Heterogeneous composites and products thereof

Abstract

A heterogeneous composite has a first layer which includes a fiber layer, a metal layer, a plastic layer or a combination thereof, a second layer which includes a fiber layer with a plastic layer, or a fiber layer with a non-woven cloth layer, and a base layer which is a thermoplastic layer. The first layer and the second layer are respectively mounted on the base layer by a glue layer, and the compressive strength value between the first layer and the second layer is less than 20%. The base layer enhances strength of the whole composite, and the heterogeneous composite provides a beautiful and competitive product.

Claims

1. A heterogeneous composite sequentially comprising: a first layer which includes a fiber layer, a metal layer, a plastic layer or a combination thereof, a second layer which includes a fiber layer with a plastic layer, or a fiber layer with a non-woven cloth layer, and a base layer which is a thermoplastic layer, wherein the first layer and the second layer are respectively mounted on the base layer by a glue layer, wherein a compressive strength value between the first layer and the second layer is less than 20%, wherein: the base layer includes polyethylene terephthalate (PET), polypropylene (PP), polyethylene (PE), Nylon, polycarbonate (PC) or polymethylmethacrylate (PMMA), the fiber layer includes polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), carbon fiber, Kevlar fiber, glass fiber, nylon, or natural fiber, the plastic layer includes polypropylene (PP), Nylon, polyurethane (PU), thermoplastic urethane (TPU), polyethylene terephthalate (PET), polycarbonate (PC) or polymethylmethacrylate (PMMA), the metal layer includes aluminum, magnuminium alloys, stainless steel, chromium-plated brass or titanium alloy, and the glue layer includes co-polyolefin, co-polyamide, co-polyester, thermoplastic polyurethane, polyolefin, polyamide or polyester.

2. The heterogeneous composite of claim 1, wherein a thickness of the base layer is about 0.2 to 3.0 mm, a thickness of the fiber layer or the non-woven cloth layer is about 0.2 to 0.5 mm, a thickness of the plastic layer is about 0.05 to 0.15 mm, and a thickness of the metal layer is about 0.1 to 0.5 mm.

3. The heterogeneous composite of claim 1, wherein the glue layer permeates about to volume of the fiber layer.

4. The heterogeneous composite of claim 2, wherein the glue layer permeates about to volume of the fiber layer.

5. The heterogeneous composite of claim 1, wherein the non-woven cloth layer is mounted on the fiber layer by a pinprick which makes the non-woven cloth layer partially cross-mounted on the fiber layer.

6. The heterogeneous composite of claim 2, wherein the non-woven cloth layer is mounted on the fiber layer by pinprick which makes the non-woven cloth layer partially cross-mounted on the fiber layer.

7. The heterogeneous composite of claim 1, wherein the plastic layer has a different pattern made by sublimation or print.

8. A luggage case, comprising the heterogeneous composite claimed in claim 1.

9. A roller skate, comprising the heterogeneous composite claimed in claim 1.

10. A protective clothing, comprising the heterogeneous composite claimed in claim 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

(1) FIG. 1 is a perspective view of a first preferred embodiment of the present invention.

(2) FIGS. 2a to 2d are sectional views of the first preferred embodiment of the present invention.

(3) FIG. 2e is a sectional view of a second preferred embodiment of the present invention.

(4) FIG. 3 is a perspective view of a third preferred embodiment of the present invention.

(5) FIGS. 4a, 4b and 4c are views of a luggage case, a roller skate, and protective clothing applying the heterogenous composite of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

(6) With reference to FIG. 1, a perspective view of a first embodiment, a heterogeneous composite 10a in accordance with the present invention is shown. The heterogeneous composite 10a sequentially has a first layer 13a, a base layer 11a and a second layer 15a. Each layer is combined by a glue layer (A).

(7) In the first embodiment of the present invention, the first layer 13a has a fiber layer 131a and a plastic layer 132a. The fiber layer 131a shows a knit pattern and has a stronger strength than the conventional one. In a preferred embodiment, the thickness of the fiber layer 131a is about 0.2 mm to 0.5 mm, and the material of the fiber layer 131a may be, but is not limited to, polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), carbon fiber, Kevlar fiber, glass fiber, nylon, or natural fiber.

(8) The plastic layer 132a is mounted on the top surface of the fiber layer 131a to form a protection or a glossy top. In addition, the plastic layer 132a may have different patterns made by thermal sublimation or print. In a preferred embodiment, the thickness of the plastic layer 132a is about 0.05 mm to 0.15 mm, and the material of the plastic layer 132a may be, but is not limited to, polypropylene (PP), Nylon, polyurethane (PU), thermoplastic urethane (TPU), polyethylene terephthalate (PET), Syrlyn or Pebox, polycarbonate (PC) or polymethylmethacrylate (PMMA).

(9) The second layer 15a also has a fiber layer 151a and a plastic layer 152a, and a glue layer A is mounted between the fiber layer 151a and the plastic layer 152a. The materials used for making the fiber layer 151a and plastic layer 152a are the same as described above.

(10) The base layer 11a is one of the main characteristics in the present invention. The base layer 11a is mounted between the first layer 13a and the second layer 15a, and enhances the strength of the heterogeneous composite 10a in the present invention. In a preferred embodiment, the base layer 11a may be made by thermoplastic, and the thermoplastic may be, but is not limited to, polyethylene terephthalate (PET), polypropylene (PP), polyethylene (PE), Nylon, polycarbonate (PC) or polymethylmethacrylate (PMMA). The thickness of the base layer 11a may be 0.2 mm to 5.0 mm.

(11) The glue layer (A) may be, but is not limited to, co-polyolefin, co-polyamide, co-polyester or thermoplastic polyurethane. The glue layer (A) may be a transparent glue or a transparent membrane which depends on the materials of the fiber layer 131a. For example, when the fiber layer 131a is made of a polyethylene fiber and the base layer 11a is a polyethylene plate, the glue layer (A) may be co-polyolefin to make a better connection of the fiber layer 131a and the base layer 11a.

(12) To make the strength balance between the two sides of the base layer 11a, the compressive strength between the first layer 13a and the second layer 15a may be 0 to 20%. The compressive strength includes anti-bending, tensile strength and impact resisting strength. When the stress of the first layer 13a and the second layer 15a is the same or similar, the post-process of manufacture would be convenient and warping, delamination, and pattern wrinkles formed between processes would be prevented. Further, the material, thickness of the layers and Denier of fiber layer may be adjusted by considering the balance of compressive strength.

(13) In one embodiment of the present invention, the material of the first layer 13a and the second layer 15a are different. For example, the fiber layer 131a of the first layer 13a is 1100 Denier, and the thickness is 0.2 mm. The thickness of the plastic layer 132a is 0.1 mm, the corresponding fiber layer 151a could be 900 to 1300 Denier and the thickness of the plastic layer 152a could be 0.05 to 0.15 mm. By the structure described in the example, the compressive strength of the base plate 11a could be balanced, and warping, delamination and pattern wrinkling would be prevented.

(14) In a preferred embodiment of the present invention, the glue layer (A) may be mounted between the fiber layer 131a and the fiber layer 151a by semi-impregnation. The term, semi-impregnation, means the glue layer (A) may permeate between the fiber layer 131a and 151a. The glue layer (A) may permeate about to volume of each fiber layer 131a and 151a without glue leakage. The method for semi-impregnation may be operated by stacking the fiber layers 131a, 151a and the glue layer (A), and then, connecting each layer by the parameter of heat compressing to make the glue layer (A) semi-impregnated into the fiber layer 131a and 151a.

(15) With FIGS. 2a to 2d, in a first preferred embodiment of the present invention, the arrangement of each layer may be varied depending on the balance of compressive strength of each layer.

(16) With FIG. 2e, in the second preferred embodiment of the present invention, the plastic layer 132a may be replaced by a non-woven cloth 153a which is mounted on the fiber layer 131a by a pinprick to make the fiber of non-woven cloth 153a partially cross-mounted on the fiber layer 131a. Optionally, the non-woven cloth 153a may be mounted on the fiber layer 131a by glue.

(17) With FIG. 3, in a third preferred embodiment of the present invention, a heterogeneous composite 10b shows similar structure to the first embodiment and the second embodiment. However, the first layer 13a is replaced by a metal sheet 13b, and the thickness of metal sheet is about 0.1 to 0.5 mm. The material of the metal sheet 13b may be, but is not limited to, aluminum, magnuminium alloys, stainless steel, chromium-plated brass or titanium alloy. The second layer 15a may be replaced with a fiber layer 15b, and the material may be, but is not limited to, carbon fiber, glass fiber, polyester fiber, Nylon fiber or natural fiber. The base layer 11b is thermoplastic and may be polyethylene (PET), polypropylene (PP), polyethylene (PE), Nylon, polycarbonate (PC) or polymethylmethacrylate (PMMA).

(18) To combine the metal sheet 13b and the plastic base layer 11b, the glue layer (B) may comprise polyolefin, polyamide or polyester. The glue layer (B) between the second layer 15b and the base layer 11b also could be polyethylene (PET), polypropylene (PP), polyethylene (PE), Nylon, polycarbonate (PC) or polymethylmethacrylate (PMMA), and co-polyolefin, co-polyamide, co-polyester or thermoplastic polyurethane described in the first preferred embodiment.

(19) To balance the compressive strength of the first layer 13a and the second layer 15b which is made of plastic plate or natural fiber, the first layer 13a may be a thin aluminum sheet with 0.2 mm thickness, and the second layer 15b may be a fiber layer of 1300 to 1800 Denier with 0.2 to 0.5 mm thickness. Therefore, the compressive strength beside the base layer 11b will be balanced.

(20) The preferable methods for manufacturing the heterogeneous composites, is to stack each layer, to choose the material of each layer, to set up the parameter of heat-pressing according to the material of each layer, to press the stacking layers into a 50 C. hot-pressing bed, to heat up to about 150 to 178 C. with pressure of 14 to 20 kg/cm2 for 3 to 6 minutes, and then to cool down to 50 C. to obtain the final products.

(21) The heterogeneous composite may be applied in various fields, such as luggage cases (shown in FIG. 4a), protective clothing (shown in FIG. 4c), roller skates (shown in FIG. 4b), in-line skates or housings of notebooks.

(22) While this invention has been described in terms of the preferred embodiments thereof, it is not intended to be so limited, but rather only to the extent set forth in the claims that follow. Moreover, the use of the terms first, second, etc. does not denote any order of importance, but rather the terms first, second, etc. are used to distinguish one element from another. Furthermore, the use of the terms a, an, etc. do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced items.