WINDSHIELD FOR VEHICLE AND METHOD FOR MANUFACTURING THE SAME
20230211587 · 2023-07-06
Assignee
Inventors
- Lele TU (Fuqing, CN)
- Hui WANG (Fuqing, CN)
- Xianping LIU (Fuqing, CN)
- Jinliang GUAN (Fuqing, CN)
- Feng CAI (Fuqing, CN)
Cpc classification
B32B2255/28
PERFORMING OPERATIONS; TRANSPORTING
B32B1/00
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10743
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10348
PERFORMING OPERATIONS; TRANSPORTING
B32B27/304
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10229
PERFORMING OPERATIONS; TRANSPORTING
B41M5/00
PERFORMING OPERATIONS; TRANSPORTING
B32B17/1055
PERFORMING OPERATIONS; TRANSPORTING
B60J1/02
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/4023
PERFORMING OPERATIONS; TRANSPORTING
B32B3/08
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10889
PERFORMING OPERATIONS; TRANSPORTING
B32B27/306
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10211
PERFORMING OPERATIONS; TRANSPORTING
B32B27/30
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10183
PERFORMING OPERATIONS; TRANSPORTING
B32B7/02
PERFORMING OPERATIONS; TRANSPORTING
B32B27/308
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10064
PERFORMING OPERATIONS; TRANSPORTING
C03C17/3681
CHEMISTRY; METALLURGY
C03C17/42
CHEMISTRY; METALLURGY
International classification
B60J1/02
PERFORMING OPERATIONS; TRANSPORTING
B32B7/12
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A windshield for a vehicle and a method for manufacturing the windshield are provided in the disclosure. The windshield includes an outer glass panel, an inner glass panel, and an intermediate adhesive layer. An opaque masking layer is disposed on at least one surface of the windshield. The opaque masking layer includes a dark ceramic-ink layer and an ultraviolet-drying ink layer. The dark ceramic-ink layer has a first no-ink region, the ultraviolet-drying ink layer is located in the first no-ink region, the ultraviolet-drying ink layer has a light transmitting region. According to the disclosure, an optical quality of the light transmitting region can be ensured, a diopter of the light transmitting region is less than or equal to 200 mdpt.
Claims
1. A windshield for a vehicle, comprising an outer glass panel, an inner glass panel, and an intermediate adhesive layer, the outer glass panel having a first surface toward an outside of the vehicle and a second surface toward an inside of the vehicle, the inner glass panel having a third surface toward the outside of the vehicle and a fourth surface toward the inside of the vehicle, the second surface being bonded with the third surface via the intermediate adhesive layer, and at least one of the outer glass panel or the inner glass panel being a bent glass panel that is formed by subjecting a flat glass panel to high-temperature heat treatment of at least 560° C. and bending process, wherein the windshield further comprises an opaque masking layer, wherein the opaque masking layer comprises a dark ceramic-ink layer and an ultraviolet-drying ink layer, wherein the dark ceramic-ink layer is disposed on at least one of the second surface or the fourth surface, the ultraviolet-drying ink layer is disposed on at least one of the second surface, the third surface, or the fourth surface, the dark ceramic-ink layer has a first no-ink region, and wherein the ultraviolet-drying ink layer is located in the first no-ink region, and the ultraviolet-drying ink layer has a light transmitting region, wherein the light transmitting region has a diopter less than or equal to 200 milli-diopter (mdpt).
2. The windshield of claim 1, comprising at least one image acquisition device that is disposed at a side of the windshield inside the vehicle, wherein the image acquisition device is configured to perform image acquisition through the light transmitting region.
3. The windshield of claim 2, wherein the light transmitting region is larger than a region of the windshield in a field of view of the image acquisition device in outline by 1 mm to 5 mm.
4. The windshield of claim 1, wherein the dark ceramic-ink layer is formed by being disposed on the flat glass panel and subjected to high-temperature heat treatment of at least 560° C. and bending process, and the ultraviolet-drying ink layer is formed on the bent glass panel that is formed through high-temperature heat treatment of at least 560° C. and bending process or on another flat glass panel without being subjected to high-temperature heat treatment of at least 560° C. and bending process.
5. The windshield of claim 1, wherein the first no-ink region has a first boundary, the ultraviolet-drying ink layer has a second boundary, the light transmitting region has a third boundary, the second boundary is larger than or equal to the first boundary, and a distance between the second boundary and the third boundary is greater than or equal to 5 mm.
6. The windshield of claim 5, wherein the distance between the second boundary and the third boundary ranges from 10 mm to 80 mm.
7. The windshield of claim 1, comprising a dark ceramic-ink region at a periphery of the windshield, wherein the dark ceramic-ink region is coated with black ceramic-ink or brown ceramic-ink.
8. The windshield of claim 1, wherein the dark ceramic-ink layer comprises an organic solvent and an inorganic powder, a mass percent of the inorganic powder in the dark ceramic-ink layer ranges from 70% to 85%, and the inorganic powder comprises a glass glaze, a pigment, and an additive, wherein the glass glaze has an average particle-size ranging from 5 .Math.m to 10 .Math.m.
9. The windshield of claim 1, wherein the ultraviolet-drying ink layer is formed through ultraviolet curing at a temperature lower than or equal to 200° C.
10. The windshield of claim 1, wherein the ultraviolet-drying ink layer comprises an ultraviolet-curable resin, a diluted acrylate monomer, a pigment, a photoinitiator, and an additive.
11. The windshield of claim 1, wherein a thickness of the dark ceramic-ink layer is larger than 15 .Math.m and a thickness of the ultraviolet-drying ink layer is larger than 15 .Math.m, and a difference between the thickness of the dark ceramic-ink layer and the thickness of the ultraviolet-drying ink layer is less than or equal to 1 .Math.m.
12. The windshield of claim 1, wherein Lab values of the dark ceramic-ink layer satisfy 4.5 <L1 <7.2, -2.3 <a1 <0.85, -1.5 <b1 < 1.8, a total color difference ΔE between the ultraviolet-drying ink layer and the dark ceramic-ink layer satisfies ΔE< 1, and the total color difference ΔE is calculated according to the following formula:
13. The windshield of claim 1, further comprising a transparent conductive film on at least one of the second surface, the third surface, or the fourth surface, wherein the transparent conductive film defines a film-free window that corresponds to the light transmitting region, and the film-free window is formed by at least partially removing the transparent conductive film.
14. The windshield of claim 1, wherein a blackness value of the dark ceramic-ink layer is about 1, a blackness value of the ultraviolet-drying ink layer is about 1, a thickness of the dark ceramic-ink layer ranges from 18 .Math.m to 25 .Math.m, and a thickness of the ultraviolet-drying ink layer ranges from 18 .Math.m to 25 .Math.m.
15. The windshield of claim 1, wherein a visible light transmittance of the light transmitting region is greater than or equal to 70%, and a haze of the light transmitting region is less than or equal to 5%.
16. The windshield of claim 1, wherein a visible light transmittance of the dark ceramic-ink layer is less than or equal to 1.5%, a visible light transmittance of the ultraviolet-drying ink layer is less than or equal to 1.5%, an ultraviolet transmittance of the dark ceramic-ink layer is less than or equal to 0.05%, and an ultraviolet transmittance of the ultraviolet-drying ink layer is less than or equal to 0.05%.
17. A method for manufacturing a windshield for a vehicle, wherein the windshield comprises an outer glass panel, an inner glass panel, and an intermediate adhesive layer, wherein the outer glass panel has a first surface toward an outside of the vehicle and a second surface toward an inside of the vehicle, the inner glass panel has a third surface toward the outside of the vehicle and a fourth surface toward the inside of the vehicle, the second surface is bonded with the third surface via the intermediate adhesive layer, and at least one of the outer glass panel or the inner glass panel is a bent glass panel that is formed by subjecting a flat glass panel to high-temperature heat treatment of at least 560° C. and bending process, wherein the windshield further comprises an opaque masking layer, wherein the opaque masking layer comprises a dark ceramic-ink layer and an ultraviolet-drying ink layer, wherein the dark ceramic-ink layer is disposed on at least one of the second surface or the fourth surface, the ultraviolet-drying ink layer is disposed on at least one of the second surface, the third surface, or the fourth surface, the dark ceramic-ink layer has a first no-ink region, and wherein the ultraviolet-drying ink layer is located in the first no-ink region, and the ultraviolet-drying ink layer has a light transmitting region, wherein the light transmitting region has a diopter less than or equal to 200 milli-diopter (mdpt); and the method comprises: at block 1, preparing a first flat glass panel, and printing the dark ceramic-ink layer on the first flat glass panel, wherein a thickness of the dark ceramic-ink layer is larger than 15 .Math.m, and the dark ceramic-ink layer has a first no-ink region; at block 2, obtaining a first bent glass panel with the dark ceramic-ink layer by subjecting the first flat glass panel printed with the dark ceramic-ink layer to high-temperature heat treatment of at least 560° C. and bending process; at block 3, preparing a second flat glass panel that has been chemically tempered or a second bent glass panel that has been processed through high-temperature heat treatment of at least 560° C. and bending process; at block 4, printing the ultraviolet-drying ink layer in one of the first no-ink region of the first bent glass panel, a region on the second flat glass panel corresponding to the first no-ink region, or a region on the second bent glass panel corresponding to the first no-ink region, wherein a thickness of the ultraviolet-drying ink layer is larger than 15 .Math.m, a difference between the thickness of the dark ceramic-ink layer and the thickness of the ultraviolet-drying ink layer is less than or equal to 1 .Math.m, a light transmitting region is disposed in the ultraviolet-drying ink layer, wherein the ultraviolet-drying ink layer is formed through ultraviolet curing at a temperature lower than or equal to 200° C.; and at block 5, obtaining the windshield by combining the first bent glass panel and the second flat glass panel through at least one intermediate adhesive layer or by combining the first bent glass panel and the second bent glass panel through at least one intermediate adhesive layer.
18. The method of claim 17, further comprising the following at block 1: pre-sintering, at a temperature greater than or equal to 500° C., the dark ceramic-ink layer on the first flat glass panel to pre-cure the dark ceramic-ink layer.
19. The method of claim 17, wherein at block 3, the dark ceramic-ink layer is disposed on at least one of surfaces of the second bent glass panel.
20. The method of claim 17, wherein at block 3, a thickness of the second flat glass panel is smaller than or equal to 1.1 mm, and a thickness difference between the first bent glass panel and the second flat glass panel is greater than or equal to 0.7 mm.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0046] The disclosure is further elaborated hereinafter in conjunction with the accompanying drawings.
[0047] As illustrated in
[0048] In the disclosure, the image acquisition device 102 is mainly a device that acquires images using optical principles such as visible-light imaging and/or infrared imaging. For example, the image acquisition device 102 may be a camera or a camcorder, etc., and can be mounted at a vehicle to achieve functions, such as lane departure warning (LDW), forward collision warning (FCW), traffic sign recognition (TSR), lane keeping assist (LKA), pedestrian collision warning (PCW), and night vision system (NVS).
[0049] Generally, considering vehicle appearance and arrangements of parts, for example, sensors such as a light sensor, a rain sensor, and a humidity sensor being integrated at an upper central position of the windshield 100, the image acquisition device 102 can be directly fixed at the upper central position, or can be fixed at a roof of the vehicle to face upper central position through a support. In order to achieve a good appearance both outside and inside the vehicle, a cover plate can be used to shield the above parts from being seen at an inside of the vehicle, and an opaque masking layer can be used to shield the above parts from being seen an outside of the vehicle. As illustrated in
[0050] As illustrated in
[0051] As illustrated in
[0052] The dark ceramic-ink layer 1031 can be formed on a surface of a flat glass panel through planographic printing, etc., and then is subjected to high-temperature heat treatment of at least 560° C. and bending process together with the flat glass panel, so that the dark ceramic-ink layer 1031 is sintered and formed on a surface of a bent glass panel. The dark ceramic-ink layer 1031 usually includes an organic solvent and an inorganic power, and a mass percent of the inorganic powder in the dark ceramic-ink layer ranges from 70% to 85%. The inorganic powder mainly includes a glass glaze, a pigment, and an additive. The glass glaze has an average particle-size ranging from 5 .Math.m to 10 .Math.m and main components of bismuth borosilicate, zinc borosilicate, etc., and is used to determine a sintering temperature range, chemical resistance, and the like of the dark ceramic-ink layer 1031. Main components of the pigment include iron oxide, copper oxide, cobalt oxide, nickel oxide, and manganese oxide, etc., and the pigment plays a role in shielding and providing color (preferably, black color).
[0053] The ultraviolet-drying ink layer 1032 can be formed, by processes such as curved-surface printing, on a surface of the bent glass panel that is formed through high-temperature heat treatment of at least 560° C. and bending process, and then is cured on the surface of the bent glass panel via ultraviolet at a temperature lower than or equal to 200° C. The ultraviolet-drying ink (also known as ultraviolet ink) layer 1032 mainly includes an ultraviolet-curable resin, a diluted acrylate monomer, a pigment, a photoinitiator, and an additive, etc. The ultraviolet-curable resin is the main component of the ultraviolet-drying ink layer 1032, is used to determine hardness, rub resistance, adhesion, light resistance, chemical resistance and water resistance of the ultraviolet-drying ink layer 1032, and is generally a polymeric prepolymer, such as acrylic resin. The diluted acrylate monomer serves as an active diluent to adjust viscosity, curing rate and post-curing performance of the ultraviolet-drying ink layer 1032. Main components of the pigment includes iron oxide, copper oxide, cobalt oxide, nickel oxide, manganese oxide, etc., and the pigment plays a role in shielding and providing color (preferably, black color). The photoinitiator is used to absorb radiation energy in the range of 350 nm to 400 nm and produce an active intermediate with a polymerization ability of an initiator, which is helpful to wet the ultraviolet-drying ink layer 1032 and improve the levelling property.
[0054] As illustrated in
[0055] As illustrated in
[0056] The second boundary 1035 overlaps the first boundary 1034, and the ultraviolet-drying ink layer 1032 covers the first no-ink region 1033. As illustrated in
[0057] In order to ensure an overall appearance, there is no color difference that can be recognized by human eyes between the dark ceramic-ink layer 1031 and the ultraviolet-drying ink layer 1032. As illustrated in
[0058] As illustrated in
[0059] As illustrated in
[0060] The transparent conductive film 4 can be directly deposited onto the second surface 12, the third surface 21, or the fourth surface 22 by chemical vapor deposition (CVD) or physical vapor deposition (PVD), for example, though magnetron sputtering deposition. In addition, preferably, the transparent conductive film 4 can withstand high-temperature heat treatment, for example, a bending process such as hot bending, tempering, etc. Specifically, the transparent conductive film 4 may include a metal layer, a metal alloy layer, or a metal oxide layer. The metal layer may be made from gold (Au), silver (Ag), copper (Cu), aluminum (Al), or molybdenum (Mo). The metal alloy layer may be made from silver alloy. The metal oxide layer may be made from indium tin oxide (ITO), fluorine-doped tin dioxide (FTO), aluminum-doped zinc dioxide (AZO), antimony-doped tin oxide (ATO), etc. For example, when the transparent conductive film 4 includes the silver layer or the silver alloy layer, the silver layer or the silver alloy layer is located between at least two medium layers, and the at least two medium layers include at least one of zinc oxide, tin oxide, indium oxide, titanium oxide, silicon oxide, aluminum oxide, silicon nitride, silicon carbide, aluminum nitride, or a titanium metal layer.
[0061] The intermediate adhesive layer 3 in the disclosure is used to bond the outer glass panel 1 with the inner glass panel 2. For example, the intermediate adhesive layer 3 may be made from polycarbonate (PC), polyvinyl chloride (PVC), polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), polyacrylate (PA), polymethylmethacrylate (PMMA), or polyurethane (PUR), etc. The intermediate bonding layer 3 may also have other functions. For example, the intermediate bonding layer 3 may be provided with at least one colored region that serves as a shadow band to reduce interference of sunlight on human eyes. Alternatively, the intermediate bonding layer 3 may have an infrared absorbent to achieve sunscreen or heat insulation function. For another example, the intermediate bonding layer 3 may also include at least two layers, one of which has a plasticizer of a higher content to make the intermediate bonding layer 3 have a sound insulation function, or one of which is in a shape of wedge to make the intermediate bonding layer 3 have a head-up display (HUD) function, etc.
[0062] A method for manufacturing the windshield is further provided, and begins with operations at block 1.
[0063] At block 1, a first flat glass panel is prepared, and the dark ceramic-ink layer 1031 is printed on the first flat glass panel, where the dark ceramic-ink layer 1031 has a first no-ink region 1033, and the first no-ink region 1033 has a first boundary 1034.
[0064] Preferably, the dark ceramic-ink layer 1031 on the first flat glass panel is pre-sintered at a temperature of at least 500° C. to pre-cure the dark ceramic-ink layer 1031, avoiding the dark ceramic ink bonding with other glass panels or production equipment, and thus ensuring the printing quality of the dark ceramic-ink layer 1031.
[0065] At block 2, a first bent glass panel with the dark ceramic-ink layer 1031 is obtained by subjecting the first flat glass panel printed with the dark ceramic-ink layer 1031 to high-temperature heat treatment of at least 560° C. and bending process.
[0066] The sintering process of the dark ceramic-ink layer 1031 is combined with the high-temperature heat treatment and bending forming process of the first bent glass panel, so that the first bent glass panel having the dark ceramic-ink layer 1031 can be obtained in one-step forming according to a production process of vehicle glasses, thereby omitting some process steps.
[0067] At block 3, a second flat glass panel that has been chemically tempered or a second bent glass panel that has been processed through high-temperature heat treatment of at least 560° C. and bending process.
[0068] Optionally, the dark ceramic-ink layer 1031 is also disposed on at least one surface of the second bent glass panel to improve the overall shielding or enhance the adhesive performance between the accessories and the glass panel.
[0069] A thickness of the second flat glass panel is smaller than a thickness of the first bent glass panel. Preferably, the thickness of the second flat glass panel is smaller than or equal to 1.1 mm, and the thickness of the first bent glass panel is larger than the thickness of the second flat glass panel by at least 0.7 mm.
[0070] As for the chemical tempering, ions with different ionic radii are exchanged on a surface of a thin glass or an ultra-thin glass, such that a relatively high surface stress is generated on the surface of the thin glass or the ultra-thin glass, accompanied by a certain depth of stress layer, thereby improving a strength of the thin glass or the ultra-thin glass in terms of mechanical properties. Preferably, the second flat glass panel is an alkaline aluminosilicate glass.
[0071] At block 4, the ultraviolet-drying ink layer 1032 is printed in one of the first no-ink region 1033 of the first bent glass panel, a region on the second flat glass panel corresponding to the first no-ink region 1033, or a region on the second bent glass panel corresponding to the first no-ink region 1033, where a light transmitting region 104 is disposed in the ultraviolet-drying ink layer 1032, and the ultraviolet-drying ink layer 1032 is formed through ultraviolet curing at a temperature lower than or equal to 200° C.
[0072] The ultraviolet-drying ink layer 1032 has a second boundary 1035, the light transmitting region 104 has a third boundary 1036. The second boundary 1035 is larger than or equal to the first boundary 1034, and a distance between the second boundary 1035 and the third boundary 1036 is larger than or equal to 5 mm. The dark ceramic-ink layer 1031 and the ultraviolet-drying ink layer 1032 are located on the same surface. According to implementations of the disclosure, the dark ceramic-ink layer 1031 and the ultraviolet-drying drying ink layer 1032 can also be located on different surfaces.
[0073] In order to ensure the quality of the image acquired by the image acquisition device 102, a visible light transmittance of the light transmitting region 104 is greater than or equal to 70%, and a haze of the light transmitting region 104 is less than or equal to 5%, more preferably less than or equal to 1.5%, or even less than or equal to 1%. Correspondingly, a visible light transmittance of the dark ceramic-ink layer 1031 is less than or equal to 1.5%, and a visible light transmittance of the ultraviolet drying ink layer 1032 is less than or equal to 1.5%. An ultraviolet transmittance of the dark ceramic-ink layer 1031 is less than or equal to 0.05%, and an ultraviolet transmittance of the ultraviolet-drying ink layer 1032 is less than or equal to 0.05%.
[0074] At block 5, the windshield 100 is obtained by combining the first bent glass panel and the second flat glass panel through at least one intermediate adhesive layer or by combining the first bent glass panel and the second bent glass panel through at least one intermediate adhesive layer 3.
[0075] In the disclosure, the first bent glass panel may serve as the outer glass panel 1 of the windshield 100, and the second flat glass panel or the second bent glass panel may serve as the inner glass panel 2 of the windshield 100. The second flat glass panel is preferably bonded with the first bent glass panel through cold forming to obtain the windshield 100.
[0076] The windshield for a vehicle and the method for manufacturing the windshield in the disclosure are elaborated above, but the disclosure is not limited to the implementations described above. Any improvements, equivalent modifications, and replacements made according to technical points of the disclosure fall into the protection scope of the disclosure.