Heat-Resistant Easy-Open Package
20180079577 ยท 2018-03-22
Inventors
Cpc classification
B32B2307/50
PERFORMING OPERATIONS; TRANSPORTING
B32B1/00
PERFORMING OPERATIONS; TRANSPORTING
B65D77/2036
PERFORMING OPERATIONS; TRANSPORTING
B32B2307/546
PERFORMING OPERATIONS; TRANSPORTING
B32B2270/00
PERFORMING OPERATIONS; TRANSPORTING
B65D77/2044
PERFORMING OPERATIONS; TRANSPORTING
International classification
B65D77/20
PERFORMING OPERATIONS; TRANSPORTING
Abstract
The present invention is directed to manually openable heat-resistant packages for containing a product that include a thermoformed tray having a product receiving area and a sealing flange endowed with sufficient heat resistance to withstand the cooking and/or pasteurization/sterilization conditions required to produce a ready-to-eat packaged meal. The tray comprises a bulk layer, and a heat sealing layer in direct contact with the bulk layer. The inventive packages also include a flexible transparent lidding film covering the thermoformed product receiving area comprising a heat sealing layer. The package includes a hermetic seal comprising a perimeter heat seal which circumvents the thermoformed tray formed by heat sealing a portion of the heat sealing layer of the lidding film to the sealing flange of the tray. Only the heat sealing layer of the tray is readily frangible and renders the heat seal manually peelable.
Claims
1. A manually openable heat-resistant package for containing a product comprising: a thermoformed tray having a product receiving area and a sealing flange, wherein the tray comprises: a bulk layer; a heat sealing layer in direct contact with the bulk layer and comprising a blend of substantially amorphous aromatic polyester and a polyester-immiscible contaminant; a flexible transparent lidding film covering the thermoformed product receiving area comprising a heat sealing layer comprising a substantially amorphous aromatic polyester; a hermetic seal comprising a perimeter heat seal circumventing the thermoformed tray formed by heat sealing a portion of the heat sealing layer of the lidding film to the sealing flange of the tray; wherein the hermetic seal comprises a seal strength of between 500 g/in and 3000 g/in at 93 C. (200 F.); and wherein only the heat sealing layer of the tray is readily frangible and renders the heat seal manually peelable.
2. A package according to claim 1, wherein the substantially amorphous aromatic polyester copolymer is selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyhexamethylene terephthalate; polyethylene-2,6-naphthalate, polytrimethylene-2,6-naphthalate, polybutylene-2,6-naphthalate, polyhexamethylene-2,6-natphthalate, polyethylene isophthalate, polytrimethylene isophthalate, polybutylene isophthalate, polyhexamethylene isophthalate, poly-1,4-cyclohexane-dimethanol terephthalate, and polybutylene adipate terephthalate and derivatives thereof.
3. A package according to claim 1, wherein the heat sealing layer of the tray comprises a substantially amorphous aromatic polyester comprising a copolymer comprising a terephthalatic acid repeating component and a diethylene glycol diol repeating component.
4. A package according to claim 3, wherein the diethylene glycol dial repeating component which is present in an amount of greater than 2 mole % of the total copolymer composition.
5. A package according to claim 3, wherein the diethylene glycol dial repeating component is present in an amount of at least 37 mole % of the total copolymer composition.
6. A package according to claim 1, wherein the heat sealing layer of the tray comprises a substantially amorphous aromatic polyester comprising a terephthalatic acid repeating component and an isophthalatic acid repeating component.
7. A package according to claim 1, wherein the bulk layer of the tray comprises a polyethylene terephthalate.
8. A package according to claim 7, wherein the polyethylene terephthalate is crystalline polyethylene terephthalate.
9. A package according to claim 1, wherein the polyester-immiscible contaminant is a polyolefin.
10. A package according to claim 9, wherein the polyolefin is selected from the group consisting of polyethylene, polypropylene, polybutene and blends thereof.
11. A package according to claim 10, wherein the polyethylene is a high density polyethylene.
12. A package according to claim 10, wherein the polyolefin is polypropylene.
13. A package according to claim 1, wherein the heat sealing layer of the tray comprises between 40% and 85% by weight of polyethylene terephthalate or polyethylene terephthalate/isophthalate copolymer relative to the total weight of the heat sealing layer.
14. A package according to claim 1, wherein the heat sealing layer of the tray comprises between 15% and 80% by weight of a polyester-immiscible contaminant relative to the total weight of the heat sealing layer.
15. A package according to claim 1, wherein the hermetic seal has a seal strength of between 1000 g/in and 3,000 g/in at 93 C. (200 F.).
16. A package according to claim 1, wherein the hermetic seal has a peel strength of between 2000 g/in and 3,000 g/in at 93 C. (200 F.).
17. A package according to claim 1, wherein the hermetic seal remains sealed while subjected to a temperature of 100 C. for between 1-10 minutes and under an internal pressure of between 3-4 psi.
18. A package according to claim 1, wherein the flexible lidding film has a haze value of 10% or less.
19. A package according to claim 1, wherein the package comprises an integrally formed tamper-evident feature.
20. A package according to claim 1 wherein the tamper-evident feature comprises visible whitened area of the lidding film produced when the hermetic seal has been breached.
21.-23. (canceled)
Description
BRIEF DESCRIPTION OF THE DRAWINGS
[0017] Further features and advantages of the present invention will become apparent from the following detailed description, taken in combination with the appended drawings, in which:
[0018]
[0019]
[0020]
[0021]
[0022]
DETAILED DESCRIPTION OF THE INVENTION
[0023] The present inventions now will be described more fully hereinafter with reference to the accompanying drawings, in which some, but not all embodiments of the inventions are shown. Indeed, these inventions may be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will satisfy applicable legal requirements. Like numbers refer to like elements throughout.
[0024] Referring now more particularly to
[0025] Further included with package 10 is a flexible lidding film 50 which covers the product receiving area 30. Package 10 also includes a hermetic seal 60 comprising a perimeter heat seal 70 circumventing the thermoformed tray formed by heat sealing a portion of the heat sealing layer 51 (shown in
[0026] An advantageous optional feature of the present invention is that it may include an integrally formed tamper-evident feature. In one preferred embodiment, the tamper-evident feature comprises a visible whitened area of the sealing flange of the tray produced when the hermetic seal has been breached which occurs when the lidding film is peeled from the tray. In another preferred embodiment, the tamper-evident feature comprises a visible whitened area of the lidding film produced when the hermetic seal has been breached which occurs when the lidding film is peeled from the tray. In still another embodiment, the tamper-evident feature comprises both a visible whitened area of the sealing flange of the tray and a visible whitened area of the lidding film produced when the hermetic seal has been breached which occurs when the lidding film is peeled from the tray.
[0027] In a preferred embodiment of the package of the present invention, lidding film may be a mono-layer film comprising heat sealing layer formed from a substantially amorphous aromatic polyester. Specific examples of substantially amorphous aromatic polyester copolymers may include, but are not limited to: polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, polyhexamethylene terephthalate; polyethylene-2,6-naphthalate, polytrimethylene-2,6-naphthalate, polybutylene-2,6-naphthalate, polyhexamethylene-2,6-natphthalate, polyethylene isophthalate, polytrimethylene isophthalate, polybutylene isophthalate, polyhexamethylene isophthalate, poly-1,4-cyclohexane-dimethanol terephthalate, and polybutylene adipate terephthalate. Among these, amorphous polyethylene terephthalate is preferably used. In another preferred, lidding film may comprises a multilayer film which includes heat sealing layer formed from an aromatic polyester, especially an amorphous polyethylene terephthalate copolymer and bulk layers, abuse layers, tie layers and/or barrier layers. It should be understood that lidding film may include any number of layers with the condition that it includes at least a heat sealing layer formed from an aromatic polyester. For example, as depicted in
[0028] Referring back now to
WORKING EXAMPLES
Trays
[0029] In the following Examples 1-8, there is described various preferred embodiments of a tray 20 having a two-layer structure as illustrated in
Example 1
[0030] Example 1 is one preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. Reported below is the layer composition relative to the total weight of the layer. [0031] Layer 21: 100 wt.-% of a blend of 6.8 kg (15 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+6.8 kg (15 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0032] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 2
[0033] Example 2 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0034] Layer 21: 100 wt.-% of a blend of 8.16 kg (18 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc. Kingsport, Tenn., USA)+5.44 kg (12 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0035] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 3
[0036] Example 3 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0037] Layer 21: 100 wt.-% of a blend of 8.85 kg (19.5 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+4.76 kg (10.5 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0038] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 4a
[0039] Example 4 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0040] Layer 21: 100 wt.-% of a blend of 9.53 kg (21 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+4.1 kg (9 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0041] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 4b
[0042] Example 4b is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0043] Layer 21: 100 wt.-% of a blend of 9.53 kg (21 lb) of an amorphous polyethylene terephthalate/isophthalate copolymer (APET)-Type 7391 (Indorama Ventures Auriga Polymers, Inc., Charlotte, N.C., USA)+4.1 kg (9 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0044] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 5
[0045] Example 5 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0046] Layer 21: 100 wt.-% of a blend of 10.21 kg (22.5 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+3.4 kg (7.5 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0047] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 6
[0048] Example 6 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above for Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0049] Layer 21: 100 wt.-% of a blend of 10.89 kg (24 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+2.72 kg (6 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0050] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Example 7
[0051] Example 7 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below. In this embodiment, layers 21 and 22 were prepared in a manner similar to that described above far Example 1 except for the composition of sealing layer 21. Reported below is the layer composition relative to the total weight of the layer. [0052] Layer 21: 100 wt.-% of a blend of 11.57 kg (25.5 lb) of an amorphous polyethylene terephthalate copolymer (APET)-EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+2.0 kg (4.5 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0053] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Comparative Example 1
[0054] Comparative Example 1 is an embodiment of the heat sealing layer 21 of tray 20 having a structure and layer compositions as described below and as illustrated in
Comparative Example 2
[0057] Comparative Example 1 is an embodiment of the heat sealing layer 21 of tray 20 having a structure and layer compositions as described below and as illustrated in
[0060] In the following Example 8, there is described another preferred embodiment of a tray 20 having a two-layer structure as illustrated in
Example 8
[0061] Example 8 is another preferred embodiment of the heat sealing layer 21 of tray 20 of the present invention having a structure and layer compositions as described below and. Reported below is the layer composition relative to the total weight of the layer. [0062] Layer 21: 100 wt.-% of a blend of 4.54 kg (10 lb) of an amorphous polyethylene terephthalate copolymer (APET)-Eastman Eastobond Copolyester 19212 (Eastman Chemical Company, Inc., Kingsport, Tenn., USA)+6.8 kg (15 lb) of a high density polyethylene (HDPE)-Alathon L5885 (having a density of 0.958 g/cc and a melt index of 0.85 g/10 min) (Lyondell Chemical Company, Houston, Tex., USA). [0063] Layer 22: 100 wt.-% of a crystalline polyethylene terephthalate film (CPET)-Preformance PET 1708 (StarPET, Inc., Asheboro, N.C., USA).
Seal Strengths
[0064] The seal strengths for the different heat sealing layers of Examples 1-8 and Comparative Examples 1-2 were determined by cutting a one-inch wide strip from the formed trays. Each strip was heat sealed to a one-inch wide strip of lidding film 50 as described above (see
Burst Strengths
[0065] The burst strengths for the different heat sealing layers of Examples 1-8 and Comparative Example 1 were determined by filling each tray (maximum volume is 600 mL) with approximately 100 mL of water and sealing a lidding film 50 as described above (see
TABLE-US-00001 TABLE 1 SEAL SEAL Wt.-% STRENGTH STRENGTH BURST HDPE/Wt.-% @ 23 C. @ 93 C. STRENGTH SAMPLE APET (g/in) (g/in) (psi) Example 1 50/50.sup.a 3185 861 0.11 Example 2 40/60.sup.a 3078 1191 1.81 Example 3 35/65.sup.a 5059 1655 3.03 Example 4a 30/70.sup.a 5365 2324 2.35 Example 4b 30/70.sup.b 4890 1690 Example 5 25/75.sup.a 4551 1707 3.16 Example 6 20/80.sup.a No peel.sup.d 3455 3.05 Example 7 15/85.sup.a No peel.sup.d 3339 3.38 Example 8 60/40.sup.a 2671 879 Comparative (100% APET) 3169 No peel.sup.d 3.11 Example 1 Comparative 35/65.sup.c No seal No seal Example 1 .sup.a = APET is EASTOBOND Copolyester 19412 (Eastman Chemical Company, Inc., Kingsport, TN, USA); .sup.b = APET is Type 7391 (Indorama Ventures Auriga Polymers, Inc., Charlotte, NC, USA); .sup.c = APET is Laser+ C 9921 (F65A) (DAK Americas LLC, Chadds Ford, PA, USA); .sup.d = no peel refers to delamination occurring at or above 4000 g/in.
[0066] It will be learned from the above results that a preferred embodiment of a heat sealing layer of a tray according to the present invention includes, but is not limited to, a substantially amorphous aromatic polyester having only a terephthalatic acid repeating component and greater than 2 mole % or at least 37 mole % of a diethylene glycol diol repeating component or both a terephthalatic acid repeating component and an isophthalatic acid repeating component combined with between 15% and 80% by weight of a polyester-immiscible contaminant, especially high density polyethylene which provides a manually openable heat-resistant package having a seal strength of between 500 g/in and 3,000 g/in at 93 C. (200 F.).
[0067] The above description and examples illustrate certain embodiments of the present invention and are not to be interpreted as limiting. Selection of particular embodiments, combinations thereof, modifications, and adaptations of the various embodiments, conditions and parameters normally encountered in the art will be apparent to those skilled in the art and are deemed to be within the spirit and scope of the present invention.