A negative electrode material includes a silicon-based material, where a particle of the silicon-based material includes at least one recessed portion, and the recessed portion is 50 nm to 20 μm in width, and 50 nm to 10 μm in depth. The recessed structure leaves room for the silicon-based material to swell, thereby solving the problem of large volume swelling of the silicon-based material. In addition, when the silicon-based material with the recessed structure is composited with a carbon material, a conductive agent, and the like to form a negative electrode plate, small particles of the carbon material and the conductive agent are embedded into the recessed portion of the silicon-based material, solving the problem of low compacted density of the silicon-based negative electrode material with a recessed structure, and compensating for the low volumetric energy density of the recessed structure.

Component A: a carboxymethyl cellulose having a degree of carboxymethyl substitution per anhydroglucose unit of 0.45 or more or a salt thereof and Component B: a saturated carboxylic acid having 6 or less carbon atoms or a salt thereof are contained.

A negative electrode active material having a specific aspect ratio and sphericity in a cumulative particle volume distribution. When tested by using a dynamic particle image analyzer, when a cumulative particle volume distribution of the negative electrode active material is 10%, an aspect ratio AR.sub.10 of the negative electrode active material satisfies 0.4≤AR.sub.10≤0.55, and a sphericity S.sub.10 of the negative electrode active material satisfies 0.48≤S.sub.10≤0.60. The negative electrode active material improves rate performance, dynamics performance, and a deformation problem of the electrochemical apparatus.

The fabrication of single-crystalline ionically conductive materials and related articles and systems are generally described.

A negative electrode active material includes a carbon material, where the carbon material has a specific degree of graphitization and aspect ratio distribution. A degree of graphitization Gr of the carbon material measured by an X-ray diffraction analysis method is 0.82 to 0.92, and based on a total quantity of particles of the carbon material, a proportion of particles with an aspect ratio greater than 3.3 in the carbon material is less than 10%. The negative electrode active material helps to improve cycle performance of the electrochemical apparatus. FIG. 1.

An lead-acid battery is described. The battery includes a carbon fiber electrode having a paste containing a novel additive including one or more carbons, organic expanders, and barium sulfate.

There is provided a method of synthesizing a porous carbon-sulfur composite comprising the step of carbonizing a carbon material having a metal-organic framework (MOF) at a temperature of 800-1000° C. to produce a porous carbon, mixing and heating the porous carbon with sulfur to infuse the sulfur (melt diffusion) into the pores of the porous carbon and removing excess sulfur not infused into the pores or present on the surface of the porous carbon. There is also provided a cathode comprising the porous carbon-sulfur composite and a method of preparing the cathode by mixing with conductive carbon and a polymer binder. The cathode finds use in an electrochemical cell comprising a sodium or lithium anode.

The present invention is related to a manufacturing method of a negative active material for a lithium secondary battery, a negative active material for a lithium secondary battery manufactured by the method, and a lithium secondary battery including the same. According to one embodiment, it is provided that: a method of manufacturing a negative active material for lithium secondary battery, comprising: coating a negative active material precursor containing Si with crude tar or soft pitch; and annealing an obtained coating product, wherein, the crude tar contains a low molecular weight component that can be removed by a distillation process in an amount of 20 wt % or less.

Disclosed are a cathode materials suitable for an aluminium ion battery, wherein the cathode materials comprise a main group element nitride, and an oxide of a main group element or an oxide of a element in Group 1 to 13. The nitride is preferably a 2-dimensional layered material. Preferably, the ratio of the main group element nitride to the oxide is between 5:95 and 95:5 (by weight).

The disclosure relates to metal phosphorothioates, batteries comprising metal phosphorothioate, cells comprising metal phosphorothioate, and methods of making thereof.