Composite material composition and a method of forming a composite material composition
10737458 ยท 2020-08-11
Assignee
Inventors
Cpc classification
B32B2307/50
PERFORMING OPERATIONS; TRANSPORTING
C08J2367/02
CHEMISTRY; METALLURGY
B32B5/26
PERFORMING OPERATIONS; TRANSPORTING
B32B3/26
PERFORMING OPERATIONS; TRANSPORTING
B32B2260/04
PERFORMING OPERATIONS; TRANSPORTING
C08J9/26
CHEMISTRY; METALLURGY
C08J2367/04
CHEMISTRY; METALLURGY
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/718
PERFORMING OPERATIONS; TRANSPORTING
B32B3/18
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/065
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/062
PERFORMING OPERATIONS; TRANSPORTING
B32B2250/20
PERFORMING OPERATIONS; TRANSPORTING
B32B5/028
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/106
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/546
PERFORMING OPERATIONS; TRANSPORTING
B32B5/12
PERFORMING OPERATIONS; TRANSPORTING
B32B2262/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B3/18
PERFORMING OPERATIONS; TRANSPORTING
B32B3/26
PERFORMING OPERATIONS; TRANSPORTING
B32B5/12
PERFORMING OPERATIONS; TRANSPORTING
B32B5/18
PERFORMING OPERATIONS; TRANSPORTING
C08J9/00
CHEMISTRY; METALLURGY
Abstract
A material composition including a matrix including a first material, the matrix including a plurality of voids disposed in the matrix, two or more voids being spaced apart from each other, a plurality of elongate fibers of a second material located within the matrix, wherein the plurality of fibers are configured to reinforce the matrix and, wherein the material composition is a composite material composition.
Claims
1. A composite material panel including a composite material composition with: a matrix formed of a first biodegradable polymer material, the matrix including a plurality of voids within the matrix, a major axis or diameter of the voids having a length between 50 micrometers and 400 micrometers; and a plurality of elongated fibers formed of a second biodegradable or recyclable material, the second biodegradable or recyclable material being different from the first biodegradable polymer material and wherein the second biodegradable material is more rigid or stiffer than the first biodegradable polymer material, the elongated fibers being located within the matrix and configured to reinforce the matrix, wherein the plurality of elongated fibers are arranged parallel to each other and are arranged in two or more parallel layers each with at least two elongated fibers, the two or more parallel layers include, at least, a first layer and a second layer, and the number of elongated fibers in the first layer is larger than the number of elongated fibers in the second layer; wherein the first biodegradable polymer material is polybutylene succinate or polylactic acid; and wherein the plurality of elongated fibers are carbon fibers, glass fibers, bamboo fibers, sisal fibers, cotton fibers, or coconut fibers.
2. The composite material panel in accordance with claim 1, wherein the voids are regularly spaced within the matrix, such that each void is equally spaced from at least two adjacent voids.
3. The composite material panel in accordance with claim 1, wherein at least one of the plurality of elongated fibers is equally spaced from two adjacent elongated fibers in the same layer.
4. The composite material panel in accordance with claim 1, wherein the plurality of elongated fibers are arranged in a longitudinal direction of the matrix such that longitudinal axes of the plurality of elongated fibers are parallel to a longitudinal axis of the matrix.
5. The composite material panel in accordance with claim 1, wherein the plurality of elongated fibers are arranged in a plurality of fiber bundles each having at least two elongated fibers attached to each other; and wherein the plurality of fiber bundles are spaced apart from each other and are arranged parallel to each other.
6. The composite material panel in accordance with claim 1, wherein the voids are arranged in a regular pattern.
7. The composite material panel in accordance with claim 1, comprising a polygon shaped body.
8. The composite material panel in accordance with claim 1, wherein the length of each elongated fiber is between 60 mm to 80 mm.
9. The composite material panel in accordance with claim 8, wherein the diameter of each elongated fiber is between 80 micrometres to 300 micrometres.
10. The composite material panel in accordance with claim 9, wherein the number of elongated fibers in the first layer is 1.5 times to 4 times the number of elongated fibers in the second layer.
11. The composite material panel in accordance with claim 1, wherein the first biodegradable polymer material is polybutylene succinate and wherein the plurality of elongated fibers are sisal fibers.
12. A composite material panel including a composite material composition with: a matrix formed of a first biodegradable polymer material, the matrix including a plurality of voids within the matrix, a major axis or diameter of the voids having a length between 50 micrometres and 400 micrometres, and wherein at least some of the voids are spherical or elliptical in shape; and and a plurality of elongated fibers formed of a second biodegradable or recyclable material, the second biodegradable or recyclable material being different from the first biodegradable polymer material and is more rigid or stiffer than the first biodegradable polymer material, the elongated fibers being located within the matrix and configured to reinforce the matrix; wherein the plurality of elongated fibers are arranged in a plurality fiber bundles each having at least two parallel elongated fibers attached to each other, and the plurality of fiber bundles are spaced apart from each other, arranged parallel to each other, and arranged in two or more parallel layers each with at least two elongated fibers bundles; wherein the first biodegradable polymer material is polybutylene succinate or polylactic acid, and wherein the plurality of elongated fibers are carbon fibers, glass fibers, bamboo fibers, sisal fibers, cotton fibers, or coconut fibers.
13. The composite material panel in accordance with claim 12, wherein a length of each fiber is between 60 mm to 80 mm.
14. The composite material panel in accordance with claim 13, wherein a diameter of each fiber is between 80 micrometres to 300 micrometres.
15. The composite material panel in accordance with claim 12, wherein the first material is Polybutylene Succinate and the plurality of elongated fibers are sisal fibers.
16. The composite material panel in accordance with claim 12, wherein the plurality of elongated fibers are arranged in a longitudinal direction of the matrix such that longitudinal axes of the plurality of elongated fibers are parallel to a longitudinal axis of the matrix.
17. A composite material panel including a composite material composition with: a matrix formed of a first biodegradable polymer material, the matrix including a plurality of voids within the matrix, a major axis or diameter of the voids having a length between 50 micrometres and 400 micrometres; and a plurality of elongated fibers formed of a second biodegradable or recyclable material, the second biodegradable or recyclable material being different from the first biodegradable polymer material and is more rigid or stiffer than the first biodegradable polymer material, the elongated fibers being located within the matrix and configured to reinforce the matrix; wherein the plurality of elongated fibers are arranged parallel to each other, and are arranged in two or more parallel layers each with at least two elongated fibers; wherein the first biodegradable polymer material is Polybutylene Succinate or Polylactic Acid, and wherein the plurality of elongated fibers are carbon fibers, glass fibers, bamboo fibers, sisal fibers, cotton fibers, or coconut fibers; wherein a length of each fiber is between 60 mm to 80 mm. and a diameter of each fiber is between 80 micrometres to 300 micrometres.
18. The composite material panel in accordance with claim 17, wherein the first material is Polybutylene Succinate and the plurality of elongated fibers are sisal fibers.
19. The composite material panel in accordance with claim 17, wherein the plurality of elongated fibers are arranged in a longitudinal direction of the matrix such that longitudinal axes of the plurality of elongated fibers are parallel to a longitudinal axis of the matrix.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) Embodiments of composite material composition and method of forming the composite material composition will be described, by way of example, with reference to the accompanying drawings in which:
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DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT
(9) The present disclosure is directed to a composite material composition that comprises a matrix formed of a first material and a plurality of fibers arranged to be embedded within and extending within the matrix. The matrix includes a plurality of voids within it. The voids within the matrix are dispersed throughout the matrix. The fibers are formed from a second material and the fibers are configured to reinforce the matrix. The first and second material are different materials and the second material is stiffer than the first material. The composite material composition is made from recyclable materials such that the composite material composition and any products using the composite material composition are environmentally friendly and sustainable. Some exemplary embodiments of a composite material will now be described with reference to the figures.
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(11) The composite material composition 100 is shown in form of a panel 110. As shown in
(12) Referring again to
(13) The matrix 120 acts as a body of medium to support the fibers and includes voids within it. The matrix 120 is a base of the composite material composition. The matrix can be shaped to any suitable shape by any suitable shaping or forming process.
(14) The matrix 120 further includes a plurality of voids 130. As shown in
(15) The voids 130 in the matrix 120 define a mesh structure within the matrix 120. The mesh structure includes a plurality of interstices or voids 130. The mesh structure of the matrix 120 is similar to a foam or foamed structure with a plurality of voids within a medium. The mesh structure of the matrix 120 is advantageous because it reduces the overall weight of the composite material composition and any product that includes the composite material composition such as a composite material panel.
(16) The elongate fibers 140 are embedded within the matrix 120, as shown in
(17) The fibers 140 extend the length of the body 10. Alternatively the fibers may only extend along a partial length of the body 10. The fibers 140 are unidirectional in the matrix 120. As shown in
(18) The fibers 140 are made from a second material. The second material is stiffer or more rigid than the first material. The second material of the fibers 140 has a higher density than the first material. Further the fibers 140 are denser than the matrix 120, since the matrix includes a plurality of voids while the fibers are solid or monolithic fibers. The second material is preferably also a non-toxic, biodegradable material. The second material may be a man-made or natural material. The second material may be one of a carbon, graphite, glass or a polymer. The fibers 140 may be carbon fibers, graphite fibers, glass fibers or polymer fibers, wherein the polymer is a biodegradable or recyclable polymer. Alternatively the second material may be bamboo, sisal, cotton or coconut. Preferably a man-made material such as glass or carbon is used to make the fibers to improve sustainability of the composite material composition and also make the composite material composition more environmentally friendly since plants or trees do not have to be harvested to form the fibers 140. The material for the fibers can be dependent on the required application. Preferably a recyclable or biodegradable polymer or material is used. The fibers can have any suitable dimensions as required. For example the length of the fibers can be between 60 mm and 80 mm with a diameter between 80 micrometers to 300 micrometers. Other dimensioned fibers can be utilized.
(19) The composite material composition may comprise two or more layers of fibers, wherein each layer of fibers includes a plurality of fibers.
(20) In an embodiment one layer of the two or more layers of fibers includes more fibers than one or more other layers. As shown in
(21) The number of layers of fibers is dependent on the overall dimensions of the composition, and in particular dependent on the thickness of the composition 100. For example the thicker the composition the more layers of fibers that can be accommodated or introduced into the composition. The number of layers can also be varied depending on the mechanical performance required by the composition or any construction using the composition. For example for a stiffer composition a greater number of fiber layers can be used.
(22) The composite material composition 100 may comprise a plurality of fiber bundles. Each fiber bundle comprises at least two fibers that are attached to each other or positioned adjacent each other. The fiber bundles may include a plurality of fibers that are bunched together. The fibers may be connected to each other or may be tightly packed together adjacent each other to form a bundle of fibers. The fiber bundles may be spaced apart from each other. In one example each fiber bundle comprises between 1000 to 4000 fibers. In a further example each fiber bundle comprises 3000 fibers.
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(25) Alternatively the void creating agent may be any suitable foaming agent, such as a chemical foaming agent. The chemical foaming agents can produce gas which can foam the voids at a specific condition. The foaming agent can be dissolved to create the voids.
(26) The method proceeds to step 306. At step 306 sheet or structure of first material and void creating agent is created by extrusion. The extrusion temperature 200 degrees Celcius and the extrusion rate is 50 rpm. In one example the sheet or structure created at step 306 may be created using a double screw extruder. The sheet or structure is the matrix of the composite material composition.
(27) At step 308 a plurality of elongate fibers are added to the matrix that comprises the first material and the void creating agent. The plurality of elongate fibers are made of a second material as described earlier. The fibers can be formed from any suitable process such rolling, turning, molding, casting, blowing or any other suitable process to create elongate fibers of a required diameter. The dimensions of the elongate fibers can be any suitable dimensions. Step 308 adding the fibers into the matrix by a moulding process such as for example a compression moulding process. The moulding compression pressure is 100 Pa, but the moulding compression pressure can be changed to suit the materials used to manufacture the composition.
(28) Step 310 comprises immersing the matrix, including the fibers, into a cooling bath for a specific time period to begin the nucleating process. The nucleating agent such as NaCl or NaHCO.sub.3 will cause structures to form within the matrix. The number or size or the number and size of the structures being controlled by the amount of time the matrix is immersed in the cooling bath The structures may be crystals. The crystal formation within the matrix as part of the nucleating process. The crystals start as spherulites and grow as the matrix is cooled. The crystals grow as the matrix is cooled following the compression moulding process. The fibers are act as physical barriers for the crystals of the nucleating agent. In one example the density of the nucleating agent, such as NaCl is 2.16 g/cm.sup.3 and the density of the matrix material, such as PBS is 1.26 g/cm.sup.3.
(29) The nucleating agent is used to increase the speed of crystallization within the first material. The cooling bath may be a water bath or any other cooling substance. The matrix is immersed in the cooling bath for several days to achieve the desired size and distribution of crystals. The crystals formed in the matrix may be crystals of the first material or may be crystals of the nucleating agent.
(30) Step 312 comprises removing the void forming agent and the structures created in the matrix. The structures relate to the voids. The voids in the matrix correspond to the size, shape and distribution of the structures formed within the matrix. As stated earlier, the structures may be crystals of either the first material or the nucleating agent. Removing the structures leaves a plurality of voids in the matrix that define a mesh structure in the matrix. The cooling at step 310 is carefully controlled to achieve a desired distribution, size and number of structures in order to achieve a desired mesh structure. The nucleating agent and the structures (e.g. crystals) are removed by using an ultrasonic clearing process. An ultrasonic clearing machine can be used to remove
(31) Step 314 comprises the step of cleaning the composite material composition as created by method 300. The step of cleaning removes any additional residual surface particulate matter, dust, dirt or other unwanted particles on the surface of the composition. The method 300 may include an additional step of steps to create a product or other arrangement using the composite material composition such as for example a composite material panel, a composite material food tray or a composite material book shelf and so on.
(32) The composite material composition 100 as described above can be made into various products using any suitable manufacturing or forming processes. The composite material composition 100 can be used to create furniture, panels, construction panels, office dividers, shoe racks, book shelves, food trays or other commodity products.
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(35) The composite material composition 100 as described is advantageous because it is relatively light weight due to the voids in the matrix, and has relatively high bending and/or buckling resistance due to the reinforcing elongate fibers. The increased bending and/or buckling resistance is achieved by using fibers that are made from a material that is stiffer than the matrix material and since the fibers are arranged in a longitudinal direction. The composite material composition as described is fabricated or manufactured to simulate bamboo and simulate the mechanical properties of bamboo. For example the composite material composition 100 can have a tensile modulus of between 200 GPa/kg and 900 GPa/kg. The strength of the composite material may be between 350 and 550 MPa/kg.
(36) The composite material composition 100 mimics the structure and mechanical properties of bamboo. The fibers 140 in the composition 100 are unidirectional and are similar to the vascular bundles of bamboo. The mesh structure of the matrix 120 mimics the cellular panechyma in bamboo. The structure of composition 100 provides any products that use the composition with low density while maintaining a high tensile strength, high compression strength, higher bending stiffness and a light weight.
(37) Any product that utilizes the composite material composition 100 will also have mechanical properties that are similar to bamboo due to the structure of the composition 100. The composite material composition 100 is advantageous because it includes a hierarchical graded distribution of elongate fibers and a mesh structure. This improves the bending stiffness of the composition 100 and any product that utilizes the composite material composition 100. The weight of any product using the composite material composition 100 is reduced due to the mesh structure of the matrix. The composite material composition 100 further includes a high strength to weight ratio. The composite material composition 100 has a lower density as compared to some wood and metal products due to the mesh structure of the matrix.
(38) The mesh structure with elongate reinforcing fibers of the composite material composition is advantageous because it improves the flexural stiffness, tensile strength and compression strength of the composition 100 and any products that use the composition 100.
(39) The composite material composition 100 is advantageous because as it is a man-made product that is chemically manufactured. The composition 100 has a lower environmental impact as compared to products made of wood or other plant materials. Products that utilize the composite material composition 100 can be cheaper to manufacture than similar products that are formed of wood or other natural plants such as furniture or construction panels. The composite material composition 100 is also advantageous because all the constituents of the composition 100 are biodegradable or recyclable materials. Therefore any products that are made of the composite material composition 100 are more likely to be recycled or broken down naturally when discarded, thus reducing the environmental impact. Products that use the composite material composition 100 are advantageous because they can be marketed as green or environmentally friendly products. This is because the composition 100 is made from biodegradable or recyclable materials.
(40) As stated earlier the composite material composition 100 mimics bamboo. However construction panels or other products that are used in construction made from bamboo can have inherent defects and raw bamboo can be difficult to form into products. The composite material composition 100 can be better controlled during the manufacturing process to reduce defects and the composition 100 is easier to form into other products.
(41) The term composition as used herein to describe a composite material composition is used to mean a configuration or arrangement or structure that includes various features or constituents that form the composition. The composite material composition may also be termed as a composite material arrangement or composite material configuration or a composite material structure. The composite material composition defines the make-up of the composite material as described herein and the particular composition can be used to form or manufacture specific products as described herein. It will be appreciated by persons skilled in the art that numerous variations and/or modifications may be made to the present invention as shown in the specific embodiments without departing from the spirit or scope of the present disclosure. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive.
(42) The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms a, an and the are intended to include plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms comprises or comprising, when used in this specification, specify the presence of stated features, integers, steps, operations, elements components and/or groups or combinations thereof, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components and/or groups or combinations thereof.
(43) As used herein, the term and/or includes any and all possible combinations or one or more of the associated listed items, as well as the lack of combinations when interpreted in the alternative (or).
(44) Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the specification and claims and should not be interpreted in an idealized or overly formal sense unless expressly so defined herein. Well-known functions or constructions may not be described in detail for brevity and/or clarity.
(45) Any reference to prior art contained herein is not to be taken as an admission that the information is common general knowledge, unless otherwise indicated. It is to be understood that, if any prior art information is referred to herein, such reference does not constitute an admission that the information forms a part of the common general knowledge in the art, any other country.