HYBRID ASYMMETRIC AUTOMOTIVE LAMINATE
20220402243 · 2022-12-22
Inventors
- Mario Arturo Mannheim Astete (Lima, PE)
- Iván CORNEJO (Lima, PE)
- Osmar CURI (Lima, PE)
- Jurgen DE SCHEPPER (Lima, PE)
Cpc classification
B32B3/266
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10155
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10036
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/54
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10119
PERFORMING OPERATIONS; TRANSPORTING
B32B17/10174
PERFORMING OPERATIONS; TRANSPORTING
B32B2605/006
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/546
PERFORMING OPERATIONS; TRANSPORTING
B32B3/08
PERFORMING OPERATIONS; TRANSPORTING
B32B3/085
PERFORMING OPERATIONS; TRANSPORTING
B32B3/06
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B3/06
PERFORMING OPERATIONS; TRANSPORTING
B32B3/08
PERFORMING OPERATIONS; TRANSPORTING
B32B3/26
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Laminated automotive glazing, once limited to just the windshield, is finding more and more application in other positions in vehicles due to its ability to reduce weight, as well as to improve passenger safety, security and comfort. Designing a laminate that can serve as a direct replacement for tempered glass can be challenging Tempered glass is 4 to 5 times stronger than annealed glass and the lamination process has limitations that are not present with tempered. In particular, it is difficult to produce thin laminated glazing with holes. The laminate of the invention comprises strengthened thin glass layers in combination with laminated inserts to provide a thin laminated glazing with holes that has all of the advantages inherent in a laminate while retaining the reliability and utility of a tempered part and further can serve as a direct replacement for a tempered part.
Claims
1. A laminated glazing comprising: a. an outer glass layer wherein, i. the outer glass layer is strengthened, ii. and has at least one hole, and b. an inner glass layer wherein, i. the inner glass layer is strengthened and ii. does not overlap the at least one hole of the outer glass layer, iii. has a lower edge which extends at least 20 mm below the beltline, iv. has a lower edge which extends such that it is overlapped by and captured by the mounting means and c. one or more plastic bonding layers positioned between opposite faces of the inner and outer glass layers wherein, i. the plastic bonding layer serving to bond the surface two of the outer glass layer to the surface three of the inner glass layer.
2. The glazing of claim 1 further comprising: a. one or more plastic layers provided with at least one cut out area in a portion of the laminate near a hole that is at least partially overlapped by the mounting means and, b. an insert wherein, i. the thickness of the insert is substantially the same as the plastic bonding layers and ii. the insert size will fit inside of the cutout area in the plastic bonding layer and iii. the insert is positioned between the inner and outer glass layers and iv. the insert has a stiffness greater than the plastic bonding layer and v. the insert is less compressible than the plastic bonding layer and vi. the insert becomes a permanent part of the laminate during the lamination process.
3. The glazing of claim 1 wherein the outer edge of the inner glass layer is offset inboard from the edge of outer glass layer along a substantial portion of the glass edge.
4. The glazing of claim 3 wherein the inner glass layer offset is in the range of 0.5 mm to 3.0 mm.
5. The glazing of claim 3 wherein the inner glass layer offset is in the range of 1.0 mm to 2.0 mm.
6. The glazing of claim 1 wherein the inner glass layer is extended such that it is at least partially overlapped by and captured by the mounting means.
7. The glazing of claim 1 wherein the inner glass layer is cold bent.
8. The glazing of claim 1 wherein the inner glass layer thickness is between 0.5 mm and 1.6 mm; preferably between 0.5 mm and 1.1 mm.
9. The glazing of claim 1 wherein the outer glass layer thickness is between 2.5 mm and 6 mm; preferably between 3 mm and 5 mm.
10. The glazing of claim 1 wherein the inner glass layer has a chamfered edge finish along at least the exposed portion of the edge.
11. The glazing of claim 1 wherein the inner glass layer has a bullnose edge finish along at least the exposed portion of the edge.
12. The glazing of claim 1 wherein the inner glass layer has a polished edge finish along at least the exposed portion of the edge.
13. The glazing of claim 2 wherein the insert is substantially comprised of at least one of the following materials: glass, carbon fiber composite, steel, aluminum, titanium, plastic, and fiberglass reinforced plastic.
14. The glazing of claim 2 wherein the insert at least partially overlaps the outer glass layer hole.
15. The glazing of claim 2 wherein the portion of the insert extending beyond the edge of the inner glass is thicker than the portion inside of the laminate.
16. The glazing of claim 2 wherein the insert is extended inboard beyond the overlap of the mounting means towards the beltline.
17. The glazing of claim 2 wherein the plastic interlayer has an elastic modulus that is higher than 50 MPa.
18. The glazing of claim 2 wherein the lower edge of the inner glass layer is extended by at least 20 mm below the beltline.
19. The glazing of claim 1 wherein the outer glass is thermally toughened achieving compressive stress between 60 and 150 MPa, preferably between 100 and 140 MPa.
20. The glazing of claim 1 wherein the inner glass is toughened or strengthened achieving compressive stress between 400 and 900 MPa, preferably between 500 and 800 MPa.
21. The glazing of claim 1 wherein a reinforcement is bonded to the exposed bottom portion of the surface two of the outer glass layer.
22. The glazing of claim 1 wherein a set of secondary retention holes is provided.
23. The glazing of claim 1 wherein a reinforcement is bonded to the inner and outer glass layers.
24. The glazing of claim 1 wherein the glazing comprises multiple monolithic portions along the lower edge separated by the inner glass layer.
25. The glazing of claim 1 wherein the inner glass layer is coated with at least one coating selected from the group consisting of thermal coating and anti-reflective coating.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
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REFERENCE NUMERALS OF DRAWINGS
[0071] 2 Glass [0072] 4 Plastic bonding layer (interlayer) [0073] 6 Obscuration [0074] 9 Insert [0075] 12 Film [0076] 18 Coating [0077] 20 Hole [0078] 22 Cutout [0079] 24 Beltline [0080] 30 Edge of glass [0081] 32 Glazing mounting means [0082] 34 Stopper [0083] 36 Retention holes [0084] 38 Reinforcement [0085] 101 Surface one [0086] 102 Surface two [0087] 103 Surface three [0088] 104 Surface four [0089] 201 Outer layer [0090] 202 Inner layer
DETAILED DESCRIPTION OF THE INVENTION
[0091] The following terminology is used to describe the laminated glazing of the invention.
[0092] A glazing is an article comprised of at least one layer of a transparent material which serves to provide for the transmission of light and/or to provide for viewing of the side opposite the viewer and which is mounted in an opening in a building, vehicle, wall or roof or other framing member or enclosure.
[0093] Laminates, in general, are articles comprised of multiple sheets of thin, relative to their length and width, material, with each thin sheet having two oppositely disposed major faces and typically of relatively uniform thickness, which are permanently bonded to one and other across at least one major face of each sheet.
[0094] Laminated safety glass is made by bonding two sheets (201 & 202) of annealed glass 2 together using a plastic bonding layer comprised of a thin sheet of transparent thermoplastic 4 (interlayer) as shown in
[0095] Typical automotive laminated glazing cross sections are illustrated in
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[0097] The plastic bonding layer 4 has the primary function of bonding the major faces of adjacent layers to each other. The material selected is typically a clear plastic when bonding to another glass layer 2. For automotive use, the most commonly used bonding layer 4 or interlayer is polyvinyl butyl (PVB). In addition to polyvinyl butyl, ionoplast polymers, ethylene vinyl acetate (EVA), cast in place (CIP) liquid resin and thermoplastic polyurethane (TPU) can also be used. Interlayers are available with enhanced capabilities beyond bonding the glass layers together. The invention may include interlayers designed to dampen sound. Such interlayers are comprised whole or in part of a layer of plastic that is softer and more flexible than that normally used.
[0098] The types of glass that may be used include but are not limited to: the common soda-lime variety typical of automotive glazing as well as aluminosilicate, lithium aluminosilicate, borosilicate, glass ceramics, and the various other inorganic solid amorphous compositions which undergo a glass transition and are classified as glass included those that are not transparent. The glass layers may be comprised of heat absorbing glass compositions as well as infrared reflecting and other types of coatings.
[0099] Most of the glass used for containers and windows is soda-lime glass. Soda-lime glass is made from sodium carbonate (soda), lime (calcium carbonate), dolomite, silicon dioxide (silica), aluminum oxide (alumina), and small quantities of substances added to alter the color and other properties.
[0100] Borosilicate glass is a type of glass that contains boric oxide. It has a low coefficient of thermal expansion and a high resistance to corrosive chemical. It is commonly used to make light bulbs, laboratory glassware, and cooking utensils.
[0101] Aluminosilicate glass is made with aluminum oxide. It is even more resistant to chemicals than borosilicate glass and it can withstand higher temperatures. Chemically tempered Aluminosilicate glass is widely used for displays on smart phones and other electronic devices.
[0102] Lithium-Aluminosilicate is a glass ceramic that has very low thermal expansion, optical transparency and high. It typically contains 3-6% Li2O. It is commonly used for fireplace windows, cooktop panels, lenses and other applications that require low thermal expansion.
[0103] Infrared reflecting coatings include but are not limited to the various metal/dielectric layered coatings applied though magnetron sputtered vacuum deposition (MSVD) as well as others known in the art that are applied via pyrolytic, spray, CVD, dip and other methods.
[0104] Infrared reflecting films include both metallic coated substrates as well as organic based optical films which reflect in the infrared.
[0105] The use of thin glass layers has been found to improve resistance to breakage from impact such as from stone chips. The thinner glass is more flexible and absorbs the energy of the impact by deflecting and then bouncing back rather than breaking as is the case with a thicker stiffer layer of glass. Also, embodiments comprising a borosilicate outer layer are substantially more resistant to impact than soda lime glass due to the nature of the composition. Embodiments comprising a chemically tempered layer will also exhibit superior resistance to impact as compared to ordinary soda-lime glass due to the high surface compression of such glasses.
[0106] The glass layers may be formed by any appropriate means known in the art including but not limited to: gravity bending, partial and full surface press bending and singlet bending.
[0107] Cold bending is a relatively new technology. As the name suggest, the glass is bent, while cold to its final shape, without the use of heat. On parts with minimal curvature a flat sheet of glass can be bent cold to the contour of the part. This is possible because as the thickness of glass decreases, the sheets become increasingly more flexible and can be bent without inducing stress levels high enough to significantly increase the long-term probability of breakage. Thin sheets of annealed soda-lime glass, in thicknesses of about 1 mm, can be bent to large radii cylindrical shapes (greater than 6 m). When the glass is chemically, or heat strengthened the glass can endure much higher levels of stress and can be bent along both major axes. The process is primarily used to bend chemically tempered thin glass sheets (<=1 mm) to shape.
[0108] Cylindrical shapes can be formed with a radius in one direction of less than 4 meters. Shapes with compound bend, that is curvature in the direction of both principle axis can be formed with a radius of curvature in each direction of as small as approximately 8 meters. Of course, much depends upon the surface area of the parts and the types and thicknesses of the substrates.
[0109] The cold bent glass will remain in tension and tend to distort the shape of the bent layer that it is bonded to. Therefore, the bent layer must be compensated to offset the tension. For more complex shapes with a high level of curvature, the flat glass may need to be partially thermally bent prior to cold bending.
[0110] The glass to be cold bent is placed with a bent to shape layer and with a bonding layer placed between the glass to be cold bent and the bent glass layer. The assembly is placed in what is known as a vacuum bag. The vacuum bag is an airtight set of plastic sheets, enclosing the assembly and bonded together it the edges, which allows for the air to be evacuated from the assembly and which also applies pressure on the assembly forcing the layers into contact. The assembly, in the evacuated vacuum bag, is then heated to seal the assembly. The assembly is next placed into an autoclave which heats the assembly and applies high pressure. This completes the cold bending process as the flat glass at this point has conformed to the shape of the bent layer and is permanently affixed. The cold bending process is very similar to a standard vacuum bag/autoclave process, well known in the art, except for having an unbent glass layer added to the stack of glass.
[0111] The beltline is the line formed by the lower visible edge of the vehicle glazing. The beltline of the vehicle front and rear doors is the portion where the door window seals come into contact with the glass. The portion of the door glazing that is below the beltline is not visible.
[0112] The glass layers may be annealed or strengthened. There are two processes that can be used to increase the strength of glass. They are thermal strengthening, in which the hot glass is rapidly cooled (quenched) and chemical tempering which achieves the same effect through an ion exchange chemical treatment.
[0113] Heat strengthened, full temper soda-lime float glass, with a compressive strength in the range of at least 70 MPa, can be used in all vehicle positions other than the windshield. Heat strengthened (tempered) glass has a layer of high compression on the outside surfaces of the glass, balanced by tension on the inside of the glass which is produced by the rapid cooling of the hot softened glass. When tempered glass breaks, the tension and compression are no longer in balance and the glass breaks into small beads with dull edges. Tempered glass is much stronger than annealed laminated glass. The thickness limits of the typical automotive heat strengthening process are in the 3.2 mm to 3.6 mm range. This is due to the rapid heat transfer that is required. It is not possible to achieve the high surface compression needed with thinner glass using the typical blower type low pressure air quenching systems.
[0114] In the chemical tempering process, ions in and near the outside surface of the glass are exchanged with ions that are larger. This places the outer layer of glass in compression. Compressive strengths of up to 1, 000 MPa are possible. The typical methods involved submerging the glass in a tank of molten salt where the ion exchange takes place. The glass surface must not have any paint or coatings that will interfere with the ion exchange process.
[0115] The invention is comprised of a laminate having two glass layers with each having opposed major faces bonded together permanently by at least one plastic bonding layer and having at least one hole.
[0116] The outer layer 201 is cut and the hole or holes are cut in the same manner as would a tempered part.
[0117] No holes are cut in the inner glass layer 202. The inner glass layer is cut such that the inner glass layer does not overlap the hole or holes in the outer glass layer. Preferably, the edge of the inner glass layer extends to just above the edge of the hole or holes in the outer glass layer. In this manner, the mounting means will capture at least a part of the inner glass layer and plastic interlayer serving to retain the laminate in the event of breakage.
[0118] The typical edge finish used for laminated and tempered glass is a diamond ground edge with a C shaped profile (
[0119] A cutout is made in the plastic bonding layer 4 such as to expose the number two surface 102 of the outer glass layer 201 in the areas in and surrounding the hole(s).
[0120] An insert 9 is fabricated to fit into the cutout. The inserts' primary function is to prevent compression of the glass layers by the mounting means during installation and during use. Therefore, the insert does not need to extend to the edge of the inner glass layer. It may be rectangular or circular in shape. It also does not need to be as large as the portion of the mounting means that overlaps the insert. Alternately, the insert 9 may extend substantially beyond the edge of the inner glass layer 202. The insert may be as large or larger than the overlapping portion of the mounting means. The insert may extend beyond the edge of the inner glass layer and overlap the hole in the outer glass layer 201. The insert 9 may have a hole 20 corresponding to the hole 20 in the outer glass layer 201. The insert may be thicker that the plastic bonding layer in the area beyond the edge of the inner glass layer. The insert may be bonded to the glass. Once mounted in the vehicle, the mounting means places the glass layers in compression further strengthening the assembly and improving resistance to breakage as well as overall stiffness.
[0121] The insert 9 can be fabricated from any suitable material that can provide the strength needed. Potential materials include but are not limited to: annealed glass, chemically strengthened glass, heat strengthened glass, carbon fiber composite, steel, aluminum, titanium, plastic and fiberglass reinforced plastic all may be suitable depending upon the exact application and loading.
[0122] The insert may be temporarily held in place my means of an adhesive. If the lamination assembly process accommodates the insert may be held in place by just the pressure and friction from the glass and interlayer. If the insert does not extend to the edge of glass or beyond, it may be captured by the cut out in the plastic bonding layer. An autoclave is used to apply heat and pressure to the assembled laminate to complete the lamination process.
[0123] If the insert extends beyond the edge of glass, the insert 9 can be bonded to the outer glass surface using any adhesive which is suitable for the materials examples of which include but are not limited to moisture cure and two component polyurethane. This step can be completed before or after the autoclave cycle.
[0124] The insert may be further strengthened and stiffened by the addition of additional components. An example would be an injected molded, cast or machined reinforced insert.
[0125] The chemically or thermally strengthened outer glass layer, when broken is likely to detach from the mounting means. An external impact is likely to only break the outer glass layer as the outer layer will absorb and dissipate the energy from most impacts. The broken outer layer will be held together in the portion of the glazing that is laminated by the intact inner layer and the interlayer. The overlap of the inner glass layer and interlayer with the mounting means will allow the glazing to remain in place in the opening and possibly for limited movement until it can be replaced.
[0126] The use of insert further enhances retention of the glazing in the mounting system.
[0127] In place of or in conjunction with the use of inserts a number of other means may be used to enhance retention of the laminate in the opening in the event of breakage by modifying the laminate along at least a portion of the non-overlapping area of the laminate in the area where the mounting means is attached.
[0128] The use of a stopper 34 is shown in
[0129] Another method that can be used is to extend the plastic interlayer to overlap the mounting means contact area as shown in
[0130] The reinforcement needs to be made of a stiff material. A layer of thick polyurethane has been shown to serve the purpose just as well as it maintains high adhesion to the glass while preventing the broken pieces from separating. Other flexible materials and coatings may also be utilized to serve this same function.
[0131] The reinforcement need not overlap the entire exposed area. Indeed, it can be substantially less and be just as effective. The only real requirement that it at least partially extend and overlap the mounting means, otherwise, it cannot improve glazing retention.
[0132] The primary problem with holes through the laminate come from the forces applied to the hole during installation and use. Another method to enhance retention of the glazing in the opening after breakage makes use of a secondary set of holes in the glass which pass through both of the glass layers and the interlayers. These are just secondary holes which will only see any force applied if the primary mounting holes should fail. The concept in illustrated in
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0133] 1. A movable door window (sidelite) with a set of two holes is illustrated in