Thin film transistor and manufacturing method thereof
10644167 ยท 2020-05-05
Assignee
- Industrial Technology Research Institute (Hsinchu, TW)
- Intellectual Property Innovation Corporation (Hsinchu, TW)
Inventors
- Tai-Jui Wang (Kaohsiung, TW)
- Yung-Hui Yeh (Hsinchu, TW)
- Jui-Wen Yang (New Taipei, TW)
- Hsiao-Chiang Yao (Kaohsiung, TW)
- Chun-Hung Chu (Hsinchu, TW)
Cpc classification
H01L27/1237
ELECTRICITY
H01L27/1277
ELECTRICITY
H01L29/78678
ELECTRICITY
H01L21/02422
ELECTRICITY
H01L29/66757
ELECTRICITY
H01L29/78603
ELECTRICITY
H01L27/1255
ELECTRICITY
H10K10/466
ELECTRICITY
H01L29/78696
ELECTRICITY
International classification
H01L29/786
ELECTRICITY
H01L29/49
ELECTRICITY
H01L27/12
ELECTRICITY
H01L29/66
ELECTRICITY
Abstract
A thin film transistor including a flexible substrate, a semiconductor layer, a first gate, and a first gate dielectric layer is provided. The semiconductor layer is located on the flexible substrate. The first gate is located on the flexible substrate and corresponds to a portion of the semiconductor layer. The first gate dielectric layer is located between the first gate and the semiconductor layer. The first gate dielectric layer is in contact with the semiconductor layer, and the hydrogen atom concentration of the first gate dielectric layer is less than 6.510.sup.20 atoms/cm.sup.3. A method of manufacturing the thin film transistor is also provided.
Claims
1. A thin film transistor, comprising: a flexible substrate; a semiconductor layer, located on the flexible substrate, wherein a material of the semiconductor layer comprises a polysilicon material; a first gate, located over a portion of the semiconductor layer; a first gate dielectric layer, located between the first gate and the semiconductor layer, the first gate dielectric layer being in contact with the semiconductor layer, a hydrogen atom concentration of the first gate dielectric layer being less than 6.510.sup.20 atoms/cm.sup.3, wherein the semiconductor layer is located between the flexible substrate and the first gate, and the thin film transistor is capable of being bended to have a minimum bending radius of 1 mm; and a second gate, wherein the semiconductor layer is located between the first gate and the second gate.
2. The thin film transistor of claim 1, further comprising a second gate dielectric layer located between the first gate and the first gate dielectric layer, a hydrogen atom concentration of the second gate dielectric layer being greater than 6.510.sup.20 atoms/cm.sup.3.
3. The thin film transistor of claim 1, wherein a material of the first gate dielectric layer comprises silicon oxide, silicon nitride, or a combination thereof.
4. The thin film transistor of claim 1, further comprising: a source and a drain respectively coupled to opposite ends of the semiconductor layer.
5. A manufacturing method of a thin film transistor, comprising: forming a second gate on a flexible substrate; forming a semiconductor layer on the flexible substrate, wherein a material of the semiconductor layer comprises a polysilicon material, the second gate is formed before forming the semiconductor layer, and the semiconductor layer is formed on the second gate; forming a first gate dielectric layer on the semiconductor layer, the first gate dielectric layer being in contact with the semiconductor layer, a hydrogen atom concentration of the first gate dielectric layer being less than 6.510.sup.20 atoms/cm.sup.3; and forming a first gate on the first gate dielectric layer, the first gate corresponding to a portion of the semiconductor layer, wherein the thin film transistor is capable of being bended to have a minimum bending radius of 1 mm.
6. The manufacturing method of the thin film transistor of claim 5, further comprising: forming a second gate dielectric layer on the first gate dielectric layer before forming the first gate, a hydrogen atom concentration of the second gate dielectric layer being greater than 6.510.sup.20 atoms/cm.sup.3, the first gate being formed on the second gate dielectric layer.
7. The manufacturing method of the thin film transistor of claim 5, wherein a method of forming the first gate dielectric layer comprises plasma-enhanced chemical vapor deposition, and a ratio of an inert gas flow to a total process gas flow of the plasma-enhanced chemical vapor deposition for forming the first gate dielectric layer is from 0.5 to 0.7.
8. The manufacturing method of the thin film transistor of claim 5, wherein a deposition rate of forming the first gate dielectric layer is from 2.5 /sec to 3.5 /sec.
9. The manufacturing method of the thin film transistor of claim 5, further comprising: forming a source and a drain respectively coupled to opposite ends of the semiconductor layer.
10. The thin film transistor of claim 1, wherein a difference between a threshold voltage variation of the thin film transistor with a minimum bending radius of 1 mm and a threshold voltage variation of the thin film transistor that is not bended is below 0.05 volt.
11. The manufacturing method of the thin film transistor of claim 5, wherein a difference between a threshold voltage variation of the thin film transistor with a minimum bending radius of 1 mm and a threshold voltage variation of the thin film transistor that is not bended is below 0.05 volt.
12. The manufacturing method of the thin film transistor of claim 5, wherein a material of the first gate dielectric layer comprises silicon oxide, silicon nitride, or a combination thereof.
13. The manufacturing method of the thin film transistor of claim 5, wherein a process temperature of the step of forming the semiconductor layer on the flexible substrate is below 600 degrees Celsius.
14. A manufacturing method of a thin film transistor, comprising: forming a semiconductor layer on a flexible substrate, wherein a material of the semiconductor layer comprises a polysilicon material; forming a first gate dielectric layer on the semiconductor layer, the first gate dielectric layer being in contact with the semiconductor layer, a hydrogen atom concentration of the first gate dielectric layer being less than 6.510.sup.20 atoms/cm.sup.3, wherein a deposition rate of forming the first gate dielectric layer is from 2.5 /sec to 3.5 /sec; forming a first gate on the first gate dielectric layer, the first gate corresponding to a portion of the semiconductor layer, wherein the thin film transistor is capable of being bended to have a minimum bending radius of 1 mm.
15. The manufacturing method of the thin film transistor of claim 14, further comprising: forming a second gate dielectric layer on the first gate dielectric layer before forming the first gate, a hydrogen atom concentration of the second gate dielectric layer being greater than 6.510.sup.20 atoms/cm.sup.3, the first gate being formed on the second gate dielectric layer.
16. The manufacturing method of the thin film transistor of claim 14, wherein a method of forming the first gate dielectric layer comprises plasma-enhanced chemical vapor deposition, and a ratio of an inert gas flow to a total process gas flow of the plasma-enhanced chemical vapor deposition for forming the first gate dielectric layer is from 0.5 to 0.7.
17. The manufacturing method of the thin film transistor of claim 14, further comprising: forming a source and a drain respectively coupled to opposite ends of the semiconductor layer.
18. The manufacturing method of the thin film transistor of claim 14, wherein a difference between a threshold voltage variation of the thin film transistor with a minimum bending radius of 1 mm and a threshold voltage variation of the thin film transistor that is not bended is below 0.05 volt.
19. The manufacturing method of the thin film transistor of claim 14, wherein a material of the first gate dielectric layer comprises silicon oxide, silicon nitride, or a combination thereof.
20. The manufacturing method of the thin film transistor of claim 14, wherein a process temperature of the step of forming the semiconductor layer on the flexible substrate is below 600 degrees Celsius.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The accompanying drawings are included to provide a further understanding of the disclosure, and are incorporated in and constitute a part of this specification. The drawings illustrate embodiments of the disclosure and, together with the description, serve to explain the principles of the disclosure.
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DESCRIPTION OF THE EMBODIMENTS
(12)
(13) Referring to
(14) In some embodiments, a buffer layer 120 may be first formed on the flexible substrate 110 before forming a subsequent film. The buffer layer 120 may be a single-layered thin film or a stacked layer composed of a plurality of thin films; the number of layers of the buffer layer 120, the material of the buffer layer 120, or the way to form the buffer layer 120 is not limited in the embodiment. When the buffer layer 120 is the stacked layer composed of a plurality of thin films, the buffer layer 120 is, for example, a stacked layer composed of organic and inorganic thin films that are alternately stacked, or the buffer layer 120 may be a stacked layer composed of a plurality of inorganic thin films stacked together. When the buffer layer 120 is the stacked layer composed of a plurality of inorganic thin films stacked together, the buffer layer 120 may be a stacked layer in which silicon nitride (SiN.sub.x) and silicon oxide (SiO.sub.x) are alternately stacked. The buffer layer 120 may be characterized by a good bonding force or a lower vapor water transmission rate (VWTR), so as to enhance the reliability of a thin film transistor 100. The buffer layer 120 may also be characterized by good thermal insulation, so as to reduce possible impact on the flexible substrate 110 due to a temperature increase during a process of forming the subsequent film.
(15) Next, a semiconductor layer 130 is formed on the flexible substrate 110. For example, a chemical vapor deposition (CVD) process, a photolithography and etching process, or other similar deposition processes and a patterning process may be applied to form a patterned amorphous silicon film on the flexible substrate 110. The amorphous silicon film may then become a polysilicon film via laser crystallization or excimer laser annealing (ELA), and the amorphous silicon film may be scanned with use of a laser and is recrystallized, so that the amorphous silicon film may become the semiconductor layer 130 with polysilicon. In other words, the material of the semiconductor layer 130 may include a polysilicon material. This technology of forming polysilicon may be referred to as a low temperature polysilicon (LTPS) process. In general, the entire manufacturing process of the semiconductor layer 130 may be performed at a low process temperature (e.g., below 600 degrees Celsius) through performing the LTPS process, so that the flexible substrate 110 may still have good stability or properties during the manufacturing process of the semiconductor layer 130.
(16) In some embodiments, an ion implantation process (not shown) may be further performed, so that the resultant semiconductor layer 130 may have doped ions, and a channel region 130b with N-type or P-type dopant may be formed according to different types of doped ions.
(17) Referring to
(18) In the PECVD process of forming the first gate dielectric layer 140, a ratio of an inert gas flow to the total process gas flow is from 0.5 to 0.7, so that a hydrogen atom concentration of the first gate dielectric layer 140 formed may be less than 6.510.sup.20 atoms/cm.sup.3. In the embodiment, the inert gas may be He, but the disclosure is not limited thereto. In other embodiments, the inert gas may also be helium (He), neon (Ne), argon (Ar), krypton (Kr), xenon (Xe), radon (Rn), or a combination thereof. In addition, in the PECVD process of forming the first gate dielectric layer 140, other process parameters (e.g., radio frequency (Rf) power) may be adjusted, so that a good deposition rate (e.g., 2.5 /sec to 3.5 /sec) and good film quality may be achieved.
(19) Next, referring to
(20) An ion implantation process (not shown) is then performed with use of the first gate dielectric layer 140 as a mask to form a source region 130a and a drain region 130c separated from each other at opposite ends of the semiconductor layer 130. The ion implantation process on the source region 130a and the drain region 130c is, for example, performed by implanting ions with appropriate energy, such as arsenic (As), phosphorus (P) and boron (B) as doped ions, so as to form P-type or N-type source region 130a and drain region 130c.
(21) With reference to
(22) In the embodiment, the insulation layer 160 conformally covers the first gate dielectric layer 140 and the first gate 150, but the disclosure is not limited thereto. In some embodiments, the insulation layer 160 may have a flat surface through performing a polishing process, for example, so that other films subsequently formed on the insulation layer 160 may be located on the flat surface of the insulation layer 160.
(23) First and second openings 160a and 160b may then be formed on the insulation layer 160 through performing an etching process or a laser drilling process. The first openings 160a penetrate the insulation layer 160 and the first gate dielectric layer 140 to expose a portion of the source region 130a and a portion of the drain region 130c. The second opening 160b penetrates the insulation layer 160 to expose a portion of the first gate 150.
(24) With reference to
(25) In the embodiment, the conductive substance filling the first openings 160a and the second opening 160b may further cover the insulation layer 160. Subsequently, the conductive substance covering the insulation layer 160 may be patterned through performing the photolithography and etching process to form a patterned conductive layer 170.
(26) After said manufacturing steps are performed, the thin film transistor 100 provided in the embodiment is substantially formed. The thin film transistor 100 includes the flexible substrate 110, the semiconductor layer 130, the first gate 150, the first gate dielectric layer 140, the source S, and the drain D. The semiconductor layer 130 is located on the flexible substrate 110 and includes the source region 130a, the channel region 130b, and the drain region 130c, wherein the channel region 130b is located between the source region 130a and the drain region 130c. The source S and the drain D are respectively coupled to the source region 130a and the drain region 130c of the semiconductor layer 130. The first gate 150 is located on the flexible substrate 110 and corresponds to the channel region 130b of the semiconductor layer 130. The first gate dielectric layer 140 is located between the first gate 150 and the semiconductor layer 130, the first gate dielectric layer 140 is in contact with the semiconductor layer 130, and a hydrogen atom concentration of the first gate dielectric layer 140 is less than 6.510.sup.20 atoms/cm.sup.3.
(27) In silicon thin films, silicon atoms and hydrogen atoms may generate SiH bonding through doped hydrogen atoms, so as to reduce the number of dangling bonds of silicon atoms within a silicon film. In normal electronic devices, if the transistors of the electronic devices subject to a bending force may have electrical defects (e.g., changes of threshold voltage (Vth)) because the SiH bonding in the gate dielectric layer is broken. Therefore, in the thin film transistor 100 provided in the embodiment, the hydrogen atom concentration of the first gate dielectric layer 140 may be reduced, so as to correspondingly reduce the number of SiH bonds in the first gate dielectric layer 140. Thereby, after the bending stress is exerted to the thin film transistor 100, the possible electrical defects of the thin film transistor 100 due to the bond breaking of the SiH bonding in the first gate dielectric layer 140 may be reduced. For example, in the embodiment, since the hydrogen atom concentration of the first gate dielectric layer 140 is less than 6.510.sup.20 atoms/cm.sup.3, the thin film transistor 100 may have a small bending radius of at least 1 mm. A difference between a threshold voltage variation of the thin film transistor 100 with the small bending radius of at least 1 mm and the threshold voltage variation of the thin film transistor 100 that is not bended is below 0.05 volt (V). That is, there is not much change in the threshold voltage variation of the thin film transistor 100.
(28) In the embodiment, the semiconductor layer 130 is located between the flexible substrate 110 and the first gate 150. In other words, the thin film transistor 100 in the embodiment has a top gate structure, but the disclosure is not limited thereto.
(29) In the embodiment, the semiconductor layer 130 is formed through performing the LTPS process. In other words, a material of the semiconductor layer 130 includes crystalline silicon and/or amorphous silicon, but the disclosure is not limited thereto.
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(32) Referring to
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(35) Referring to
(36) Next, referring to
(37) Next, referring to
(38) Next, referring to
(39) Next, referring to
(40) After the above-mentioned manufacturing steps are performed, the thin film transistor 500 provided in the embodiment may be substantially formed. The difference between the thin film transistor 500 provided in the embodiment and the thin film transistor 100 depicted in
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EXPERIMENTAL EXAMPLE
(44) The following experimental example is intended to illustrate that there is not much change in a threshold voltage variation of a thin film transistor according to an embodiment of the disclosure while the bending extent is significant. However, the experimental example does not limit the scope of the disclosure.
(45) Please refer to both
(46) Specifically, when the same thin film transistor is measured before and after it is bent,
(47) In
(48) To sum up, the gate dielectric layer of the thin film transistor according to an embodiment of the disclosure is in contact with the semiconductor layer and has the hydrogen atom concentration of less than 6.510.sup.20 atoms/cm.sup.3, so that the number of SiH bonds within the gate dielectric layer is corresponding reduced. Therefore, after the thin film transistor is subject to the bending stress, the possible electrical defects of the thin film transistor due to the bond breaking of the SiH bonding in the first gate dielectric layer 140 may be reduced, thereby enhancing the reliability of the thin film transistor.
(49) It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the disclosure without departing from the scope or spirit of the disclosure. In view of the foregoing, it is intended that the disclosure cover modifications and variations of this disclosure provided they fall within the scope of the following claims and their equivalents.