Method and appliance for cutting materials by multi-beam femtosecond laser
11883903 · 2024-01-30
Assignee
- AMPLITUDE (Pessac, FR)
- Centre National De La Recherche Scientifique (Paris, FR)
- Universite De Bordeaux (Bordeaux, FR)
- ALPHANOV INSTITUT D'OPTIQUE D'AQUITAINE (Talence, FR)
Inventors
- Konstantin Mishchik (Bordeaux, FR)
- John LOPEZ (GRADIGNAN, FR)
- Rainer Kling (Cestas, FR)
- Clémentine Javaux-Leger (Leognan, FR)
- Guillaume Duchateau (Pessac, FR)
- Ophélie Dematteo-Caulier (Ychoux, FR)
Cpc classification
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
G02B27/0927
PHYSICS
B33Y30/00
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0676
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0006
PERFORMING OPERATIONS; TRANSPORTING
B23K26/0624
PERFORMING OPERATIONS; TRANSPORTING
B23K26/359
PERFORMING OPERATIONS; TRANSPORTING
B23K2103/50
PERFORMING OPERATIONS; TRANSPORTING
International classification
B23K26/00
PERFORMING OPERATIONS; TRANSPORTING
B23K26/06
PERFORMING OPERATIONS; TRANSPORTING
B23K26/067
PERFORMING OPERATIONS; TRANSPORTING
B23K26/359
PERFORMING OPERATIONS; TRANSPORTING
B23K26/53
PERFORMING OPERATIONS; TRANSPORTING
B33Y10/00
PERFORMING OPERATIONS; TRANSPORTING
B33Y30/00
PERFORMING OPERATIONS; TRANSPORTING
G02B19/00
PHYSICS
G02B27/09
PHYSICS
Abstract
Disclosed is a method for cutting dielectric or semiconducting material with a laser. The method includes the following steps: emission of a laser beam including at least one burst of N femtoseconds laser pulses; spatial separation of the laser beam into a first split beam having a first energy, and respectively, a second split beam having a second energy; spatial concentration of energy of the first split beam in a first zone of the material, respectively, of the second split beam in a second zone of the material, the first zone and the second zone being separate and staggered by a distance dx; and adjustment of the distance between the first zone and the second zone in such a way as to initiate a straight micro-fracture oriented between the first zone and the second zone.
Claims
1. A method for laser cutting dielectric or semiconductor materials, wherein said method comprises the following steps: emitting in single-pulse mode at a rate, a laser beam (100) at a wavelength comprised in a spectral band of transparency of the material comprised between 250 nm and 2.2 m, the laser beam (100) comprising successive bursts of N laser pulses, where N is a natural integer higher than or equal to 2 and lower than or equal to 20, said laser pulses having a duration comprised between 10 and 900 femtoseconds, the N laser pulses of one burst being temporally separated from each other by a time interval defined by a pulse rate of 1 GHz to 10 Ghz and a repetition rate of the successive bursts of N laser pulses being comprised between 1 kHz and 10 MHz; spatially splitting the laser beam (100) into a first split beam (101) having a first energy distributed along a first optical axis and, respectively, a second split beam (102) having a second energy distributed along a second optical axis distinct from the first optical axis, the first energy and the second energy are lower than 1 mJ and higher than 1 nJ, the first energy and the second energy being higher than a material modification threshold, and wherein an upper limit of the energy domain is fixed by the threshold of damages which are optically viewable, to the naked eye or using an optical microscope; spatially concentrating the energy of the first split beam (101) in a first area (31) of the material and, simultaneously, that of the second split beam (102) in a second area (32) of the material, the first area (31) and the second area (32) being separated from each other and spaced apart by a distance dx, so as to produce localized modifications in the first area (31) and in the second area (32) without generating material ablation or microbubbles in the material; and adjusting the distance (dx) between the first area (31) and the second area (32), the distance (dx) being comprised between 1 micrometre and about ten micrometres so as to initiate an oriented rectilinear micro-fracture (45), this micro-fracture (45) being oriented along a predetermined direction extending between the first area (31) and the second area (32).
2. The method according to claim 1, wherein the laser beam (100) emitted by the laser source having Gaussian spatial distribution, the first split beam (181) and the second split beam (182) are spatially shaped so as to each have a Bessel beam spatial distribution.
3. The method according to claim 2, wherein the Bessel beam spatial distribution of the first split beam (181) is transversally and/or longitudinally modified along the optical axis of the first split beam in the first area (31) and/or, respectively, the Bessel beam spatial distribution of the second split beam (182) is transversally and/or longitudinally modified along the optical axis of the second split beam in the second area (32).
4. The method according to claim 2, wherein the step of spatially splitting the laser beam is adapted to generate a plurality of M spatially-split beams, where M is a natural integer higher than or equal to three, the plurality of M spatially-split beams having a lateral offset relative to each other, taken two-by-two, and wherein the step of spatial concentration of energy comprises spatially concentrating the energy of the plurality of M split beams in a plurality of M separated areas of the material, each split beam having an energy higher than a material modification threshold, and wherein an upper limit of the energy domain is fixed by the threshold of damages which are optically viewable, to the naked eye or using an optical microscope so as to produce a plurality of localized modifications in the plurality of M separated areas of the material without generating material ablation or microbubbles in the material; and adjusting the distance between any two areas among the plurality of M separated areas, the distance (dx) being comprised between 1 micrometre and about ten micrometres, so as to initiate an oriented rectilinear microfracture between said any two areas among the plurality of M separated areas.
5. The method according to claim 3, wherein the step of spatially splitting the laser beam is adapted to generate a plurality of M spatially-split beams, where M is a natural integer higher than or equal to three, the plurality of M spatially-split beams having a lateral offset relative to each other, taken two-by-two, and wherein the step of spatial concentration of energy comprises spatially concentrating the energy of the plurality of M split beams in a plurality of M separated areas of the material, each split beam having an energy higher than a material modification threshold, and wherein an upper limit of the energy domain is fixed by the threshold of damages which are optically viewable, to the naked eye or using an optical microscope so as to produce a plurality of localized modifications in the plurality of M separated areas of the material without generating material ablation or microbubbles in the material; and adjusting the distance between any two areas among the plurality of M separated areas, the distance (dx) being comprised between 1 micrometre and about ten micrometres, so as to initiate an oriented rectilinear micro-fracture between said any two areas among the plurality of M separated areas.
6. The method according to claim 1, wherein the step of spatially splitting the laser beam (100) is adapted to generate a plurality of M spatially-split beams, where M is a natural integer higher than or equal to three, the plurality of M spatially-split beams having a lateral offset relative to each other, taken two-by-two, and wherein the step of spatial concentration of energy comprises spatially concentrating the energy of the plurality of M split beams in a plurality of M separated areas of the material, each split beam having an energy higher than a material modification threshold, and wherein an upper limit of the energy domain is fixed by the threshold of damages which are optically viewable, to the naked eye or using an optical microscope so as to produce a plurality of localized modifications in the plurality of M separated areas of the material without generating material ablation or microbubbles in the material; and adjusting the distance (dx) between any two areas among the plurality of M areas, the distance (dx) being between 1 micrometre and about ten micrometres, so as to initiate an oriented rectilinear micro-fracture (45) between said any two areas among the plurality of M separated areas.
7. The method according to claim 1, further comprising a step of relative displacement between said split beams and the material.
8. The method according to claim 1, further comprising an additional step of applying another laser beam, laterally offset by a distance lower than one millimetre with respect to said micro-fracture, this other laser beam having an energy lower than the material ablation threshold so as to cause a thermal stress without additional micro-fracturing of dielectric or semiconductor material.
Description
DETAILED DESCRIPTION OF AN EXEMPLARY EMBODIMENT
(1) The following description in relation with the appended drawings, given by way of non-limitative examples, will allow a good understanding of what the invention consists in and how it can be implemented.
(2) In the appended drawings:
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METHOD AND APPLIANCE
(22) In the present application and in the figures, the same reference signs denote identical or similar elements.
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(24) A sample 3 is arranged on a sample-holder. The sample 3 is made of a transparent dielectric material, for example tempered or not glass, or of a semiconductor material. The sample 3 is in the form of a plate having a generally uniform thickness, comprised between a few tenths of millimetres and a few millimetres, and preferably between 100 microns and one millimetre.
(25) The system comprises a laser source 1 generating a beam 100 comprising femtosecond pulses, as described in relation with
(26) A splitting plate 21, for example a semi-transparent plate, splits the beam 100 into a first laser beam 101 and a second laser beam 102. A mirror 22 reflects the second laser beam 102 along an optical axis parallel to and located at a distance dx from the optical axis of the first laser beam 101. This system allows applying simultaneously the first laser beam 101 in a first interaction area 31 of the sample and the second laser beam 102 in a second interaction area 32 of the sample. By way of example, the sample-holder is mounted mobile in translation on a stage, so as to allow the sample 3 to be displaced with respect to the laser beams 101, 102, which are fixed.
(27) The spacing, denoted dx, between the optical axis of the first beam 101 in the first area 31 and the optical axis of the second beam 102 in the second area 32 of the sample is adjusted with a sub-micrometric accuracy.
(28) The appliance of
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(30) In particular conditions of pulse duration and spatial spacing dx between the two impacted areas, this system surprisingly makes it possible to generate an oriented micro-fracture, this micro-fracture being oriented along a predetermined direction extending between the first area 31 and the second area 32 of the sample. Moreover, this configuration offers the advantage not to generate material ablation or microbubbles in the material. The so-obtained cutting surface has a surface roughness comprised between 0.2 m and 5 m. Consequently, the cutting method allows avoiding additional steps of polishing or precision grinding.
(31) It ensues from the present disclosure that the adjustment of the spacing dx between two adjacent areas impacted by the same initial split beam is hence critical for the generation of an oriented rectilinear micro-fracture 45, this micro-fracture 45 being oriented along a predetermined direction extending between these two adjacent areas.
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(34) Particularly advantageously, a sequence of femtosecond pulses, usually called burst mode, illustrated in
(35) According to the present disclosure, the burst mode is combined with the beam spatial splitting to generate an oriented rectilinear micro-fracture, this micro-fracture extending between two interaction areas distant from each other by dx. The combination of the spatial splitting of the laser beam and of the temporal splitting of a femtosecond pulse into a burst of femtosecond pulses has for effect to maximize the localization of the energy deposition made by the femtosecond pulses. The use of femtosecond pulses allows obtaining a maximum of absorption of the energy available in the material. However, the femtosecond pulses induce a less spatially localized absorption than a picosecond pulse. Nevertheless, the use of a burst allows a relocalization of the energy deposited. This concentration of the deposited energy allows a micro-fracturing and, thereafter, a direct cutting of the material. Moreover, the spatial splitting and temporal splitting make it possible to control the generation of non-linear optical effects in the material.
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(38) Without being bound by the theory, the use of a double beam, or, more generally a multi-beam, makes it possible to control the stresses induced in the material, and hence to orient the micro-crack or micro-fracture.
(39) On the one hand, the spacing dx is adjusted to be large enough so that the conditions of absorption of a beam are not too modified by the absorption of the adjacent beam. In the other hand, dx must not be too large in order for an effect of orientation of the fracture initiation to be efficient. By way of non-limitative example, a spacing dx is chosen between 1 m and 10 m, for sizes of the areas 31 and 32 each lower than 2 m.
(40) On the other hand, the sum of the energy of the first laser beam 101 and of the energy of the second laser beam 102 is herein equal to the energy of the laser beam 100 of
(41) The oriented micro-fracture 45 is generated at an energy that is lower than the energy required for a significant internal modification of the material. For each material to be cut, there exists an optimum energetic domain, depending of each material. This domain is inferiorly limited in energy by the material modification threshold. This threshold is lower than the threshold of damages that are optically viewable, to the naked eye or using an optical microscope (fusion, creation of bubbles, also called voids). On the other hand, this lower energy threshold can be viewed using instruments such as a polarizing or phase-contrast microscope. The upper limit of the energy domain is fixed by the threshold of damages which are optically viewable, to the naked eye or using an optical microscope.
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(43) The cutting appliance comprises: a laser source 1, an optical system comprising mirrors M1, M2, M3, a beam splitter 11, another beam splitter 12 and a focusing lens 4.
(44) The laser source 1 generates a laser beam 100 consisted of femtosecond pulses, such as described in relation with
(45) By way of non-limitative example, the laser beam 100 coming from the source 1 is linearly polarized. A planar mirror 10 reflects the laser beam 100 towards a beam splitter 11. The beam splitter 11 spatially splits the laser beam 100 into a first beam 101 directed along a first optical axis and a second beam 102 directed along a second optical axis. Preferably, at the exit of the beam splitter 11, the energy of the first beam 101 is equal to the energy of the second beam 102. A mirror M1 and, respectively, M2, reflects the first beam 101 and, respectively, the second beam 102, towards another beam separator 12. The beam separator 12 recombines the first beam 101 and the second beam 102 while maintaining an angular offset, denoted GAMMA, between the first optical axis and the second optical axis. A mirror M3 reflects the first beam 101 and the second beam 102 towards an optical system 4, for example a microscope lens. The optical system 4 focuses the first beam 101 in a first area 31 of the sample 3 and, simultaneously, the second beam 102 in a second area 32 of the sample 3.
(46) The system of
(47) The orientation of the mirror M1 and/or of the mirror M2 allows adjusting the position of the first area 31 with respect to the position of the second area 32, by means of the angle gamma.
(48) The system of
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(52) The method of the present disclosure is operational at high laser rate (>200 kHz), which allows increasing the cutting speed up to several metres per second, because it is not penalized by a phenomenon of heat accumulation in the material. For that purpose, the laser beams are displaced with respect to the sample so as to avoid the spatial overlapping between two consecutive pulses (or bursts), to obtain a cutting speed of the order of 100 mm/s at 10 kHz, 1 m/s at 100 kHz or 10 m/s at 1 MHz.
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(55) In a first exemplary embodiment, illustrated in
(56) In another exemplary embodiment, illustrated in
(57) According to another exemplary embodiment, illustrated in
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(61) In the simulation examples illustrated in
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(63) The Bessel beam 184 obtained in
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(65) In all the cases viewed in
(66) Line 1): a conventional optical microscope. This technique allows visualizing the cracks, the defects and the coloured centres of the material.
(67) Line 2): a phase-contrast microscope. This technique allows visualizing the modifications of the material associated with a modification of the refractive index (not visible with an optical microscope).
(68) Line 3): a crossed-polarisation microscope. This technique allows visualizing the distribution of the stresses induced around the modified areas.
(69) Different exemplary embodiments are visualized:
(70) Column a): Standard Bessel beam. This beam is obtained according to the device illustrated in
(71) Column b): Standard Bessel beam in burst mode, with 4 pulses per burst, each pulse in a burst being separated from another pulse of the same burst by a time interval of 25 ns.
(72) Column c): Narrow Bessel beam, obtained according to the device illustrated in
(73) In the cases a) and b), the optical microscope shows very few observable modifications, only the case c) lets appear micro-cracks, the energy localization is hence sufficient in this case. The phase-contrast microscope reveals that the case a) has neither generated a modification of index in the material. On the other hand, the use of the burst mode makes it possible to sufficiently localize the energy to obtain strong variations of index. In the case c), the presence of fractures scatters the light and prevents from obtaining a sharp image. The cross-polarization microscope neither reveals modifications in the case a), confirms in the case b) the presence of stresses locally induced around the areas affected by the beam, and of wider areas around the fractures induced in the case c).
(74) The optimum adjustment of the spatial splitting of the beam, of the burst mode and of the Bessel beam spatial shaping hence makes it possible to define the conditions of an energy deposition allowing the initiation of fractures, while minimizing the induced stress area.
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(76) An example of phase mask 90 is illustrated in
(77) Another example of diffractive optical element 90 is illustrated in
(78) The method allows generating micro-fractures arranged one after each other while being tangent to the desired cutting line. Generally, the separation is spontaneous. In the case where the separation is not immediate or spontaneous, a variant of the method consists in applying another laser beam laterally offset with respect to the micro-fractures on the side of the part which is not desired to be kept, over a distance lower than one millimetre with respect to the cutting trajectory. This other laser beam has different laser characteristics so as to bring a slight thermal stress without micro-fracturing nor additional cutting of the material. For that purpose, the other laser beam has an energy lower than the ablation threshold, in single-pulse mode and not in burst mode, and can operate at a higher rate. This additional step allows a contactless separation of the cut part from the plate of dielectric or semiconductor material.
(79) The method of the present disclosure applies in particular to the cutting of transparent, amorphous or crystalline mineral dielectric materials, such as chemically tempered glass, standard glass or sapphire, or to the cutting of semiconductor materials, for example silicon or germanium. By transparent, it is meant transparent to the laser wavelength. By mineral, it is meant non-organic and non-metallic. The material to be cut may be reinforced/tempered (with pre-stresses or variable stress profile on the thickness) or normal (without pre-stress). The following materials may be mentioned in non-exhaustive and non-limitative way: tempered sodiocalcic glass used in applications of mobile phone or electronic tablet screen protection (for example, Gorilla glass from Coring, Dragon Trail from Asahi Glass or Xensation from Schott) or high-resolution flat display screens. Several Gorilla nuances exist as a function of the chemical tempering thickness (DOL, for Depth of Layer, of 30 to 50 m), the glass thickness and its mechanical strength and scratch resistance; reinforced borosilicate glass (Eagle from Corning), or erosion-thinned tempered glass; tempered sodiocalcic glass for household appliances (Flat Glass from Schott, of thickness higher than 1 mm); sodiocalcic glass for application in the building and architecture fields; borosilicate glass for ophthalmologic optical glasses; melted silica, quartz, fluorinated glasses for UV optical glasses; chalcogenide glass for mean IR optical glasses; sapphire used as a LED substrate, protective glass for CCD sensor in smart-electronics, protective glass for moving parts or casings in watchmaking, multi-layer laminated glass, comprising a plastic or adhesive film taken between two layers of glass.
(80) More particularly, the invention finds applications in: curvilinear cutting of tempered sodiocalcic glass used as a protective glass for the portable electronic devices with or without a touch-screen (mobile phone, smart phone, electronic tablet); linear cutting of tempered sodiocalcic glass for high-resolution flat display screens (TV, display, computer); curvilinear cutting of tempered glass used as a protective glass in the military ground display systems; curvilinear cutting of protective glass or sapphire for CCD sensors used in optoelectronics or electronics, for example the protective glass of a portable phone photo/video lens; curvilinear cutting of optical components made of borosilicate glass or melted silica; cutting of ultrathin glass of 30 to 40 m thick; cutting of glass tube for medical applications; singulation of sapphire used as a substrate for the blue LEDs in optoelectronics; cutting of doped or non-doped YAG crystal, or of diamond, for photonic components.