Carbon Dioxide Capture Systems
20190209961 ยท 2019-07-11
Inventors
Cpc classification
B01D2253/204
PERFORMING OPERATIONS; TRANSPORTING
Y02P20/151
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B01D2259/4566
PERFORMING OPERATIONS; TRANSPORTING
B01J20/3483
PERFORMING OPERATIONS; TRANSPORTING
B01D53/0446
PERFORMING OPERATIONS; TRANSPORTING
C10L1/02
CHEMISTRY; METALLURGY
C12P1/00
CHEMISTRY; METALLURGY
Y02P20/59
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02C20/40
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02E50/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
C12P1/00
CHEMISTRY; METALLURGY
C02F3/32
CHEMISTRY; METALLURGY
Abstract
Carbon dioxide capture systems in accordance with various embodiments of the present disclosure are provided. In one embodiment, an apparatus for capturing carbon emissions from a vehicle is provided, comprising: an exhaust feeder comprising a first end and a second end, wherein the first end connects to the vehicle and receives exhaust gases emitted from the vehicle; a housing connected to the second end and secured to an exterior surface of the vehicle, wherein the housing receives the exhaust gases emitted from the vehicle via the exhaust feeder; wherein the housing comprises: at least one gas deflector surface that directs the exhaust gases to a sorbent material configured to capture carbon dioxide from the exhaust gases; a detachable section that allows for removal and installation of the sorbent material; and an exit port that allows for release of residual gases after the sorbent material captures carbon dioxide.
Claims
1. An apparatus for capturing carbon emissions from a vehicle, comprising: an exhaust feeder comprising a first end and a second end, wherein the first end of the exhaust feeder connects to the vehicle and receives exhaust gases emitted from the vehicle; a housing connected to the second end of the exhaust feeder and secured to an exterior surface of the vehicle, wherein the housing receives the exhaust gases emitted from the vehicle via the exhaust feeder; wherein the housing comprises: at least one gas deflector surface that directs the exhaust gases to a sorbent material configured to capture carbon dioxide from the exhaust gases; a detachable section that allows for removal and installation of the sorbent material; and an exit port that allows for release of residual gases after the sorbent material captures carbon dioxide from the exhaust gases.
2. The apparatus of claim 1, wherein the first end of the exhaust feeder connects to the vehicle via a tailpipe of the vehicle.
3. The apparatus of claim 1, wherein the exhaust feeder is constructed using heat-resistant and corrosion-resistant materials.
4. The apparatus of claim 1, wherein the housing is constructed using heat-resistant and corrosion-resistant materials.
5. The apparatus of claim 1, wherein the housing is secured to a top, a bottom, or a rear of the vehicle.
6. The apparatus of claim 1, wherein the housing further comprises a plurality of mesh bags configured to hold the sorbent material while still allowing the exhaust gases directed from the gas deflector surfaces to pass through the sorbent material.
7. The apparatus of claim 1, wherein the apparatus further comprises a flange that secures the exhaust feeder to the housing using a locking mechanism.
8. The apparatus of claim 1, wherein the apparatus further comprises a flange that secures the exhaust feeder to the housing using a slotting mechanism.
9. The apparatus of claim 1, wherein the exhaust feeder is constructed using a flexible material.
10. The apparatus of claim 1, wherein the gas deflector surfaces are located in the housing and centered around the exhaust feeder.
11. A method for reducing carbon emissions from a vehicle, comprising: receiving exhaust gases emitted from a vehicle at a first end of an exhaust feeder; delivering exhaust gases from the first end of the exhaust feeder to a second end of the exhaust feeder; transporting the exhaust gases from the second end of the exhaust feeder into a housing secured to an exterior surface of a vehicle; directing the exhaust gases in the housing to a sorbent material using gas deflector surfaces; adsorbing carbon dioxide from the exhaust gases using the sorbent material; expelling residual gases using an exit port in the housing after the sorbent material captures carbon dioxide from the exhaust gases; removing a section of the housing to allow for extraction of the sorbent material; heating the sorbent material after extraction to regenerate the sorbent material; storing carbon dioxide expelled from the sorbent material during heating of the sorbent material in a storage tank; utilizing the carbon dioxide for algae development including usage in biofuels, biomass generation, wastewater treatment, and fertilizers; and reinstalling the sorbent material in the housing after regeneration of the sorbent material from heating.
12. The method of claim 11, wherein the first end of the exhaust feeder connects to the vehicle via a tailpipe of the vehicle.
13. The method of claim 11, wherein the exhaust feeder is constructed using heat-resistant and corrosion-resistant materials.
14. The method of claim 11, wherein the housing is constructed using heat-resistant and corrosion-resistant materials.
15. The method of claim 11, wherein the housing is secured to a top, a bottom, or a rear of the vehicle.
16. The method of claim 11, wherein the housing further comprises a plurality of mesh bags configured to hold the sorbent material while still allowing the exhaust gases directed from the gas deflector surfaces to pass through the sorbent material.
17. The method of claim 11, wherein a flange secures the exhaust feeder to the housing using a locking mechanism.
18. The method of claim 11, wherein a flange secures the exhaust feeder to the housing using a slotting mechanism.
19. The method of claim 11, wherein the exhaust feeder is constructed using a flexible material.
20. The method of claim 11, wherein the gas deflector surfaces are located in the housing and centered around the exhaust feeder.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0026] The various embodiments of the present invention now will be discussed in detail with an emphasis on highlighting the advantageous features. These embodiments depict the novel and non-obvious embodiments shown in the accompanying drawings, which are for illustrative purposes only. These drawings include the following figures:
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DETAILED DESCRIPTION OF THE DRAWINGS
[0038] The following detailed description describes the present embodiments with reference to the drawings. In the drawings, reference numbers label elements of the present embodiments. These reference numbers are reproduced below in connection with the discussion of the corresponding drawing features. These drawings, and their written descriptions, indicate that certain components of the apparatus are formed integrally, and certain other components are formed as separate pieces. Those of ordinary skill in the art will appreciate that components shown and described herein as being formed integrally may in alternative embodiments be formed as separate pieces. Those of ordinary skill in the art will further appreciate that components shown and described herein as being formed as separate pieces may in alternative embodiments be formed integrally. Further, as used herein the term integral describes a single unitary piece.
[0039] In many embodiments, carbon dioxide capture system may be secured to a vehicle and configured to receive exhaust gases from the vehicle as further described below. In various embodiments, the carbon dioxide capture system may include an exhaust feeder configured to connect to the vehicle (e.g., via a vehicle's tailpipe) and receive exhaust gases emitted by the vehicle during operation. In several embodiments, the carbon dioxide capture system may include a housing containing sorbent material (e.g., mesh bags of sorbent) for capturing carbon dioxide and/or any other pollutant from the exhaust gases. In many embodiments, after the carbon dioxide has been adsorbed from the exhaust gases, the carbon dioxide capture system may release residual gases via an exit port. When the sorbent material is saturated following the adsorption of carbon dioxide, it may be extracted and then regenerated for continual use. For example, sorbent material may be regenerated using elevated temperatures (e.g., microwaving at 100-130 degrees Celsius) and/or applying reduced pressure. In many embodiments, the regeneration process may also expel the carbon dioxide adsorbed in the sorbent material for use in environmentally friendly consumption. For example, the captured carbon dioxide may be expelled from the sorbent material and stored for carbon fixation (e.g., photosynthesis) to promote algae development. Algae may be used to generate biofuels, biomass, wastewater treatment substances, and fertilizers. In many embodiments, after regeneration, the sorbent material may be reinstalled into the carbon dioxide capture system. As described further below, various embodiments and/or configurations of the carbon dioxide capture systems may be used in accordance with specific conditions or applications of a vehicle. For example, the carbon dioxide capture system may be configured for various sorbent capacity, structural configuration, material usage, etc. The embodiments discussed in accordance with the carbon dioxide capture systems help to solve current issues of carbon capture from vehicles, such as limitations of space, increased costs of equipment, and vehicle fuel economy. Carbon dioxide capture systems using cargo boxes in accordance with embodiments of the invention, are discussed below.
Carbon Dioxide Capture Systems Using Cargo Boxes
[0040] Carbon dioxide capture systems may include so called cargo boxes (may also be referred to as housing). In some embodiments, a cargo box may be an off-the-shelf cargo box that may be customized for use with the carbon dioxide capture system. Although the term cargo box is used herein, the cargo box may not actually allow for storing cargo but instead may include various components for capturing gases (e.g., CO.sub.2), as further described below. Further, the carbon dioxide capture system may also include various components connected to the cargo box, as further described below.
[0041] A carbon dioxide capture system secured to a vehicle in accordance with an embodiment of the invention is illustrated in
[0042] In several embodiments, the cargo box 104 may be secured to the vehicle 100 in a manner known to one of skill in the art. For example, the cargo box 106 may be secured to a top, bottom, front, or rear of a vehicle, provided that placement of the cargo box 106 does not significantly impair control or driving of the vehicle. In some embodiments, the cargo box 104 may be secured within the vehicle 100. Considering the cargo box 106 will house exhaust gases that may be corrosive and/or of a high temperature, the cargo box 106 may also be constructed using heat-resistant and/or corrosion-resistant material, such as (but not limited to) metals, stainless steel, titanium, high-temperature plastics, and/or silicon carbide. Likewise, the exhaust feeder 104 may be constructed using heat-resistant and/or corrosion-resistant materials. Furthermore, the exhaust feeder 104 may be also constructed using a flexible material and may take the shape of a tube and/or pipe to adapt to the surfaces of different vehicles and placement of the cargo box 106 on the vehicle 100. For example, the exhaust feeder 104 may bend in accordance to the surface of a truck if the cargo box 106 is placed in a rear of the truck.
[0043] As further described below, the cargo box may include at least one gas deflector surface that directs the exhaust gases to a sorbent configured to capture carbon dioxide from the exhaust gases. In various embodiments, a sorbent may be porous materials capable of capturing carbon dioxide from gases or exhaust streams. The captured carbon dioxide is often removed afterwards by elevated temperatures and/or applying reduced pressure and then stored for use in biological carbon fixation, such as use of carbon dioxide to achieve algae growth, as further described below. Sorbents may include metal-organic frameworks (MOFs), zeolites, silica, calcium oxides, organic-inorganic hybrids, alkylamines/amines, hydrotalcites, and activated carbons. The many types of sorbents vary in performance. Examples of common MOFs include MOF-74, UTSA-16, MIL-101, and HKUST-1, while examples of zeolite structures include FAU, LTA, MFI, and CHA. Both MOFs and zeolites provide a high capture rate of carbon dioxide but drastically degrade in humid environments, a trait common to areas of school transportation. Hydrotalcites and metal-oxides are also known for a high capture rate but require high temperatures in excess of 300 degrees Celsius. Activated carbons provide a high capture rate in both dry and humid environments. Overall, effective sorbents may capture 20 percent of initial mass in carbon dioxide. A person of ordinary skill in the art will appreciate the differences in sorbent material and select suitable sorbent material in accordance with varying operating conditions of vehicles. For reference, Table 1 below is a list of some available sorbents.
TABLE-US-00001 TABLE 1 Name Type PEI-MIL-101 Amine-MOF mmen-Mg.sub.2(dobpdc) Amine-MOF dmen-Mg.sub.2(dobpdc) Amine-MOF dmpn-Mg.sub.2(dobpdc) Amine-MOF mmen-CuBTTri Amine-MOF NH.sub.2-MIL-53(Al) Amine-MOF en-CuBTTri Amine-MOF Mg-MOF-74 MOF Ni-MOF-74 MOF Co-MOF-74 MOF HKUST-1 MOF SIFSIX-3(Zn) MOF Zn(ox)(atz).sub.2 MOF Zn-MOF-74 MOF CuTATB-60 MOF bio-MOF-11 MOF FeBTT MOF MOF-253-Cu(BF4) MOF ZIF-78 MOF CuBTTri MOF SNU-50 MOF USO-2-Ni-A MOF MIL-53(Al) MOF MIL-47 MOF UMCM-150 MOF MOF-253 MOF ZIF-100 MOF MTV-MOF-EHI MOF ZIF-8 MOF IRMOF-3 MOF MOF-177 MOF UMCM-1 MOF MOF-5 MOF 13X Zeolite Ca-A Zeolite
[0044] Although specific carbon dioxide capture systems are discussed with respect to
Cargo Boxes
[0045] Carbon capture systems may include cargo boxes that include various components such as (but not limited to) an input port connected to an exhaust feeder, gas defector surface(s), a detachable section that allows for removal and installation of sorbent material(s), an exit port. A cargo box of a carbon dioxide capture system in accordance with an embodiment of the invention is illustrated in
[0046] In many embodiments, the cartridge(s) may be a container for the sorbents thereby allowing the removal and installation of the sorbent by removing and installing the cartridges. In this manner, the sorbents may be contained and handled using the cartridges. Further, the cartridges may be constructed using various materials suitable for handling sorbents and/or exhaust gases. In some embodiments, the cartridges may be one or more mesh bag(s) configured to hold the sorbent. In such embodiments, the mesh bags may allow the exhaust gases directed from the gas deflector surface(s) to pass though the sorbent material. In some embodiments, the cartridges may be built into the detachable section 208 of the cargo box 200. In some embodiments, the cartridges may be placed in any configuration provided exhaust gases enter the cargo box 200 via the input port and residual gases exit via an exit port 210. In some embodiments, each of the cartridges 208 may have its own input port and exit port.
[0047] In further reference to
[0048] Although specific cargo boxes of carbon dioxide capture systems are discussed with respect to
Carbon Dioxide Capture Systems Using Cartridges in Parallel and/or in Series
[0049] Carbon dioxide capture systems may be configured using cartridges in parallel and/or in series, as further described below. In many embodiments, the cartridges may or may not use a cargo box configuration but may instead be connected using a manifold and/or a coupler. For example, the cartridges may be connected to each other in parallel using a manifold. In a further example, cartridges may be connected to each other in series using a coupler, as further described below.
[0050] A carbon dioxide capture system secured to a vehicle in accordance with another embodiment of the invention is illustrated in
[0051] In reference to
[0052] As discussed previously, the carbon dioxide capture systems may be secured to a top, a bottom, a front, or a rear of a vehicle. Further, considering that the cartridges 310, the manifold 306, and the coupler(s) (e.g., couplers 308, 321, 325) will likely be in contact with exhaust gases that may be corrosive and/or of a high temperature, the cartridges 310, the manifold 306, and the coupler(s) 308, 321, 325 may be constructed using heat-resistant and corrosion-resistant material, including (but not limited to) metals, stainless steel, titanium, high-temperature plastics, and silicon carbide. Furthermore, the manifold 306, the coupler(s) 308, 321, 325, and the exhaust feeder 304 may also be constructed using a flexible material (e.g., PVC pipe), to adapt to the surfaces of different vehicles.
[0053] Although specific carbon dioxide capture systems utilizing cartridges in parallel and/or in series are discussed with respect to
Cartridges
[0054] A cartridge may be used in a carbon dioxide capture system to capture the carbon dioxide from exhaust gases. As described above, a cartridge may be a container for sorbents or any other material that may be used to separate a target gas (e.g., CO.sub.2) from the exhaust gases of a vehicle. In some embodiments, one or more cartridge(s) may be connected directly to an exhaust feeder via a manifold, as described above. In other embodiments, the cartridge may be placed inside a cargo box as a container for sorbent material, as described above.
[0055] A diagram illustrating a cartridge comprising meshes in accordance with an embodiment of the invention is shown in
[0056] A diagram illustrating a cartridge without meshes in accordance with an embodiment of the invention is shown in
[0057] A top-down perspective diagram illustrating a cartridge comprising meshes in accordance with an embodiment of the invention is shown in
[0058] In many embodiments, the cartridge 400 may be made of materials that are heat-resistant and corrosive-resistant, including metals, stainless steel, titanium, high-temperature plastics, and silicon carbide. The sorbent material 414 may comprise of any material that captures carbon dioxide (preferably at least 15 percent of mass in carbon dioxide captured), including metal-organic frameworks (MOFs), zeolites, silica, calcium oxides, organic-inorganic hybrids, alkylamines/amines, hydrotalcites, and activated carbons. A list of the commonly available sorbent material 414 is discussed in Table 1. Typically, different performance of the types of sorbent material 414 under various vehicle operating conditions should be expected. The sorbent material 414 may be of various size and shape, including pieces of sorbent in spherical shape formed together, such that it is held securely in between meshes or a mesh bag. In various embodiments, a mesh bag may be of any container with pore sizes that allow for inflow of gases while still holding the sorbent material 414. Various materials may be used in a mesh bag (e.g., nylon and cotton, among others). When the sorbent material 414 is partially or fully saturated with carbon dioxide, it may be removed, via the detachable lid 420 of the cartridge 400, and reinstalled following sorbent regeneration which allows for storage of carbon dioxide for biological carbon fixation. An example of biological carbon fixation is the use of carbon dioxide along with photosynthesis to achieve algae growth, with algae capable of being used in biofuels, biomass generation, wastewater treatment, and fertilizers.
[0059] Although specific cartridges are discussed with respect to
Reducing Carbon Dioxide Emissions Using Carbon Dioxide Capture Systems
[0060] A carbon dioxide capture system may be utilized to reduce carbon dioxide emissions. A flowchart illustrating a process for reducing carbon dioxide emissions from a vehicle in accordance with an embodiment of the invention is shown in
[0061] A flowchart illustrating a process for capturing CO.sub.2 in accordance with an embodiment of the invention is shown in
[0062] Regeneration of a sorbent allows for reuse of existing sorbent material and utilization of captured CO.sub.2 for beneficial processes such as (but not limited to) algae development. In turn, algae development allows for generation of biofuels, biomass, utilities in wastewater treatment, and fertilizers. A flowchart illustrating a process for regenerating a sorbent in accordance with an embodiment of the invention is shown in
[0063] A flowchart illustrating a process for reducing CO.sub.2 emissions from a vehicle in accordance with another embodiment of the invention is shown in
[0064] Although specific process for reducing carbon emissions from a vehicle using carbon dioxide capture systems are discussed with respect to
[0065] While the above descriptions contain many specific embodiments of the invention, these should not be construed as limitations on the scope of the invention, but rather as an example of one embodiment thereof. It is therefore to be understood that the present invention may be practiced otherwise than specifically described, without departing from the scope and spirit of the present invention. Thus, embodiments of the present invention should be considered in all respects as illustrative and not restrictive.