, benzene, and oxygen containing hydrocarbons such as alcohols) to form graphitic carbon, followed by etching of the metal from under the graphitic carbon using appropriate etchants such as, for example, FeCl.sub.3 or potassium permanganate.
(21) Collimated light through a photomask or multi-photon photography may be used in a photo-initiated polymerization to produce a polymer microlattice comprised of a plurality of unit cells. Exemplary polymers include polystyrene and poly(methyl methacrylate) (PMMA). Once polymerized in the desired pattern, the remaining un-polymerized monomer may be removed.
(22) The polymer structure (polymer scaffold) may then be plated with a suitable metal using an electroless plating process.
(23) For example, electroless nickel plating (EN) is an auto-catalytic chemical technique that may be used to deposit a layer of nickel-phosphorus or nickel-boron alloy on a solid workpiece, such as metal, plastic, or ceramic. The process relies on the presence of a reducing agent, for example hydrated sodium hypophosphite (NaPO.sub.2H.sub.2.H.sub.2O) which reacts with the metal ions to deposit metal. Alloys with different percentages of phosphorus, ranging from 2-5 (low phosphorus) to up to 11-14 (high phosphorus) are possible. The metallurgical properties of the alloys depend on the percentage of phosphorus.
(24) Electroless plating has several advantages over electroplating. Free from flux-density and power supply issues, it provides an even deposit regardless of workpiece geometry, and with the proper pre-plate catalyst, may deposit on non-conductive surfaces. In contradistinction, electroplating can only be performed on electrically conductive substrates.
(25) Before performing electroless plating, the material to be plated must be cleaned by a series of chemicals; this is known as the pre-treatment process. Failure to remove unwanted soils from the part's surface results in poor plating. Each pre-treatment chemical must be followed by water rinsing (normally two to three times) to remove chemicals that may adhere to the surface. De-greasing removes oils from surfaces, whereas acid cleaning removes scaling.
(26) Activation may be done with an immersion into a sensitizer/activator solutionfor example, a mixture of palladium chloride, tin chloride, and hydrochloric acid. In the case of non-metallic substrates, a proprietary solution is often used.
(27) The pre-treatment required for the deposition of metals on a non-conductive surface usually consists of an initial surface preparation to render the substrate hydrophilic. Following this initial step, the surface may be activated by a solution of a noble metal, e.g., palladium chloride. Electroless bath formation varies with the activator. The substrate is then ready for electroless deposition.
(28) The reaction is accomplished when hydrogen is released by a reducing agent, normally sodium hypophosphite (with the hydrogen leaving as a hydride ion) or thiourea, and oxidized, thus producing a negative charge on the surface of the part. The most common electroless plating method is electroless nickel plating, although silver, gold and copper layers can also be applied in this manner.
(29) In principle any hydrogen-based reducing agent can be used although the redox potential of the reducing half-cell must be high enough to overcome the energy barriers inherent in liquid chemistry. Electroless nickel plating most often employs hypophosphite as the reducer while plating of other metals like silver, gold and copper typically makes use of low-molecular-weight aldehydes.
(30) A benefit of this approach is that the technique can be used to plate diverse shapes and types of surfaces.
(31) As illustrated in
(32) As an alternative to or in addition to the above processes, the graphene lattices may be formed via any of the fabrication techniques (or portion(s) of the fabrication techniques thereof, including any pre-treatments) described in U.S. Provisional Application Ser. No. 62/611,347, filed Dec. 28, 2017, entitled SP.sup.2-Bonded Carbon Structures, all of which are hereby incorporated in this disclosure.
(33) With reference to
(34) Metal layer 320, metal layer 340, and metal-filled via 330 may be formed via conventional processes within the dielectric 310 to form the dielectric stack of a back-end-of-line (BEOL) portion of a semiconductor device, with the exception of the formation of the graphene lattices which isolate the dielectric material from the metal layer 320, metal layer 340, and/or metal-filled via 330. For example, a back-end process may involve the deposition of dielectric followed by etching of the dielectric and blanket deposition of metal and metal etch to get vias and metal interconnects (i.e., metal layers 320 (or 340)).
(35) However, the processes for forming the graphene lattices, as described above, are performed prior to formation of the metal layer 320, metal layer 340, and metal-filled via 330. The graphene lattices will grow at the interfaces of the dielectric 310 and any or all of the metal layer 320, metal layer 340, and metal-filled via 330, in order to provide stress relief between two dissimilar materials. Without the graphene lattices, the solid materials (and corresponding stepped interface) of the dielectric and metals (while having dissimilar thermal expansion properties due to dissimilar thermal expansion coefficients) have an abrupt change in thermal expansion at the interface.
(36) The graphene lattices at the dielectric/metal interfaces enable stress relief because the graphene lattices provide an intermediary boundary between the dielectric solid material (e.g., SiO.sub.2, Al.sub.2O.sub.3, ZrO.sub.2, SiN, Tetraethyl Orthosilicate (TEOS), Polyimide, polybenzoxazole (PBO), benzocyclobutene (BCB)) and the solid material of the metal layer 320, metal layer 340, and/or metal-filled via 330 (e.g., W, Cu, Al, Ni, Pd, Au, Ag) that serves as a stress-relief buffer instead of a stepped interface between solid materials having dissimilar coefficients of thermal expansion. In other words, the graphene lattices avoid having an abrupt transition between dielectric and metal materials having different thermal expansion coefficients. Heat, therefore, is dissipated and spread about in a gradual manner during operation of the semiconductor device. The extent to which the metal material(s) heats up is reduced with the graphene lattices present around the metal material(s). Since the coefficients of thermal expansion at the metal/dielectric interfaces are different, during temp cycling the different rates of expansion and contraction will result in high interfacial stress and the formation of cracks and corresponding reliability issues. The presence of the lattice, which is structured to be compressible/expandable, allows for buffering of the stress at the interface and mitigation of reliability issues.
(37) Any of the graphene lattice formation processes mentioned above may be employed, but the high temperature involved for processing at least the carbon or graphene process steps may be excessive for the process to be performed in situ, i.e., with the metal layer or wire (in the viawhich forms the metal-filled via) present. Therefore, it may be optional to alternatively use lower temperature processes by using alloys (such as NiCu with varying percentages of Ni and Cu to change the solubility of carbon) instead of just Cu (or other conducting material) to grow the graphene. This may alter the process from being surface mediated to diffusion-precipitation based. In either scenario, the voids of the graphene lattice will be empty and will not contain any dielectric.
(38) With additional reference to
(39) In an example, the dielectric layer 310 and the metal layer 320 (or 340) are at least part of a back-end-of-line (BEOL) portion of a semiconductor device.
(40) In an example, the dielectric layer 310 comprises at least one material selected from the group consisting of SiO.sub.2, Al.sub.2O.sub.3, ZrO.sub.2, SiN, Tetraethyl Orthosilicate (TEOS), Polyimide, PBO, BCB, and combinations thereof, and the metal layer 320 (or 340) comprises at least one element selected from the group consisting of W, Cu, Al, Ni, Pd, Au, Ag, and combinations thereof.
(41) In an example, the metal layer 320 (or 340) has a coefficient of thermal expansion that is different than a coefficient of thermal expansion of the dielectric layer 310.
(42) In an example, each of the interconnected graphene segments is a hollow graphene tube.
(43) In an example, each of the interconnected graphene segments is a graphene tube filled with a non-conducting material.
(44) Also, with reference to
(45) In an example, the dielectric layer 310 and the metal-filled via 330 are at least part of a back-end-of-line (BEOL) portion of a semiconductor device.
(46) In an example, the dielectric layer 310 comprises at least one material selected from the group consisting of SiO.sub.2, Al.sub.2O.sub.3, ZrO.sub.2, SiN, Tetraethyl Orthosilicate (TEOS), Polyimide, PBO, BCB, and combinations thereof, and the metal-filled via 330 comprises at least one element selected from the group consisting of W, Cu, Al, Ni, Pd, Au, Ag, and combinations thereof.
(47) In an example, the metal-filled via 330 has a coefficient of thermal expansion that is different than a coefficient of thermal expansion of the dielectric layer 310.
(48) In an example, each of the interconnected graphene segments is a hollow graphene tube.
(49) In an example, each of the interconnected graphene segments is a graphene tube filled with a non-conducting material.
(50) Further, with reference to
(51) In an example, the metal layer 320 (or 340) and the metal-filled via 330 have coefficients of thermal expansion that are different than a coefficient of thermal expansion of the dielectric layer 310.
(52) In an example, each of the interconnected graphene segments is a hollow graphene tube.
(53) In an example, each of the interconnected graphene segments is a graphene tube filled with a non-conducting material.
(54) With reference to
(55) In an example of the method, the metal layer and the metal-filled via have coefficients of thermal expansion that are different than a coefficient of thermal expansion of the dielectric layer.
(56) In an example of the method, each of the interconnected graphene segments is a hollow graphene tube.
(57) In an example of the method, each of the interconnected graphene segments is a graphene tube filled with a non-conducting material.
(58) In yet another aspect of the disclosure, a method of forming a structure for a back-end-of-line (BEOL) portion of an integrated circuit package is described herein with reference to
(59) In yet another aspect of the disclosure, a method of forming a structure for a back-end-of-line (BEOL) portion of an integrated circuit package is described herein with reference to
(60) In another implementation, the microlattice may simply be a metal lattice without graphene.
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(62) In any of the examples above, the graphene employed as the lattice could alternatively be replaced with a metal, metal alloy, dielectric, and/or ceramic. The above-mentioned processes of manufacturing the lattice (or portions thereof) may be adjusted accordingly dependent on the material of the lattice employed. Steps in the above-mentioned processes may also be eliminated or added dependent on the material of the lattice employed. Such alternatives are considered to be within the spirit and scope of the disclosure, and may therefore utilize the advantages of the configurations and examples described above.
(63) The method steps in any of the examples described herein are not restricted to being performed in any particular order. Also, structures mentioned in any of the method examples may utilize structures mentioned in any of the device examples. Such structures may be described in detail with respect to the device examples only but are applicable to any of the method examples.
(64) Features in any of the examples described in this disclosure may be employed in combination with features in other examples described herein, such combinations are considered to be within the spirit and scope of the present disclosure.
(65) The above discussion is meant to be illustrative of the principles and various example implementations according to this disclosure. Numerous variations and modifications will become apparent once the above disclosure is fully appreciated. It is intended that the following claims be interpreted to embrace all such variations and modifications.