Cylindrical single-piece lithium-ion battery of 400Ah and its preparation method

Abstract

A cylindrical single-piece lithium-ion battery of 400 Ah includes: a cylindrical battery enclosure (1), a battery mandrel (3), a plurality of tabs (4), a wiring terminal (6), a positive and negative electrode cover (11); a positive electrode sheet, said battery positive electrode is composed of LiFePO.sub.4, conductive carbon-black, graphite, adhesive such as PVDF, and solvent such as NMP; a negative electrode sheet, the battery negative electrode is composed of lithium titanate, conductive carbon-black, graphite, adhesive such as PVDF, and solvent such as NMP. The cylindrical lithium-ion battery made by the invention has a capacity of 400 Ah which is the one reportedly having the largest capacity in the world presently.

Claims

1. A method of making a cylindrical single-piece lithium-ion battery, comprising steps as follows: (1) mixing evenly LiFePO.sub.4, conductive carbon black, graphite, polyvinylidene fluoride as adhesive, and N-methylpyrrolidone as solvent in a weight percentage ratio of 42.0-43.0:1.3-1.7:0.8-1.2:2.5-3.5:51.0-53.0 to form a first slurry and mixing evenly lithium titanate, conductive carbon black, graphite, polyvinylidene fluoride as adhesive and N-methylpyrrolidone as solvent in a weight percentage of 49.0-50.0:0.8-1.2:0.8-1.2:3.0-4.0:44.0-46.0 to form a second slurry; (2) coating and rolling the first slurry and the second slurry to form a positive electrode sheet and a negative electrode sheet, respectively, wherein each of the positive and negative electrode sheets is of a length of 33.81m, has an aluminum foil as current-collector and exposes a foil edge, and the aluminum foil has a thickness between 28 m and 32 m and a width between 319 mm and 321 mm; (3) baking the positive electrode sheet and the negative electrode sheet for 48 hours at 100 C.; (4) aligning and stacking up the positive electrode sheet and the negative electrode sheet with a separating membrane in-between, which are then mounted to an automatic winding machine to form a cylindrical shape; (5) welding a plurality of aluminium tabs onto the foil edge of the positive electrode sheet and a plurality of aluminium tabs onto the foil edge of the negative electrode sheet, wherein each of the aluminium tabs has a length between 69 mm and 71 mm, a width between 9.9 mm and 10.1 mm and thickness between 0.135 mm and 0.165 mm; (6) securing each of the aluminium tabs in a space defined by wiring terminal 6 and sliding ring 7 using tab clamping nut 8 to form a cell pack; (7) inserting the cell pack into an enclosure with two ends each being wrapped by a supporting bracket; (8) connecting sequentially wiring terminal 6, O-ring 10, insulation cushion 9 and cover 11 together, which are then fixed with clamping nut 12 and locating screw 13; and (9) sealing cover 11 to the enclosure using a laser welder.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a cross-sectional view showing assembling of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made according to a first embodiment. In this figure, 1 is cylindrical battery enclosure 1, 2 is battery winding core, 3 is battery mandrel, 4 is tab, 5 is supporting bracket, 6 is wiring terminal, 7 is sliding ring, 8 is clamping nut, 9 is insulation cushion, 10 is O-shaped ring, 11 is positive and negative cover, 12 is wiring terminal clamping nut, and 13 is locating pin.

(2) FIG. 2 is a photo of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment.

(3) FIG. 3 shows design sizes in mm of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment.

(4) FIG. 4 is a charging-discharging curve of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment, wherein the x-axis denotes capacity in unit of Ah, while the Y-axis denotes voltage in unit of volt.

(5) FIG. 5 shows a photo of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment before application of a nail test.

(6) FIG. 6 shows a photo of a cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment after application of a nail test.

(7) FIG. 7 shows a photo illustrating burning and explosion of 20 Ah LiCoO.sub.2/C lithium-ion battery after application of nail test.

DETAILED DESCRIPTION OF PARTICULAR EMBODIMENTS OF THE INVENTION

(8) Reference is now made to the accompanying drawings in which is shown an illustrative embodiment of the present invention from which its features and advantages will be apparent.

Embodiment 1

(9) Pre-baked crude materials including LiFePO.sub.4, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 42.0-43.0:1.3-1.7:0.8-1.2:2.5-3.5:51.0-53.0 and in total weight of 7.279 kg are evenly mixed together to form battery positive electrode slurry;

(10) Pre-baked crude materials including lithium titanate, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 49.0-50.0:0.8-1.2:0.8-1.2:3.0-4.0:44.0-46.0 and in total weight of 6.656 kg are evenly mixed together to form battery negative electrode slurry.

(11) During coating and rolling process, both of the positive and negative electrodes use aluminum foil as the current-collector. The aluminum foil has a thickness of 302 m, and width of 3201 mm; the length of both positive and negative electrode sheets is 33.81 m.

(12) The electrode sheets obtained from above steps are heated for 48 h at a temperature of 100 C.; Then the positive and negative electrode sheets are placed to be aligned with and parallel with a membrane and are loaded into a full automatic winding machine; next, one hundred of aluminum tabs are welded onto an aluminum foil edge of each positive and negative electrode sheets, and high-temperature resistant adhesive paper is employed to secure firmly a root portion of the tabs. Each aluminum tab of positive and negative electrode sheets has a length of 701 mm, width of 100.1 mm and thickness of 0.150.015 mm.

(13) The plurality of evenly divided positive and negative tabs 4 pass through a space defined between the wiring terminal 6 and sliding ring 7, and then are locked by the tab clamping nut 8 (this connection manner is called wiring collar); a cell pack is carefully inserted into the enclosure 1; each of two ends of the enclosure 1 is wrapped by a supporting bracket 5; after finishing of the bracket 5, the wiring terminal 6, O-shaped ring 10, insulation cushion 9 and cover 11 are assembled together in sequence and are clamped together by the clamping nut 12 and locating screw 13 (See for FIG. 1); three safety valve sheets are provided on each of positive and negative electrode covers. Each valve sheet has a diameter of 13 mm, thickness of 0.5 mm, and burst pressure of 7.5-8 kg; during winding, assembling and welding procedure, a multimeter is used to detect short circuit. When doing so, vacuum injecting means is used to perform electrolyte injection. Said electrolyte may be LiPF.sub.6 (EC+PC+DMC+DEC). Finally, a laser welder runs to weld covers to two ends of the battery in a sealing manner.

(14) Various parameters are listed below:

(15) Battery enclosure: made of stainless steel, diameter: 134 mm, length: 450 mm, weight: 12 Kg; rated capacity: 400 Ah; rated working voltage: 1.8V; internal resistance: 0.33 m; cycle lifetime: more than 8000 times.

(16) Photos of the cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment are shown in FIG. 2, and its contour sizes are indicated in FIG. 3.

(17) The cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. During charging period, current is at first kept constant and then voltage is kept constant. The charging restriction voltage is 2.3V. During discharging period, current is constant, and discharging cutoff voltage is 0.5V. Current with magnitude of 0.33 C is used to perform the above test.

(18) The cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment has a weight of 12 kg, discharging capacity of 417.718 Ah, charging-discharging efficiency of 99.6%, internal resistance of 0.33 m, and cycle lifetime of at least 8000 times (in theory, it can be 20000 times).

(19) It is clear from FIG. 4 that the battery has stable charging-discharging voltage, long holding time of potential (capacity may be 95% of the discharging capacity), these being brought by reaction between Spinel-type Li.sub.4Ti.sub.5O.sub.12 and Rock Salt-type Li.sub.7Ti.sub.5O.sub.12. Reaction of the two substance makes the electrode potential stable. When above reaction is finished substantially, the potential will rapidly rise or drop. When charging and discharging ends, the resulting significant voltage steep change may be used to indicate termination of charging and discharging, thereby facilitating detection of the battery capacity.

(20) The cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment has an internal resistance of only 0.33 m meaning very good conductivity. The battery electrode sheet of large capacity also has great cross-section area and therefore, the internal resistance of the battery is very small (the resistance is in reverse proportion to the cross-section area). Compared with the battery prepared using laminated sheets, during winding process of the battery electrode sheet, the positive and negative electrode sheets of the battery prepared by using this technique will be pressed tightly against the membrane under the tension. Accordingly, the winding core is robust and has large cross section area. Therefore, the battery has very small internal resistance.

(21) In test range of the first embodiment, the capacity of the cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery is not seen attenuated. It is predicted based on feature of Li.sub.4Ti.sub.5O.sub.12 and previous data of battery with small capacity that the cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah will have a cycle lifetime of at least 8000 times (in theory, it can be 20000 times). This cycle lifetime is about 2-4 times longer than those lithium-ion batteries in the marketplace.

(22) The internal resistance, cycle lifetime and other major technical parameters of the cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment have met expected design requirements.

(23) The cylindrical single-piece LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 400 Ah made in the first embodiment is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. Neither burning nor burst has occurred when applying the nail test. In addition, 6 safety valves mounted on both covers located at two ends of the battery are not opened at all (See FIG. 5). The surface temperature of the battery is only 34 C. Comparatively, nail test applied to a conventional LiFePO.sub.4/C battery seen in the marketplace demonstrates that the surface temperature of the battery is 200 C. Apparently, the safety of the battery is significantly improved.

Comparative Example 1

(24) Pre-baked crude materials including LiFePO.sub.4, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 38.0-39.0:0.8-1.2:0.3-0.7:2.5-3.5:56.0-58.0 and in total weight of 2.672 kg are evenly mixed together to form battery positive electrode slurry.

(25) Pre-baked crude materials including artificial graphite, conductive carbon black, adhesive PVDF, and solvent NMP in weight % of 36.0-37.0:0.8-1.2:3.0-4.0:58.0-60.0 and in total weight of 1.192 kg are evenly mixed together to form battery negative electrode slurry.

(26) During coating and rolling process, the positive electrode uses aluminum foil as the current-collector, while the negative electrode uses copper foil as its current-collector. The aluminum foil has a thickness of 302 m, and width of 3201 mm; and the copper foil has a thickness of 222 m, and width of 3201 mm. The length of both positive and negative electrode sheets is 11.00 m.

(27) The electrode sheets obtained from above steps are heated for 48 h at a temperature of 100 C.; Then the positive and negative electrode sheets are placed to be aligned with and parallel with a membrane and are loaded into a full automatic winding machine; next, 73 aluminum tabs are welded onto a foil edge of the positive electrode sheet, and 73 copper tabs are welded onto a foil edge of the negative electrode sheet. The aluminum tab of positive electrode sheet has a length of 701 mm, width of 100.1 mm and thickness of 0.10.01 mm. The copper tab of negative electrode sheet has a length of 701 mm, width of 100.05 mm and thickness of 0.050.01 mm.

(28) The positive and negative tabs are secured onto the corresponding wiring terminals using tab bolts and tab plates. The tabs should be clamped tightly. A cell pack is carefully inserted into a battery casing; each of two ends of the casing is wrapped by a supporting bracket; after finishing of the bracket, the positive and negative wiring terminals, internal insulation rings, O-shaped ring, cover, external insulation ring, and wiring terminal anti-loosening cushion are assembled together in sequence and are clamped together by the clamping nut; a safety valve sheet is provided on each of positive and negative electrode covers. Each valve sheet has a diameter of 13 mm, thickness of 0.5 mm, and burst pressure of 7.5-8 kg; during winding, assembling and welding procedure, a multimeter is used to detect short circuit. When doing so, vacuum injecting means is used to perform electrolyte injection. Said electrolyte may be LiPF.sub.6 (EC+PC+DMC+DEC). Finally, a laser welder runs to weld covers to two ends of the battery in a sealing manner.

(29) The cylindrical LiFePO.sub.4/C (artificial graphite) lithium-ion battery of 100 Ah made in the comparative example 1 is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. During charging period, current is at first kept constant and then voltage is kept constant. The charging restriction voltage is 2.0V. During discharging period, current is constant, and discharging cutoff voltage is 2.0V. Current with magnitude of 0.33 C is used to perform the above test.

(30) The cylindrical LiFePO.sub.4/C (artificial graphite) lithium-ion battery of 100 Ah made in the comparative example 1 has a weight of 3.7 kg, discharging capacity of 102.245 Ah, charging-discharging efficiency of 93.9%, internal resistance of 0.60 m, and cycle lifetime of about 3000 times.

(31) The nail test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006 to the cylindrical LiFePO.sub.4/C (artificial graphite) lithium-ion battery of 100 Ah made in the comparative example 1. Neither burning nor burst has occurred. In addition, one of two safety valves mounted on both covers located at two ends of the battery is opened. The surface temperature of the battery is 200 C.

Comparative Example 2

(32) Pre-baked crude materials including LiFePO.sub.4, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 38.0-39.0:0.8-1.2:0.3-0.7:2.5-3.5:56.0-58.0 and in total weight of 2.672 kg are evenly mixed together to form battery positive electrode slurry.

(33) Pre-baked crude materials including carbon fiber ball, conductive carbon black, adhesive PVDF, and solvent NMP in weight % of 36.0-37.0:0.8-1.2:3.0-4.0:58.0-60.0 and in total weight of 1.192 kg are evenly mixed together to form battery negative electrode slurry.

(34) During coating and rolling process, the positive electrode uses aluminum foil as the current-collector, while the negative electrode uses copper foil as its current-collector. The aluminum foil has a thickness of 302 m, and width of 3201 mm; and the copper foil has a thickness of 222 m, and width of 3201 mm. The length of both positive and negative electrode sheets is 11.00 m.

(35) The electrode sheets obtained from above steps are heated for 48 h at a temperature of 100 C.; Then the positive and negative electrode sheets are placed to be aligned with and parallel with a membrane and are loaded into a full automatic winding machine; next, 73 aluminum tabs are welded onto a foil edge of the positive electrode sheet, and 73 copper tabs are welded onto a foil edge of the negative electrode sheet. In addition, high-temperature resistant adhesive paper is used to attach the tabs tightly. The aluminum tab of positive electrode sheet has a length of 701 mm, width of 100.1 mm and thickness of 0.10.01 mm. The copper tab of negative electrode sheet has a length of 701 mm, width of 100.05 mm and thickness of 0.050.01 mm.

(36) The positive and negative tabs are secured onto the corresponding wiring terminals using tab bolts and tab plates. The tabs should be clamped tightly. A cell pack is carefully inserted into a battery casing; each of two ends of the casing is wrapped by a supporting bracket; after finishing of the bracket, the positive and negative wiring terminals, internal insulation rings, O-shaped ring, cover, external insulation ring, and wiring terminal anti-loosening cushion are assembled together in sequence and are clamped together by the clamping nut; a safety valve sheet is provided on each of positive and negative electrode covers. Each valve sheet has a diameter of 13 mm, thickness of 0.5 mm, and burst pressure of 7.5-8 kg; during winding, assembling and welding procedure, a multimeter is used to detect short circuit. When doing so, vacuum injecting means is used to perform electrolyte injection. Said electrolyte may be LiPF.sub.6 (EC+PC+DMC+DEC). Finally, a laser welder runs to weld covers to two ends of the battery in a sealing manner.

(37) The cylindrical LiFePO.sub.4/C (carbon fiber ball) lithium-ion battery of 100 Ah made in the comparative example 2 is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. During charging period, current is at first kept constant and then voltage is kept constant. The charging restriction voltage is 3.8V. During discharging period, current is constant, and discharging cutoff voltage is 2.0V. Current with magnitude of 0.33 C is used to perform the above test.

(38) The cylindrical LiFePO.sub.4/C (carbon fiber ball) lithium-ion battery of 100 Ah made in the comparative example 2 has a weight of 3.7 kg, discharging capacity of 104.662 Ah, charging-discharging efficiency of 95.2%, internal resistance of 0.50 m, and cycle lifetime of about 3000 times.

(39) The nail test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006 to the cylindrical LiFePO.sub.4/C (carbon fiber ball) lithium-ion battery of 100 Ah made in the comparative example 2. Neither burning nor burst has occurred. In addition, neither of two safety valves mounted on both covers located at two ends of the battery is opened. The surface temperature of the battery is 180 C.

Comparative Example 3

(40) Pre-baked crude materials including LiCoO.sub.2, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 39.0-40.0:0.3-0.7:0.8-1.2:1.5-2.5:56.0-58.0 and in total weight of 0.467 kg are evenly mixed together to form battery positive electrode slurry.

(41) Pre-baked crude materials including graphite, conductive carbon black, adhesive PVDF, and solvent NMP in weight % of 37.0-38.0:0.8-1.2:2.0-3.0:58.0-60.0 and in total weight of 0.261 kg are evenly mixed together to form battery negative electrode slurry.

(42) During coating and rolling process, the positive electrode uses aluminum foil as the current-collector, while the negative electrode uses copper foil as its current-collector. The aluminum foil has a thickness of 202 m, and width of 1831 mm; and the copper foil has a thickness of 122 m, and width of 1831 mm. The length of both positive and negative electrode sheets is 2.13 m.

(43) The electrode sheets obtained from above steps are heated for 48 h at a temperature of 100 C.; Then the positive and negative electrode sheets are placed to be aligned with and parallel with a membrane and are loaded into a full automatic winding machine; next, 6 aluminum tabs are welded onto a foil edge of the positive electrode sheet, and 6 Ni tabs are welded onto a foil edge of the negative electrode sheet. In addition, high-temperature resistant adhesive paper is used to attach the tabs tightly. The aluminum tab of positive electrode sheet has a length of 701 mm, width of 100.1 mm and thickness of 0.10.01 mm. The Ni tab of negative electrode sheet has a length of 701 mm, width of 100.05 mm and thickness of 0.10.01 mm.

(44) The positive tab passes through a hole defined in the insulation sheet and then is wrapped with the supporting bracket. Finally, it is welded directly on the inner side of the positive electrode cover (tablet cover). Next, a cell pack is carefully inserted into a battery enclosure. After that, the negative tab passes through a hole defined in the insulation sheet and then is welded to the positive tab and finally is wrapped with the supporting bracket. The O-shaped ring, negative cover, and negative wiring terminal are assembled together tightly in sequence; a safety valve sheet is provided on the negative electrode cover. The valve sheet has a diameter of 13 mm, thickness of 0.5 mm, and burst pressure of 7.5-8 kg; during winding, assembling and welding procedure, a multimeter is used to detect short circuit. When doing so, vacuum injecting means is used to perform electrolyte injection. Said electrolyte may be LiPF.sub.6 (EC+PC+DMC+DEC). Finally, a laser welder runs to weld covers to two ends of the battery in a sealing manner.

(45) The cylindrical LiCoO.sub.2/C lithium-ion battery of 20 Ah made in the comparative example 3 is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. During charging period, current is at first kept constant and then voltage is kept constant. The charging restriction voltage is 4.2V. During discharging period, current is constant, and discharging cutoff voltage is 3.0V. Current with magnitude of 0.33 C is used to perform the above test.

(46) The cylindrical LiCoO.sub.2/C lithium-ion battery of 20 Ah made in the comparative example 3 has a weight of 0.58 kg, discharging capacity of 20.392 Ah, charging-discharging efficiency of 87.1%, internal resistance of 4.77 m, and cycle lifetime of about 2500 times.

(47) The nail test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006 to the cylindrical LiCoO.sub.2/C lithium-ion battery of 20 Ah made in the comparative example 3. The cover of the negative electrode and the safety valve sheet thereon are both opened. Burning and burst occur to the battery, as shown in FIG. 7.

Comparative Example 4

(48) Pre-baked crude materials including LiFePO.sub.4, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 42.0-43.0:1.3-1.7:0.8-1.2:2.5-3.5:51.0-53.0 and in total weight of 3.795 are evenly mixed together to form battery positive electrode slurry.

(49) Pre-baked crude materials including lithium titanate, conductive carbon black, graphite, adhesive PVDF, and solvent NMP in weight % of 49.0-50.0:0.8-1.2:0.8-1.2:3.0-4.0:44.0-46.0 and in total weight of 3.472 kg are evenly mixed together to form battery negative electrode slurry.

(50) During coating and rolling process, both of the positive and negative electrodes use aluminum foil as the current-collector. The aluminum foil has a thickness of 302 m, and width of 3201 mm; the length of both positive and negative electrode sheets is 17.63 m.

(51) The electrode sheets obtained from above steps are heated for 48 h at a temperature of 100 C.; Then the positive and negative electrode sheets are placed to be aligned with and parallel with a membrane and are loaded into a full automatic winding machine; next, 60 aluminum tabs are welded onto an aluminum foil edge of each positive and negative electrode sheets, and high-temperature resistant adhesive paper is employed to secure firmly a root portion of the tabs. Each aluminum tab of positive and negative electrode sheets has a length of 701 mm, width of 100.1 mm and thickness of 0.150.015 mm.

(52) The plurality of evenly-divided positive and negative tabs pass through a space defined between the wiring terminal and sliding ring, and then are locked by the tab clamping nut (this connection manner is called wiring collar); a cell pack is carefully inserted into the enclosure; each of two ends of the enclosure is wrapped by a supporting bracket; after finishing of the bracket, the positive and negative wiring terminals, O-shaped ring, insulation cushion and cover are assembled together in sequence and are clamped together by the clamping nut and locating screw; two safety valve sheets are provided on each of positive and negative electrode sheets. Each valve sheet has a diameter of 13 mm, thickness of 0.5 mm, and burst pressure of 7.5-8 kg; during winding, assembling and welding procedure, a multimeter is used to detect short circuit. When doing so, vacuum injecting means is used to perform electrolyte injection. Said electrolyte may be LiPF.sub.6 (EC+PC+DMC+DEC). Finally, a laser welder runs to weld covers to two ends of the battery in a sealing manner.

(53) The cylindrical LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 200 Ah made in the example 4 is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. During charging period, current is at first kept constant and then voltage is kept constant. The charging restriction voltage is 2.3V. During discharging period, current is constant, and discharging cutoff voltage is 0.5V. Current with magnitude of 0.33 C is used to perform the above test.

(54) The cylindrical LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 200 Ah made in the example 4 has a weight of 7 kg, discharging capacity of 204.754 Ah, charging-discharging efficiency of 98.9%, internal resistance of 0.47 m, and cycle lifetime of at least 8000 times (in theory, it can be 20000 times).

(55) The cylindrical LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery of 200 Ah made in the example 4 is tested by charging-discharging with constant current using battery test equipment such as model BTS-5V200A produced by Shenzhen New Wale electronic products INC. The above test is conducted according to Electric automobile lithium-ion battery set forth in Chinese automobile industry standard QC/T743-2006. Neither burning nor burst has occurred during the nail test. In addition, 4 safety valves mounted on both covers located at two ends of the battery are not opened at all. The surface temperature of the battery is 34 C.

(56) In a summary, the cylindrical LiFePO.sub.4/Li.sub.4Ti.sub.5O.sub.12 lithium-ion battery made by the first embodiment of the invention has large capacity, small internal resistance, long cycle lifetime, good safety reliability, strong environment adaption, good uniformity and accordingly, it can be applied widely to electric automobile, hybrid power automobile, military equipment, aerospace, hydraulic power, thermal power, wind power, polar power station system and uninterrupted power supply for post telecommunications, thus meeting increasing marketplace requirements, and having wide prospect.

(57) It is the definite choice for developing and utilizing green energy. The cylindrical lithium-ion battery with high capacity, large power and good safety will find its great application and prospect throughout the world.